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Sulfur (cas 7704-34-9) MSDS

1.1.1

IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKINGProduct identifiersProduct name

Product NumberBrandCAS-No.

:

:::

Sulfur84683-7704-34-9

1.2 Relevant identified uses of the substance or mixture and uses advised againstIdentified uses : Laboratory chemicals, Manufacture of substances

2.2.1

2.2

HAZARDS IDENTIFICATIONClassification of the substance or mixtureClassification according to Regulation (EC) No 1272/2008 [EU-GHS/CLP]Skin irritation (Category 2)

Classification according to EU Directives 67/548/EEC or 1999/45/ECIrritating to skin.

Label elementsLabelling according Regulation (EC) No 1272/2008 [CLP]Pictogram

Signal word

Hazard statement(s)H315

Precautionary statement(s)

Supplemental Hazard

Warning

Causes skin irritation.

none

noneStatements

According to European Directive 67/548/EEC as amended.Hazard symbol(s)

R-phrase(s)R38 Irritating to skin.

S-phrase(s)S46 If swallowed, seek medical advice immediately and show this container or

label.

2.3

3.3.1

Other hazards - none

COMPOSITION/INFORMATION ON INGREDIENTSSubstancesSynonyms

FormulaMolecular Weight

Component

Sulfur

:

::

sulfur (Aerosol)

S32,07 g/mol

Concentration

CAS-No.EC-No.

7704-34-9231-722-6

-

4.4.1

FIRST AID MEASURESDescription of first aid measuresGeneral adviceConsult a physician. Show this safety data sheet to the doctor in attendance.

If inhaled

4.2

4.3

5.5.1

5.2

5.3

5.4

6.6.1

If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.

In case of skin contactWash off with soap and plenty of water. Consult a physician.

In case of eye contactFlush eyes with water as a precaution.

If swallowedNever give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.

Most important symptoms and effects, both acute and delayedSymptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath,headache, nausea, and vomiting., Dermatitis

Indication of any immediate medical attention and special treatment neededno data available

FIREFIGHTING MEASURESExtinguishing mediaSuitable extinguishing mediaUse water spray, alcohol-resistant foam, dry chemical or carbon dioxide.

Special hazards arising from the substance or mixtureSulphur oxides

Advice for firefightersWear self contained breathing apparatus for fire fighting if necessary.

Further informationno data available

ACCIDENTAL RELEASE MEASURESPersonal precautions, protective equipment and emergency proceduresUse personal protective equipment. Avoid dust formation. Avoid breathing vapors, mist or gas. Ensureadequate ventilation. Avoid breathing dust.

6.2

6.3

6.4

7.7.1

7.2

7.3

8.8.1

8.2

Environmental precautionsDo not let product enter drains.

Methods and materials for containment and cleaning upPick up and arrange disposal without creating dust. Sweep up and shovel. Keep in suitable, closedcontainers for disposal.

Reference to other sectionsFor disposal see section 13.

HANDLING AND STORAGEPrecautions for safe handlingAvoid contact with skin and eyes. Avoid formation of dust and aerosols.Provide appropriate exhaust ventilation at places where dust is formed.

Conditions for safe storage, including any incompatibilitiesStore in cool place. Keep container tightly closed in a dry and well-ventilated place.

Specific end usesno data available

EXPOSURE CONTROLS/PERSONAL PROTECTIONControl parametersComponents with workplace control parametersExposure controlsAppropriate engineering controlsHandle in accordance with good industrial hygiene and safety practice. Wash hands before breaks andat the end of workday.

Personal protective equipmentEye/face protectionSafety glasses with side-shields conforming to EN166 Use equipment for eye protection testedand approved under appropriate government standards such as NIOSH (US) or EN 166(EU).

Skin protectionHandle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique(without touching glove's outer surface) to avoid skin contact with this product. Dispose ofcontaminated gloves after use in accordance with applicable laws and good laboratory practices.Wash and dry hands.

The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and

9.9.1

the standard EN 374 derived from it.

Body Protectionimpervious clothing, The type of protective equipment must be selected according to theconcentration and amount of the dangerous substance at the specific workplace.

Respiratory protectionFor nuisance exposures use type P95 (US) or type P1 (EU EN 143) particle respirator.For higherlevel protection use type OV/AG/P99 (US) or type ABEK-P2 (EU EN 143) respirator cartridges.Use respirators and components tested and approved under appropriate government standardssuch as NIOSH (US) or CEN (EU).

PHYSICAL AND CHEMICAL PROPERTIESInformation on basic physical and chemical propertiesa)

b)

c)

Appearance

Odour

Odour Threshold

Form: flakesColour: light yellowslight

no data available

d)

e)

f)

g)

h)

pH

Melting point/freezingpoint

Initial boiling point andboiling range

Flash point

Evaporation rate

no data available

Melting point/range: 118 - 120 °C

444,7 °C

207 °C - closed cup

no data availablei) Flammability (solid, gas) no data available

j)

k)

l)

Upper/lowerflammability orexplosive limitsVapour pressure

Vapour density

Upper explosion limit: 6,83 %(V)Lower explosion limit: 0,17 %(V)

10 hPa at 246 °C1 hPa at 183,8 °C

no data available

m) Relative density 2,05 g/cm3 at 20 °C

n)o)

p)

q)

r)

s)

t)

Water solubilityPartition coefficient: n-octanol/waterAutoignitiontemperatureDecompositiontemperature

Viscosity

Explosive properties

Oxidizing properties

insolubleno data available

240 °C

no data available

8 mm2/s at 140 °C -

no data available

no data available

9.2

10.10.1

10.2

10.3

10.4

10.5

10.6

11.11.1

Other safety informationno data available

STABILITY AND REACTIVITYReactivityno data available

Chemical stabilityno data available

Possibility of hazardous reactionsno data available

Conditions to avoidno data available

Incompatible materialsStrong oxidizing agentsAmines, Bases

Hazardous decomposition productsOther decomposition products - no data available

TOXICOLOGICAL INFORMATIONInformation on toxicological effects

Acute toxicityLDLO Oral - rabbit - 175 mg/kg

LD50 Oral - rat - > 2.000 mg/kg

LC50 Inhalation - rat - 4 h - > 9,23 mg/l

LD50 Dermal - rabbit - > 2.000 mg/kg

LDLO Intravenous - rat - 8 mg/kg

LDLO Intravenous - rabbit - 5 mg/kg

LDLO Intraperitoneal - guinea pig - 55 mg/kg

LDLO Intravenous - dog - 10 mg/kg

Skin corrosion/irritationSkin - rabbit - No skin irritation

Serious eye damage/eye irritationEyes - rabbit - No eye irritation

Respiratory or skin sensitizationno data available

Germ cell mutagenicityno data available

CarcinogenicityIARC: No component of this product present at levels greater than or equal to 0.1% is identified as

probable, possible or confirmed human carcinogen by IARC.

Reproductive toxicityno data available

Specific target organ toxicity - single exposureno data available

Specific target organ toxicity - repeated exposureno data available

Aspiration hazardno data available

Potential health effectsInhalationIngestionSkin

May be harmful if inhaled. Causes respiratory tract irritation.May be harmful if swallowed.May be harmful if absorbed through skin. Causes skin irritation.

Signs and Symptoms of ExposureSymptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath,headache, nausea, and vomiting., Dermatitis

Additional InformationRTECS: Not available

12.12.1

ECOLOGICAL INFORMATIONToxicityToxicity to fish

Toxicity to daphnia andother aquaticinvertebrates

LC50 - Oncorhynchus mykiss (rainbow trout) - > 180 mg/l - 96 h

LC50 - other fish - 866 mg/l - 96 h

EC50 - Daphnia magna (Water flea) - > 5.000 mg/l - 48 h

12.2

12.3

Persistence and degradabilityno data available

Bioaccumulative potentialno data available

12.4

12.5

12.6

13.

Mobility in soilno data available

Results of PBT and vPvB assessmentno data available

Other adverse effectsno data available

DISPOSAL CONSIDERATIONS

13.1

14.14.1

Waste treatment methodsProductOffer surplus and non-recyclable solutions to a licensed disposal company. Dissolve or mix the materialwith a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber.

Contaminated packagingDispose of as unused product.

TRANSPORT INFORMATIONUN number

14.2

14.3

14.4

14.5

14.6

15.

ADR/RID: 1350

UN proper shipping nameADR/RID: SULPHURIMDG: SULPHURIATA: Sulphur

Transport hazard class(es)ADR/RID: 4.1

Packaging groupADR/RID: III

Environmental hazardsADR/RID: no

Special precautions for userno data available

REGULATORY INFORMATION

IMDG: 1350

IMDG: 4.1

IMDG: III

IMDG Marine pollutant: no

IATA: 1350

IATA: 4.1

IATA: III

IATA: no

This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.

15.1

15.2

16.

Safety, health and environmental regulations/legislation specific for the substance or mixtureno data available

Chemical Safety Assessmentno data available

OTHER INFORMATIONFurther informationThe above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information this document is based on the resent state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. guidechem shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale.