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Contents JANUARY/FEBRUARY 1968 PESTICIDES 6 Absorption and Metabolism of Antimycin Administered with a Rat Diet P. Ο. Ritter and F. M. Strong 13 Metabolism of Insecticides. Microsynthesis of 14 C-/3-Dihydroheptachîor N. H. Poonawalla and Friedhelm Korte 15 Metabolism of /3-Dihydroheptachlor- 14 C in Soil and by Microorganisms Ν. H. Poonawalla and Friedhelm Korte 17 Degradation of Monsodium Methanearsonic Acid by Soil Microorganisms D. W. Von Endt, P. C. Kearney, and D. D. Kaufman 21 Adsorption of 3-Aminotriazole by Montmorillonitc /. D. Russell, M. I. Cruz, and J. L. White 25 Enzymic Browning and Free Tyrosine in Potatoes as Affected by Pentachloronitrobenzene /. P. Sweeney and P. A. Simandle 28 Oxidation of Methyl- and Dimethylcarbamate Insecticide Chemicals by Microsomal Enzymes and Anticholinesterase Activity of Metabolites E. S. Oonnithan and J. E. Casida 45 Metabolic Studies with 0,0-Diethyl 0-(3,5,6-Trichloro-2-pyridyl) Phosphorothioate (Dursban) Insecticide in a Lactating Cow W. H. Gutenmann, L. E. St. John, Jr., and D. J. Lisk 48 Determination of Hydrolytic Metabolites of Organophosphorus Insecticides in Cow Urine Using an Improved Thermionic Detector L. E. St. John, Jr., and D. J. Lisk 50 Improved Method for Determination of Sulfonamides in Milk and Tissues F. Tishler, J. L. Sutter, J. N. Bathish, and H. E. Hagtnan 54 Determination of Terbacil Residues Using Microcoulometric Gas Chromatography H. L. Pease VOL. 16, NO. 1 © COPYRIGHT 1968 BY THE AMERICAN CHEMICAL SOCIETY EDITOR: PHILIP K. BATES Manager, Manuscript Reviewing: Katherine I. Biggs Manager, Manuscript Editing: Ruth Reynard Editorial Assistants: Anne Marie Cromey, Elizabeth J. Kight, Patricia Mernone, Norma Yess Director of Design: Joseph Jacobs Production Manager: Bacil Guiley Layout: Herbert Kuttner Production Easton, Pa. 18042 Associate Editor: Charlotte C. Sayre Editorial Assistant: Jane M. Andrews EDITORIAL HEADQUARTERS 1155 Sixteenth St., N.W. Washington, D.C. 20036 Phone 202-737-3337 Teletype WA 23 ADVISORY BOARD Morton Beroza, Donald G. Crosby, Richard Hall, Irwin Hornstein, J. B. Knaak, Gordon Mackinney, Robert L. Metcalf, Alvin B. Phillips, W. F. Phillips, Loren B. Sjoström, J. Wade Van Valkenburg, Jr., Emily L. Wick AMERICAN CHEMICAL SOCIETY PUBLICATIONS Director of Publications: Richard L. Kenyon Director of Business Operations: Joseph H. Kuney Publication Manager, Journals: David E. Gushee Executive Assistant to the Director of Publications: Rodney N. Hader Circulation Development Manager: Herbert C. Spencer Assistant to the Director of Publications: William Q. Hull 2 J. AGR. FOOD CHEM.

Transcript of Masthead

Page 1: Masthead

Contents J A N U A R Y / F E B R U A R Y 1968

P E S T I C I D E S

6 Absorption and Metabolism of Antimycin Administered with a Rat Diet P. Ο. Ritter and F. M. Strong

13 Metabolism of Insecticides. Microsynthesis of 14C-/3-Dihydroheptachîor N. H. Poonawalla and Friedhelm Korte

15 Metabolism of /3-Dihydroheptachlor-14C in Soil and by Microorganisms Ν. H. Poonawalla and Friedhelm Korte

17 Degradation of Monsodium Methanearsonic Acid by Soil Microorganisms D. W. Von Endt, P. C. Kearney, and D. D. Kaufman

21 Adsorption of 3-Aminotriazole by Montmorillonitc / . D. Russell, M. I. Cruz, and J. L. White

25 Enzymic Browning and Free Tyrosine in Potatoes as Affected by Pentachloronitrobenzene / . P. Sweeney and P. A. Simandle

28 Oxidation of Methyl- and Dimethylcarbamate Insecticide Chemicals by Microsomal Enzymes and Anticholinesterase Activity of Metabolites

E. S. Oonnithan and J. E. Casida

45 Metabolic Studies with 0 ,0-Die thyl 0-(3,5,6-Trichloro-2-pyridyl) Phosphorothioate (Dursban) Insecticide in a Lactating Cow

W. H. Gutenmann, L. E. St. John, Jr., and D. J. Lisk

48 Determination of Hydrolytic Metabolites of Organophosphorus Insecticides in Cow Urine Using an Improved Thermionic Detector

L. E. St. John, Jr., and D. J. Lisk

50 Improved Method for Determination of Sulfonamides in Milk and Tissues F. Tishler, J. L. Sutter, J. N. Bathish, and H. E. Hagtnan

54 Determination of Terbacil Residues Using Microcoulometric Gas Chromatography H. L. Pease

V O L . 1 6 , N O . 1 © C O P Y R I G H T 1 9 6 8 B Y T H E A M E R I C A N C H E M I C A L S O C I E T Y

EDITOR: PHILIP K. BATES

Manager, Manuscript Reviewing: Katherine I. Biggs Manager, Manuscript Editing: Ruth Reynard Editorial Assistants: Anne Marie Cromey, Elizabeth J. Kight, Patricia Mernone, Norma Yess

Director of Design: Joseph Jacobs Production Manager: Bacil Guiley Layout: Herbert Kuttner Production — Easton, Pa. 18042 Associate Editor: Charlotte C. Sayre Editorial Assistant: Jane M. Andrews

EDITORIAL H E A D Q U A R T E R S 1155 Sixteenth St., N.W. Washington, D.C. 20036 Phone 202-737-3337 Teletype WA 23

ADVISORY BOARD

Morton Beroza, Donald G. Crosby, Richard Hall, Irwin Hornstein, J. B. Knaak, Gordon Mackinney, Robert L. Metcalf, Alvin B. Phillips, W. F . Phillips, Loren B. Sjoström,

J. Wade Van Valkenburg, Jr., Emily L. Wick

AMERICAN CHEMICAL SOCIETY PUBLICATIONS

Director of Publications: Richard L. Kenyon

Director of Business Operations: Joseph H. Kuney

Publication Manager, Journals: David E. Gushee

Executive Assistant to the Director of Publications: Rodney N. Hader

Circulation Development Manager: Herbert C. Spencer

Assistant to the Director of Publications: William Q. Hull

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Contents Continued

F L A V O R S

108 Dihydrochalcones. Synthesis of Potential Sweetening Agents Leroy Krbechek, George Inglett, Melville Holik, Basil Dowling, Richard Wagner, and Richard Riter

113 Some Minor Sesquiterpene Hydrocarbons of Black Pepper C. J. Muller, R. K. Creveling, and W. G. Jennings

P L A N T C O M P O U N D S

118 Spectrophotometry Determination of Limonin in Orange Juice K. W. Wilson and C. A. Crutchfield

125 Physicochemical Properties of Brown Rice from Oryza Species and Hybrids C. C. Ignacio and B. O. Juliano

128 Immunochemical Study of Soybean Proteins N. Catsimpoolas and E. W. Meyer

132 Sinapine and Related Esters in Seed Meal of Crambe abyssinica F. L. Austin and I. A. Wolf

F E R T I L I Z E R S

136 Inhibition of Thermal Decomposition of Ammonium Nitrate G. H. Madany and George Burnet

C O M M U N I C A T I O N S

142 Thin-Layer Chromatography of Bromacil Residues in Soils D. J. Hamilton

143 Chromatographic Determination of 4-Trinuoromethyl-2,4'-dinitrodiphenyl Ether Residues in Soybeans

/ . P. Walter, M. L. Ker chers id, and M. G. Merkle

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