2006

1

1 ) , : 1. n=4 , l=3

2. n=5 , l=1 3. n=5 , l=2 , ml=3 4. n=2 , ml=0 5. n=2 , ms=1/2

( 5)

) : R-NH2 2 1. R-NH2 [-] 2. R-NH2 [-]

3. R-NH2 , pH -. 4. R-NH2 pH .

( 5)

) pH - 1 . 250C 1. HCOONa 4. 2. KCl 5. NH4Br 3. 3 6. Ca(OH)2

( 5) ) 2-

=

|

|

3

| |3

3 3 3

3

3 2 2 3 3 3

CH

CH OH

|| |1.CH C CH CH 2. CH CH O

O CH

3.CH CH CHCH CH 4.CH C CH CHOH

( 5) ) :

=

=

|

|3

3 3 3OH

3 2 3 3CH

1.CH CH CHCOOH 3.CH C HCH

2.CH C CHCH CH 4.CH COOH

; i) Br2 CCl4 ii) K2CO3

( 5)

2006

2 2 ) - , :

17 , 27 , 7 , 18

, ( 5)

) :

A B , , , :

|| | |3 3 3 3 3 3 3O Cl OH

CH CCH CH CHCH CH C CH CH CHCH . .

( 5) ) :

|3 3 2 3 6 5Cl

3 2 3 2 2

1.CH COOH 2.CH CH CHCH 3.C H OH

4.CH CH C CH 5.CH CH CH OH

( 5)

) 1 (=10-5) , 2(=10-7) 3(=10-9) : 1. 3 HCl 2. aOH HCl 3. CH3COOH NaOH : (CH3COOH)=10-5 Kb(NH3)=10-5

( 5) ) CH3MgCl CH3CH2CH2CH=O - . : 1. CH3MgCl | |3 2 3CH C CH CH

O

2. CH3CH2CH2CH2MgCl CH2=O

3. ||3

CH3CH C MgCl

CH3 CH2=O

4. CH3CH2CH2MgCl CH3CH=O . .

2006

3( 5)

3 . C2() 2H O+ |O| +HCl Mg+ + .............. 2H O+C6H14O (K) +KCN Z 2+2 H +2 2 + ) ( 10) ) KMnO4 H2SO4.

( 8) ) mL KMnO4 0,05 H2SO4 - 6gr ;

( 7) 4 100ml 0,1 ( 1) 250C pH 3 . 1. 1 0,1 1L . pH ( 2). ( 6) 2. 1 0,01mol HCl 3 . - pH 3 ( 6). 3. 3 0,02mol NaOH 4. pH 4 . ( 7) 4. 1 100 ml 3 0,1 (b(NH3)=10-5). pH 5 . ( 6). .