Handbook of Infrared Standards II || METHYL CHLORIDE SPECTRAL MAPS AND WAVENUMBER DATA: 6.2...

SECTION IV METHYL CHLORIDE SPECTRAL MAPS AND WAVENUMBER

DATA: 6.2 μπι-7.7 μιτι

For high resolution research in the regions of strong atmospheric absorptions due to water vapor and carbon dioxide, there is need to have reference spectra for molecular species other than these two molecules, H20 and C02. It has therefore been con-sidered useful to present the spectra of CH3C1, which have been recorded by the same FTS facility as was used in generating the information given in Section I of this handbook. These spectra observed between 1309 cm-1 (7.7 /xm) and 1594 cm-1

(6.2 /xm) have been included in the following pages (618-715) by adopting the for-mat of a spectral map on the even-numbered pages and wavenumber data on the opposite odd-numbered pages. If one examines the summary map attached to the inside of the back cover page of this book, one notices that for this spectral region, mostly water vapor standards have been listed in the previous handbook.1 Only be-tween 1305-1345 cm-1 N20 standards are also available. Incidentally, when look-ing at the same spectral map, we realize that there has been a scarcity of wavenumber standards in the far infrared. For the spectral region 25-350 cm- 1, pure rotational water vapor data were furnished. This deficiency of standards in the infrared has been partly rectified by FTS measurements on CH3OH in the region 100-350 cm-1. The results have been reported in extensive publications,24,25 each of which is 60 to 70 pages in length and includes spectral positions as well as spectral maps.

24G. Moruzzi, P. Riminucci, F. Strumia, B. Carli, M. Carlotti, R. M. Lees, I. Mukhopadhyay, J. W. C. Johns, B. P. Winnewisser, and M. Winnewisser, J. of Mol. Spectrosc. 144, 139-200, (1990).

25G. Moruzzi, F. Strumia, J. C. S. Moraes, R. M. Lees, I. Mukhopadhyay, J. W. C. Johns, B. P. Win-newisser and M. Winnewisser, J. of Mol. Spectrosc. 153, 511-577 (1992).

§ X ABSORPTION o § X ABSORPTION o § X ABSORPTION o

o

o o

212

LINE

WAVENUMBER

ROTATIONAL

BAND

ISOTOPIC

-1

NO.

CM

;VAC.

ASSIGNMENT

SPECIES

1

2

3 4 5

6 7 8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

1309.

1309.

1309.

1309.

1309.

1309.

1309.

1310.

1310.

1310.

1310.

1311 .

1311 .

1311 .

1311 .

1311 .

1311 .

1312.

1312.

1312.

1312.

1313.

1313.

1313.

1313.

1313.

1313.

1313.

1313.

1313. .05928

.20385

.34065

.36735

.67446

.88495

.90592

.19086

.24717

.60164

.87768

.00888

.09262

.66328

.84671

.86030

.88995

.07527

.19692

.25615

.60663

.05340

.11655

. 14376

.26708

.37934

.43312

.44905

.53994

.77802

* *

*

* *

*

*

*

*

*

* *

* * * *

* *

* * *

* *

* *

* *

*

* *

- "LINE NO.": serial number identifying the :

- "WAVENUMBER": observed value.

- * : all given lines are selected according

Lines with an asterisk (*) are selected but not

LINE

WAVENUMBER

ROTATIONAL

BAND

ISOTOPIC

-1

NO.

CM

;VAC.

ASSIGNMENT

SPECIES

31

32

33

34

35

36

37

38

39

40

1314.

1314.

1314.

1314.

1314.

1314.

1314,

1314,

1315.

1315. .23665

.25439

.37062

.45319

.55591

.60441

.61859

.94362

.04022

.44945

* * * *

* * *

* * *

pectral line in the map on the opposite page.

to intensity, halfwidth and symmetry criteria,

identified.

619 612

8 X ABSORPTION o 8 X ABSORPTION o 8 X ABSORPTION o

o 212

LINE

WAVENUMBER

ROTATIONAL

BAND

ISOTOPIC

LINE

WAVENUMBER

ROTATIONAL

BAND

ISOTOPIC

-1

-1

NO.

CM

;VAC.

ASSIGNMENT

SPECIES

NO.

CM

;VAC.

ASSIGNMENT

SPECIES

1

2

3 4 5 6

7 8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

1315.51771

1315.58702

1315.62192

1315.72654

1315.74662

1315.78229

1316.13106

1316.23063

1316.24239

1316.30477

1316.57331

1316.63849

1316.79474

1316.89113

1317.09728

1317.25722

1317.51031

1317.82148

1317.97546

1318.04959

1318.06770

1318.40507

1318.47400

1318.56053

1318.70975

1318.99829

1319.18486

1319.20207

1319.33613

1319.54674

* * * * * * * * * * * * * *

*

* * * * *

*

* * * * * * * * *

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

1319.60643 *

1319.68377 *

1319.90309 *

1319.96292 *

1320.16862 *

1320.29265 *

1320.34812 *

1320.48935 *

1320.59956 *

1320.68221 *

1320.73278 *

1320.96744 *

1320.99639 *

1321.08995 *

1321.44169 *

1321.70992 *

1321.77347 *

1321.79287 *

1321.81154 *

1321.83652 *

1322.02143 *

1322.16190 *

1322.18329 *

1322.25151 *

1322.27020 *

1322.48984 *

1322.58411 *

1322.62104 *

- "LINE NO.": serial number identifying the spectral line in the map on the opposite page.


- * : all given lines are selected according to intensity, halfwidth and symmetry criteria.

Lines with an asterisk (*) are selected but not identified.

621 612


212

LINE

NO. 1

2

3 4 5

6 7

8

9

10

1 1

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

WAVENUMBER

-1

CM

;VAC.

1322.84717

1322.93410

1322.96655

1323.03786

1323.09569

1323.10656

1323.33405

1323.64035

1323.71990

1323.79250

1323.97783

1324.18545

1324.29890

1324.34653

1324.39758

1324.61045

1324.78407

1324.84897

1324.86896

1325.10157

1325.15980

1325.17421

1325.38136

1325.52409

1325.56679

1325.74838

1325.77001

1325.92085

1326.21856

1326.57034

* *

* * * * * *

* * *

* * *

* *

* * * *

* * *

*

*

ROTATIONAL

ASSIGNMENT

0P6(3O)

OP 5(30)

OP 6(29)

OP 5(29)

OP 6(28)

BAND

NU2

NU2

NU2

NU2

NU2

ISOTOPIC

SPECIES

CH3 35C1

CH3 35C1

CH3 35C1

CH3 35C1

CH3 35C1

LINE

NO.

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

WAVENUMBER

-1

CM

;VAC.

1326.72236

1326.74487

1326.87487

1326.92239

1326.99895

1327.05032

1327.21025

1327.30769

1327.32852

1327.75203

1327.96080

1328.03589

1328.06728

1328.14525

1328.29856

1328.33526

1328.44779

1328.92621

1329.17149

1329.20468

1329.33592

1329.38574

1329.51082

1329.59753

1329.64675

1330.09270

* *

*

* * * * *

* *

*

* * *

*

* * * * *

ROTATIONAL

ASSIGNMENT

OP 5(28)

OP 6(27)

OP 5(27)

OP 6(26)

OP 5(26)

OP 6(25)

BAND

NU2

NU2

NU2

NU2

NU2

NU2

ISO-rOPIC

SPECIES

CH3

CH3

CH3

CH3

CH3

CH3

35C1

35C1

35C1

35C1

35C1

35C1





623 612

g X ABSORPTION c § X ABSORPTION o § X ABSORPTION o

C75 212

LINE

WAVENUMBER

ROTATIONAL

BAND

ISOTOPIC

-1

NO.

CM

;VAC.

ASSIGNMENT

SPECIES

1

2

3 4 5

6 7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

30 - - -

Lines

1330

1330

1330,

1330

1331.

1331 .

1331 .

1331 ,

1331.

1331 .

1331 .

1331 .

1331 .

1331 ,

1332.

1332.

1332.

1332.

1332.

1332.

1332.

1332.

1332.

1332.

1332.

1332.

1333.

1333.

1333.

1333,

"LINE .36505

.52080

.59076

.89603

. 14236

.25105

.44326

.45587

.49482

.57484

.60072

.61062

.63762

.79725

.40117

.47368

.48449

.51436

.55474

.56936

.58683

.60314

.64819

.69032

.73313

.87030

.20366

.49181

.53197

.54337

NO. " :

"WAVENUMBER' *

* *

*

* * * * *

* * * * * *

*

PO

PO

PO

PO

PO

PO

PO

PO

PO

PO

PO

PO

PO

PO

OP

ser ial

* : all given

with

2(25)

6(24)

2(24)

5(24)

4(24)

6(23)

0(23)

1(23)

2(23)

3(23)

5(23)

4(23)

0(22)

1(22)

6(22)

number

NU2

NU2

NU2

NU2

NU2

NU2

NU2

NU2

NU2

NU2

NU2

NU2

NU2

NU2

NU2

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

identifying the

observed value.

lines are se

an asterisk ( [*) are elected accord in«

selected but no

LINE

NO.

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

WAVENUMBER

CM

1333,

1333,

1333.

1334.

1334.

1334.

1334,

1334.

1334.

1334.

1334.

1334.

1334.

1334.

1334.

1334.

1334.

1334.

1335.

1335.

1335.

1335.

1335.

1335.

1335.

1335.

1335.

1335.

1336.

1336. ;VAC.

.57803

.72432

.73606

.03423

.19613

.37914

.58298

.59640

.63436

.68988

.72182

.73553

.74716

.78958

.86596

.89243

.92232

.97358

. 12414

.18891

.38513

.54715

.62670

.64131

.68301

.76281

.86992

.94129

.08754

.25019

* * * * * *

* *

* *

* * * *

* * *

* *

* * *

ROTATIONAL

ASSIGNMENT

PO

PO

PO

PO

PO

PO

PO

PO

0(21)

1(21)

2(21)

3(21)

4(21)

0(20)

1(20)

2(20)

BAND

NU2

NU2

NU2

NU2

NU2

NU2

NU2

NU2

ISOTOPIC

SPECIES

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

ipectral line in the map on the opposite page.


identified.

625 612

LINE

NO.

61

62

63

64

65

66

67

68

69

70

71

72

73

74

WAVENUMBER

-1

CM

;VAC.

1336.56582

1336.72428

1336.76697

1336.78300

1336.79406

1336.82947

1336.87504

1336.91292

1336.93884

1336.98383

1337.05217

1337.38591

1337.44173

1337.46672

*

* *

*

* * * * *

ROTATIONAL

ASSIGNMENT

PQ

PO

PO

PO

PO

2(19)

3(19)

4(19)

6(19)

5(19)

BAND

NU2

NU2

NU2

NU2

NU2

ISOTOPIC

SPECIES

CH3 35C1

CH3 35C1

CH3 35C1

CH3 35C1

CH3 35C1



- * : all given lines are selected according to intensity, halfwi-dth and symmetry criteria.


627 612

8 X ABSORPTION o 8 X ABSORPTION o g X ABSORPTION o

Γ

3-

<]ω

J

oo 212

LINE

NO. 1

2

3 4 5

6 7 8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

WAVENUMBER

_ 1

CM

1337.

1337.

1337.

1337.

1337.

1337.

1337.

1338.

1338.

1338.

1338.

1338.

1338.

1338.

1338.

1339.

1339.

1339.

1339.

1339.

1339.

1339.

1339.

1339.

1339.

1339.

1340.

1340.

1340.

1340. ;VAC.

.69186

.70883

.73751

.75798

.77860

.83430

.84534

. 11990

.68537

.71342

.73133

.78362

85420

.86657

.89942

.04268

.07039

.11155

. 19495

.72732

.74615

.78003

.85529

.89069

.94484

.98630

.00394

.08386

.19550

.25985

*

*

*

* *

*

* *

*

* *

* *

*

*

ROTATIONAL

ASSIGNMENT

PO

PO

PO

PO

PO

PO

PO

PO

PO

PO

PO

PO

PO

PO

PO

0(18)

1(18)

2(18)

3(18)

0(17)

1(17)

2(17)

3(17)

5(17)

6(17)

0(16)

1(16)

3(16)

4(16)

6(16)

BAND

NU2

NU2

NU2

NU2

NU2

NU2

NU2

NU2

NU2

NU2

NU2

NU2

NU2

NU2

NU2

ISOTOPIC

SPECIES

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

LINE

NO.

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

WAVENUMBER

_ 1

CM

1340,

1340

1340

1340

1340

1340.

1340

1340

1341

1341

1341

1341

1341

1341

1341

1341 ,

1341

1341

1341

1341

1341

1341

1341

1342

1342

1342

1342

1342

1342

1343

;VAC.

.73349

.75337

.76958

.78960

.81224

.84872

.90678

.94388

.02973

.06802

.19123

.20527

.24923

.26886

.28939

.31433

.36467

.73206

.75253

.81460

.83444

.91457

.93488

.04672

.06790

.19754

.59585

.64812

.99700

.43538

* *

*

*

* * * *

* * *

*

* *

*

* *

* *

ROTATIONAL

ASSIGNMENT

PO

PO

PO

PO

PO

PO

PO

PO

PO

PO

PO

0(15)

1(15)

2(15)

3(15)

4(15)

6(15)

0(14)

1(14)

2(14)

4( 14)

5(14)

BAND

NU2

NU2

NU2

NU2

NU2

NU2

NU2

NU2

NU2

NU2

NU2

ISOTOPIC

SPECIES

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1





629 612

8 % ABSORPTIOM o g % ABSORPTION o 8 X ABSORPTION o

1

3

==g% ~1

y

o en n Z2

8 CD

212

LINE

NO.

61

62

63

64

65

66

67

68

69

70

71

72

73

WAVENUMBER

-1

CM

;VAC.

1343.69309

1343.70594

1343.72846

1343.78258

1343.79538

1343.89251

1343.90559

1343.93571

1344.04167

1344.22244

1344.65253

1344.74488

1344.77367

*

*

*

* * * * *

ROTATIONAL

ASSIGNMENT

PO

PO

PO

PO

PO

0(12)

1(12)

2(12)

3(12)

2(11)

BAND

NU2

NU2

NU2

NU2

NU2

ISOTOPIC

SPECIES

CH3 35C1

CH3 35C1

CH3 35C1

CH3 35C1

CH3 35C1





631 612

8 X ABSORPTION o § % ABSORPTION o 8 > ABSORPTION o

8 212

INE

NO. 1

2

3 4 5

6 7

8

9

10

1 1

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

WAVENUMBER

_ 1

CM

1344.

1344.

1345.

1345.

1345.

1345.

1345.

1345.

1345.

1345.

1345.

1345.

1345.

1346,

1346.

1346.

1346.

1346.

1346.

1346.

1346.

1346.

1346.

1346.

1346.

1347.

1347,

1347,

1347,

1347, ;VAC.

.85902

.88782

.04422

.20860

.45044

.60395

.62695

.64857

.67246

.69927

.81723

.86198

.98032

.02527

.18505

.23002

.42209

.46664

.57252

.60811

.63259

.64574

.76708

.82759

.99708

.15140

.21270

.40890

.47042

.50934

*

*

*

* *

* *

*

*

*

*

* *

*

*

*

*

ROTATK DNAL

ASSIGNMENT

PO

PO

PO

PO

PO

PO

PO

PO

PO

PO

PO

PO

PO

3(11)

4(11)

6(11)

1(10)

3(10)

4(10)

5(10)

6(10)

0(

3(

4(

5(

6(

9)

9)

9)

9)

9)

BAND

NU2

NU2

NU 2

NU2

NU2

NU2

NU2

NU2

NU2

NU2

NU2

NU2

NU2

ISO! fOPIC

SPECIES

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

LINE

NO.

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

WAVENUMBER

_ 1

CM

;VAC.

1347.55964

1347.58447

1347.65960

1347.69475 *

1347.78466

1347.90146 *

1347.95964

1348.18498

1348.38370 *

1348.41275 *

1348.46198

1348.50316

1348.51429 *

1348.52863

1348.60510

1348.64168 *

1348.73294

1348.91286

1349.05379 *

1349.14683

1349.33332 *

1349.43871

1349.46455

1349.54237

1349.67258

1349.74947 *

1349.85671

1350.24613 *

1350.27221 *

1350.36614

ROT/ \TI( DNAL

ASSIGNMENT

PO

PO

PO

PO

PO

PO

PO

PO

PO

PO

PO

PO

PO

PO

PO

PO

PO

PO

PO

0(

K

2(

3(

4(

5(

6(

0(

K

2(

3(

4(

5(

0(

K

2(

3(

4(

0(

8)

8)

8)

8)

8)

8)

8)

7)

7)

7)

7)

7)

7)

6)

6)

6)

6)

6)

5)

BAND

NU2

NU2

NU2

NU2

NU2

NU2

NU2

NU2

NU2

NU2

NU2

NU2

NU2

NU2

NU 2

NU2

NU2

NU2

NU2

ISO^ fOPIC

SPECIES

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

- "LINE NO.": serial number identifying the spectral line in the map.on the opposite page.




633 612

g X ABSORPTION o § X ABSORPTION o § X ABSORPTION o

212

LINE

NO.

61

62

63

64

65

66

67

68

69

70

WAVENUMBER

-1

CM

;VAC.

1350.39232

1350.48226 *

1350.60349

1351.28551

1351.31198

1351.39120

1351.47328 *

1351.52559

1352.04798 *

1352.07443 *

ROTATIONAL

ASSIGNMENT

PO K

5)

PO 3( 5)

PQ 0( 4)

PO K

4)

PO 2( 4)

PO 3( 4)

BAND

NU2

NU2

NU 2

NU2

NU2

NU2

ISOTOPIC

SPECIES

CH3 35C1

CH3 35C1

CH3 35C1

CH3 35C1

CH3 35C1

CH3 35C1





635 612


o DO ZD

O O

CO 212

LINE

NO. •1

2

3 4 5

6 7

8

9

10

1 1

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

WAVENUMBER

_ 1

CM

1352.

1352.

1352.

1353.

1353.

1353.

1353.

1354.

1354.

1354.

1354.

1354.

1354.

1354.

1355.

1355.

1355.

1355.

1355.

1355.

1355.

1355.

1355.

1355.

1355.

1355.

1356.

1356.

1356.

1357. ;VAC.

.19685

.22343

.93717

. 12670

.78055

.87108

.99486

.19891

.36632

.55561

.62333

.63809

.77366

.82481

.01974

.05287

.07222

.14661

.22440

.27551

.32745

.64430

.72968

.76035

.87341

.88469

.43971

.95912

.97387

. 12372 *

* *

* * * * * *

* *

t t * * * * * *

* * * * * *

*

ROTATIONAL

ASSIGNMENT

PO 0(

PO

PO

PO

K

K

0(

3)

3)

2)

1)

BAND

NU2

NU 2

NU2

NU2

ISOTOPIC

SPECIES

CH3

CH3

CH3

CH3

35C1

35C1

35C1

35C1

LINE

NO.

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

WAVENUMBER

_ 1

CM

1357.

1357.

1357.

1357.

1357.

1357.

1357.

1357.

1357.

1357.

1358.

1358.

1358.

1358.

1358.

1358.

1358.

1358.

1358.

1358.

1359.

1359.

1359. ;VAC.

. 18018

.24866

.26284

.32558

.41049

.43198

.74974

.83100

,87549

.97153

.14700

. 18250

.19473

.22336

.25500

.27167

.30880

.45150

.53320

.92657

.03979

. 19264

.21843

* * *

* *

* * * * *

* *

* * * * *

* * *

ROTATIONAL

ASSIGNMENT

RO

RO

RO

2(

0(

K

3)

4)

4)

BAND

NU2

NU2

NU2

ISOTOPIC

SPECIES

CH3

CH3

CH3

35C1

35C1

35C1





637 612

8 X ABSORPTION o § X ABSORPTION o § X ABSORPTION o

^o

3Γ

3

CO c»

212

LINE

NO. 1

2

3 4 5

6 7 8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

WAVENUMBER

CM

1359.

1359.

1359,

1360.

1360.

1360.

1360.

1360.

1360.

1360.

1360.

1360.

1360.

1360.

1361.

1361.

1361.

1361.

1361 .

1361 ,

1361

1361

1361

1362

1362,

1362

1362

1362

1362

1362

;VAC.

.60838

.73075

.76233

.03026

.05556

. 13154

.33688

.43725

.54695

.57956

.60431

.80200

.88446

.95882

. 13883

.25648

.29723

.36785

.53557

.60579

.75505

.89830

.98646

.06611

.10056

.21355

.24160

.51736

.56220

.70484

* * *

*

* *

* *

*

*

* * *

*

* *

*

*

ROTATIONAL

ASSIGNMENT

RO 0(

RO

RO

RO

RO

RO

RO

RO

RO.

RO

RO

RO

K

2(

4(

K

2(

4(

6(

3(

4(

K

3(

5)

5)

5)

5)

6)

6)

6)

6)

7)

7)

8)

8)

BAND

NU2*

NU2

NU2

NU2

NU2

NU2

NU2

NU2

NU2

NU2

NU2

NU2

ISOTOPIC

•SPECIES

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

LINE

NO.

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

WAVENUMBER

_ ̂

CM

1362.

1362.

1362.

1363.

1363.

1363.

1363.

1363.

1363.

1363.

1363.

1363.

1363.

1363.

1363.

1364.

1364.

1364.

1364,

1364,

1364,

1364.

1364.

1364.

1364

1364.

1364,

1364,

1364,

1364, ;VAC.

,76453

.81745

.98311

.12544

.18734

.22972

.32144

.50263

.59317

.65704

.76844

.79059

.81507

.95203

.96510

.05776

.09514

.18331

.22951

.29143

.30665

.42006

.47754

.54576

.58254

.63065

.65749

.73455

.76073

.80056

* * * * * *

*

* *

* * *

*

* * * * * * * * *

ROTATIONAL

ASSIGNMENT

RO

RO

RO

RO

K

3(

4(

6(

9)

9)

9)

9)

RO 0(10)

RO

RO

RO

2(10)

3(10)

6(10)

BAND

NU2

NU 2

NU2

NU2

NU2

NU2

NU2

NU2

ISOTOPIC

SPECIES

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1





639 612

8 % ABSORPTION o 8 X ABSORPTION o % % ABSORPTION o

212

LINE

NO.

61

62

63

64

65

66

67

68

69

70

71

72

73

74

75

76

77

78

79

80

81

82

83

84

85

86

87

WAVENUMBER

_ 1

CM

1364.

1364.

1365.

1365.

1365.

1365.

1365.

1365.

1365.

1365,

1365

1365.

1365.

1365.

1365.

1365.

1365.

1365,

1366.

1366.

1366.

1366.

1366.

1366.

1366

1366

1366

;VAC.

.88356

.96840

.00487

.07172

.21023

.31505

.34915

.39658

.49516

.53133

.57972

.62580

.66391

.74490

.77534

.84317

.95372

.97283

.13200

.15416

.24897

.43596

.45554

.65132

.69823

.72616

.83006

*

*

*

*

*

* *

*

* *

*

*

ROTATIONAL

ASSIGNMENT

RO 0(11)

RO

RO

RO

RO

2(11)

3(11)

4(11)

6(11)

RO 0(12)

RO

RO

PP

RO

RO

RO

RO

PP

RO

2(12)

3(12)

6(25)

4(12)

6(12)

0(13)

1(13)

6(24)

4(13)

BAND

NU2

NU2

NU2

NU2

NU2

NU2

NU2

NU2

NU5

NU2

NU2

NU2

NU2

NU5

NU2

ISOTOPIC

SPECIES

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

- "LINE NO.": serial number identifying the spectral line in


- * : all given lines are selected according to intensity, ha


map on the opposite page,

idth and symmetry criteria.

641 612


212

LINE

WAVENUMBER

-1

NO.

CM

;VAC.

ROTATIONAL

BAND

ISOTOPIC

ASSIGNMENT

SPECIES

1

2

3

4 5

6 7

8 9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

1366.

1366.

1367.

1367.

1367.

1367.

1367.

1367.

1367.

1367.

1367

1367

1367

1368

1368

1368

1368

1368

1368

1368

1368.

1368.

1368.

1369.

1369.

1369.

1369.

1369.

1369.

1369. 90373

99132

20013

21913

27325

47034

53941

68390

72682

82863

.92905

.95624

.97343

.00834

.06214

.10548

.12091

.30229

.31364

.45394

54513

70423

84239

10394

17280

25289

28343

29463

44422

45946

RQ 0(14)

RO 1(14)

RO 2(14)

RO 4(14)

RO 0(15)

RO K15)

PP 6(22)

RO 3(15)

RO 5(15)

RO 0(16)

RO 3(16)

RO 0(17)

RO 1(17)

NU2

CH3 35C1

NU2

CH3 35C1

NU2

CH3 35C1

NU2

CH3 35C1

NU2

CH3 35C1

NU2

CH3 35C1

NU5

CH3 35C1

NU2

CH3 35C1

NU2

CH3 35C1

NU2

CH3 35C1

NU2

CH3 35C1

NU2

CH3 35C1

NU2

CH3 35C1

- ''LINE NO.": serial number identifying the




LINE

NO.

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

WAVENUMBER

_ 1

CM

1369.

1369.

1369.

1369.

1369.

1369.

1369.

1369.

1369.

1369.

1369.

1369.

1370.

1370.

1370.

1370.

1370,

1370.

1371 ,

1371 ,

1371 ,

1371 ,

1371

1371

1371

1371

1371 .

1371 ,

1371 ,

1371

;VAC.

.57084

.59732

.61644

.64832

.67642

.70773

.76591

.90930

.94059

.95212

.98329

.99705

. 17625

.19028

.29074

.35647

.64261

.91313

.00235

.05620

.07508

.18726

.27994

.68106

.70557

.82035

.89699

.92624

.98246

.99824

* *

* * *

* * *

* *

* * *

* * *

* *

ROTATIONAL

ASSIGNMENT

RO

RO

RO

RO

3(17)

4(17)

6(17)

5(17)

RO 0(18)

RO

RO

RO

RO

RO

RO

RO

1(18)

3(18)

1(19)

3(19)

4(19)

5(19)

3(20)

BAND

NU2

NU2

NU2

NU 2

NU2

NU2

NU2

NU2

NU2

NU2

NU2

NU2

ISOTOPIC

SPECIES

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1



identified.

643 612

§ X ABSORPTION o § X ABSORPTION o

I

:3

7-ΰ O o

3 O O

212

LINE

NO.

WAVENUMBER

-1

CM

;VAC.

ROTATIONAL

BAND

ISOTOPIC

ASSIGNMENT

SPECIES

61

62

63

64

65

66

67

68

69

70

71

72

73

74

75

76

1372.

1372.

1372.

1372.

1372.

1372.

1372.

1373.

1373.

1373. 42848

43880

52557

61224

66348

73636

82506

10196

29052

30301

1373.45168

1373.46316

1373.61910

1373.70034

1374.04886

1374.11189

RO 4(21)

NU2

CH3 35C1

PP 6(16)

NU5

CH3 35C1

RO 4(22)

NU2

CH3 35C1

RO 6(23)

NU2

CH3 35C1

RO 5(23)

NU2

CH3 35C1

RO 6(24)

NU2

CH3 35C1





645 612

§ X ABSORPTION o § X ABSORPTION o 8 X ABSORPTION o

2 212

LINE

NO. 1

2 2

3 4 5

6 7

8

9

10

1 1

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

WAVE^

- 1

CM

1374.

1374.

1374.

1374.

1374.

1375.

1375.

1375.

1375.

1375.

1375.

1375.

1375.

1375.

1375.

1375.

1375.

1375.

1376.

1376.

1376.

1376.

1376.

1376.

1376.

1376.

1376.

1376.

1376.

1377. JUMBER

1 ;VAC.

.30444

.42371

.54791

.93063

.97332

. 15335

.19515

.21792

.38215

.42253

.49774

.54708

.57794

.61632

.65484

.79021

.85546

.86757

.09916

.40037

.41315

.43677

.54828

.56825

.59811

.78830

.85271

.88957

.91162

.03935

*

* * * * *

* *

*

* *

* * * *

* * *

* * * *

ROTATIONAL

ASSIGNMENT

RO

OR

RO

PP

RO

RO

RO

PP

RO

2(24)

4(24)

6(26)

6(12)

5(26)

6(27)

0(27)

5(27)

5(28)

BAND

NU 2

NU2

NU2

NU5

NU2

NU2

NU2

NU5

NU2

ISO! rOPIC

SPECIES

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

- "LINE NO.": serial number identifying the




LINE

WAVENUMBER

ROTATIONAL

BAND

ISOTOPIC

-1

NO.

CM

;VAC.

ASSIGNMENT

SPECIES

31

1377.09409 *

32

1377.25833 *

33

1377.38196 *

34

1377.42595 *

35

1377.46112 *

36

1377.58539 *

37

1377.71285

RO 0(29)

NU2

CH3 35C1

38

1377.78842 *

39

1377.82493 *

40

1377.83841 *

41

1377.87750

PP 6( 9)

NU5

CH3 35C1

42

1378.11750 *

43

1378.16272 *

44

1378.19411 *

45

1378.33528 *

46

1378.39736 *

47

1378.79518 *

48

1378.87693 *

49

1378.91029 *

50

1379.05372 *

51

1379.11509 *

52

1379.15943 *

53

1379.35607 *

54

1379.97466 *

55

1380.02858 *

56

1380.25386 *

57

1380.55327 *

58

1380.71380 *

59

1380.76034 *

60

1380.79276 *



ident i fied.

647 612


05 212

LINE WAVENUMBER

ROTATIONAL BAND ISOTOPIC

-1

NO.

CM

;VAC.

ASSIGNMENT

SPECIES

61

1381.05344

62 1381.30034

63 1381.44153





649 612

8 X ABSORPTION o 8 X ABSORPTION o 8 X ABSORPTION o

o

o 212

LINE

WAVENUMBER

-1

ROTATIONAL

BAND

ISOTOPIC

IO.

1

2

3 4 5

6 7 8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

CM

;VAC.

1381.64187

1381.82177

1381.87973

1381.97790

1382.08095

1382.10247

1382.24633

1382.38654

1382.40583

1382.61135

1382.90770

1383.04893

1383.06615

1383.33957

1383.57548

1383.70293

1383.78362

1384.06680

1384.09416

1384.12669

1384.67153

1384.81771

1384.83846

1384.89079

1385.17891

1385.20933

1385.44440

1385.46749

1385.71135

1385.77756

*

*

*

*

* * *

* *

*

* *

*

* * * *

* *

*

*

*

* * * *

ASSIGNMENT

PP

PP

OP

OP

5(20)

5(19)

6( 6)

6( 7)

NU5

NU5

NU5

NU5

SPECIES

CH3 35C1

CH3 35C1

CH3 35C1

CH3 35C1





LINE

NO.

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

WAVENUMBER

_ 1

CM

1385.

1385.

1385.

1385.

1386.

1386.

1386.

1386.

1386.

1386.

1386.

1386,

1387.

1387,

1387

1387,

1387

1388

1388

1388

1388

;VAC.

.82908

.85276

.93652

.97368

.01525

.02886

.12956

.31105

.39785

.61085

.66276

.78322

.29501

.78978

.81584

.91555

.98120

.24131

.26319

.45586

.72724

*

*

*

*

* *

* * *

* *

ROTATIONAL

ASSIGNMENT

OP

OP

OP

OP

PP

OP

PP

OP

OP

PP

6( 8)

6( 9)

6(10)

6(11)

5(14)

6(15)

5(12)

6(25)

6(26)

5(11)

BAND

NU 5

NU5

NU5

NU5

NU5

NU5

NU5

NU 5

NU5

NU5

ISOTOPIC

SPECIES

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

pectra'l line in the map on the opposite page.


identified.

651 612

8 X ABSORPTION o 8 X ABSORPTION o 8 * ABSORPTION o

212

LINE

WAVENUMBER

-1

NO.

CM

;VAC.

ROTATIONAL

BAND

ASSIGNMENT

ISOTOPIC

SPECIES

LINE

WAVENUMBER

-1

NO.

CM

;VAC.

ROTATIONAL

BAND

ISOTOPIC

ASSIGNMENT

SPECIES

1

2

3 4 5

6 7 8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

1388.96811

1389.14045

1389.25275

1389.26712

1389.46003

1389.47815

1389.54546

1389.58923

1389.69205

1389.90880

1390.34964

1390.37022

1390.79806

1391.09021

1391.22262

1391.25406

1391.26953

1391.52483

1391.55744

1391.71519

1391.94888

1392.18216

1392.29856

1392.41802

1392.76249

1392.88439

1392.94243

1393.07669

1393.32019

1393.56623

PP 5(10)

PP 5( 9)

PP 4(23)

PP 4(22)

PP 5( 6)

RP 6( 7)

PP 4(21 )

NU5

CH3 35C1

NU5

CH3 35C1

NU5

CH3 35C1

NU5

CH3 35C1

NU5

CH3 35C1

NU5

CH3 35C1

NU5

CH3 35C1

31

32

33

34

35

36

37

38

39

40

1393.

1393.

1394.

1394.

1395.

1395.

1395.

1395.

1395.

1395. .73671

.85924

.79912

.88967

. 16363

.19472

.43866

.56892

.58140

.85774

*

*

t * * *

PP

PP

RP

PP

5( 5)

4(20)

6( 9)

4(18)

NU5

NU5

NU5

NU5

CH3

CH3

CH3

CH3

35C1

35C1

35C1

35C1





653 612

§ X ABSORPTION o § X ABSORPTION o

3̂ § X ABSORPTION o

13

o

=3

*- ? n< O O cn o

3

212

LINE

NO. 1

2

3 4 5

6 7 8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

WAVEh

-1

CM

1396.

1396.

1396.

1397.

1397.

1397.

1397.

1397.

1397.

1398.

1398.

1398.

1398.

1398.

1398.

1398.

1398.

1398.

1398.

1398.

1398.

1398.

1398.

1398.

1398.

1398.

1399.

1399.

1399.

1399. JUMBER

1 ;VAC.

.23523

.58822

.87013

.00120

.03685

.47022

.55507

.87172

.95585

.14334

.29222

.31517

.34672

.45095

.47505

.52800

.54900

.61090

.62899

.65495

.71507

.80716

.88077

.89330

.90496

.96898

.28371

.56207

.77253

.89702

* *

*

* *

* * *

*

*

*

*

* *

* *

*

*

ROTATIONAL

ASSIGNMENT

PP

PP

OP

OP

OP

OP

OP

PP

OP

OP

OP

PP

4(17)

4(16)

5( 7)

5( 8)

5(10)

5(11)

5(12)

4(14)

5(13)

5( 14)

5(15)

3(28)

BAND

NU5

NU5

NU5

NU5

NU5

NU5

NU5

NU5

NU5

NU5

NU5

NU5

ISOTOPIC

SPECIES

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

LINE

NO.

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

WAVENUMBER

_ 1

CM

1399.

1400.

1400.

1400.

1400.

1400.

1400.

1400.

1400.

1400.

1400.

1400.

1400.

1400.

1400.

1400.

1400.

1400.

1401 .

1401 .

1401 .

1401 ,

1401 .

1401 .

1402.

1402.

1402.

1402.

1402.

1403. ;VAC.

,93669

.02406

.10785

.16012

.17197

.29338

.30987

.32398

.37360

.46424

.48000

.54642

.56565

.63978

.78212

.80309

.91995

.96993

.14011

.24903

.31336

.48960

.54255

.66865

.01025

.03473

.10451

.39208

.88864

.09423

*

* *

*

* *

*

*

*

* * * * * * * *

*

*

ROTATIONAL

ASSIGNMENT

OP

OP

PP

OP

OP

PP

OP

OP

OP

PP

PP

5(24)

5(25)

4(12)

5(26)

5(27)

3(27)

5(28)

5(29)

5(30)

3(25)

3(24)

BAND

NU5

NU5

NU5

NU5

NU5

NU5

NU5

NU5

NU 5

NU5

NU5

ISOTOPIC

SPECIES

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1





655 612


05 212

LINE

NO. 1

2 3

4 5

6 7 8

9

10

1 1

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

WAVENUMBER

_ 1

CM

1403.

1403.

1403.

1403.

1403.

1404.

1404.

1404.

1404.

1404.

1405.

1405.

1405.

1406.

1406.

1406.

1406.

1406.

1406.

1406.

1407.

1407

1407.

1407,

1407

1407.

1407

1407

1407

1408

;VAC.

.53673

.61616

.63313

.67683

.87441

.02660

.46853

.48150

.64428

.65815

.07373

.26408

.82964

.06349

.12624

.23616

.38425

.71572

.86683

.97755

.04382

.05916

.07837

.18374

.33754

.67424

.75858

.82862

.86109

.12603

t *

* *

* * *

*

* *

*

* * * * *

* * * *

ROTATIONAL

ASSIGNMENT

PP

PP

PP

PP

PP

PP

RP

PP

RP

PP

4( 8)

3(23)

3(22)

4( 7)

3(21)

3(20)

5( 8)

3( 19)

5( 9)

3(18)

BAND

NU5

NU5

NU5

NU5

NU5

NU5

NU5

NU5

NU5

NU5

ISOTOPIC

SPECIES

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

LINE

NO.

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

WAVENUMBER

_ 1

CM

1408.

1408.

1408.

1408.

1408.

1409.

1409.

1409.

1410.

1410.

1410.

1410.

1410.

1410.

1410.

1410.

1410. 1 ;VAC.

.24601

.29705

.48569

.63045

.80601

.30129

.31268

.85699

.12109

.22010

.23398

.24586

.38366

.61330

.72468

.76780

.81618

t *

* *

*

*

* *

* *

ROTATIONAL

ASSIGNMENT

PP

PP

PP

PP

OP

OP

OP

3( 17)

3(16)

3(15)

2(30)

4(

4(

4(

7)

8)

9)

BAND

NU5

NU5

NU5

NU5

NU5

NU5

NU5

ISOTOPIC

SPECIES

CH3

CH3

CH3

CH3

CH3

CH3

CH3

35C1

35C1

35C1

35C1

35C1

35C1

35C1





657 612

8 X ABSORPTION o 8 X ABSORPTION o 8 X ABSORPTION o IT

3

i" en oo 212

LINE

NO. 1

2

3

4 5

6 7 8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

WAVENUMBER

-1

CM

;VAC.

1410.86968

1410.92834

1410.94515

1410.99201

1411.04209 *

1411.06037

1411.13413 *

1411.19666 *

1411.21223

1411.28074 *

1411.29547

1411.36892 *

1411.38309

1411.47527

1411.55802 *

1411.57205

1411.65875 *

1411.67273

1411.88711

1411.98354 *

1412.00033

1412.09911 *

1412.11742

1412.21805 *

1412.23834

1412.34029 *

1412.36279

1412.49091

1412.60613

1412.62237

ROTATIONAL

ASSIGNMENT

OP

OP

PP

OP

OP

OP

OP

OP

OP

OP

OP

OP

OP

OP

OP

OP

OP

PP

OP

4(10)

4(11)

3(14)

4(12)

4(13)

4(15)

4(16)

4(17)

4(18)

4(19)

4(20)

4(22)

4(23)

4(24)

4(25)

4(26)

4(27)

3(12)

4(28)

BAND

NU5

NU5

NU5

NU5

NU5

NU5

NU5

NU5

NU5

NU5

NU5

NU5

NU5

NU5

NU5

NU5

NU5

NU5

NU5

ISOTOPIC

SPECIES

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

LINE

NO.

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

WAVENUMBER

-1

CM

;VAC.

1412.69897

1412.75706

1412.89495

1413.03511

1413.13536

1413.18097

1413.32631

1413.38041

1413.44326

1413.47502

1413.52493

1413.78145

1413.82493

1414.09697

1414.17728

1414.25681

1414.35506

1414.70385

1415.13067

1415.18936

1415.92043

1415.98119

1416.02791

1416.17849

1416.23631

1416.59080

1416.73257

1416.78190

1416.83599

1416.88235

*

* * *

*

* * * * *

* * *

* *

* *

*

*

*

*

ROTATIONAL

ASSIGNMENT

OP

OP

PP

PP

PP

PP

PP

PP

PP

4(29)

4(30)

2(26)

3(11)

2(25)

3( 9)

3( 8)

2(22)

3( 7)

BAND

NU5

NU5

NU5

NU5

NU5

NU5

NU 5

NU5

NU5

ISOTOPIC

SPECIES

CH3 35C1

CH3 35C1

CH3 35C1

CH3 35C1

CH3 35C1

CH3 35C1

CH3 35C1

CH3 35C1

CH3 35C1





659 612

§ X ABSORPTION o § X ABSORPTIONo § X ABSORPTION o

3 D D

5 -*^ l

o a —

o

a ! -3 _ω o -* 3D

α * DO 00

O O

J o 212

LINE

WAVENUMBER

ROTATIONAL

BAND

ISOTOPIC

-1

NO.

CM

;VAC.

ASSIGNMENT

SPECIES

61

62

63

64

65

1417,

1417

1417

1417

1417 .40074

.69539

.71785 *

.85940

.97541 *

PP

PP

RP

2(21)

3( 6)

4( 7)

NU5

NU5

NU5

CH3

CH3

CH3

35C1

35C1

35C1





661 612

§ X ABSORPTION o 8 X ABSORPTION o § X ABSORPTION o

O

DO

212

LINE

NO. 1

2

3 4 5

6 7 8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

WAVENUMBER

_ 1

CM

1418.

1418.

1418.

1418.

1418.

1419.

1419.

1419.

1419.

1419.

1419.

1420.

1420.

1420.

1420.

1420.

1421 .

1421 .

1421 .

1422,

1422.

1422,

1422,

1422,

1422,

1422,

1422,

1423,

1423,

1423, ;VAC.

.20028

.21377

,38404

.77615

.79380

,03010

,07067

.21807

.73320

.84973

,98880

.16797

.23997

.28513

.30103

.78657

.26648

.49942

.79773

.29610

.31467

.32946

.36769

.81239

.93419

.95556

.99258

.04297

.10906

. 12517 *

* *

* *

* * *

*

* *

* * *

t * *

*

*

ROTATIONAL

ASSIGNMENT

PP

RP

PP

RP

PP

PP

PP

PP

OP

OP

OP

2(20)

4( 8)

2(19)

4( 9)

2(18)

3( 3)

2(16)

2(15)

3(

3(

3(

4)

6)

8)

BAND

NU5

NU5

NU5

NU5

NU5

NU5

NU5

NU5

NU5

NU5

NU5

ISOTOPIC

SPECIES

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

LINE

NO.

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

WAVENUMBER

_ 1

CM

1423.

1423,

1423.

1423.

1423.

1423.

1423.

1423.

1423.

1423.

1423.

1423.

1423,

1423,

1423,

1423.

1424,

1424,

1424,

1424,

1424.

1424,

1424,

1424,

1424,

1424,

1424

1424,

1424

1424, ;VAC.

. 14918

.19359

.22150

.24225

.25689

.27597

.29510

.39519

.41324

.52956

.60208

.62049

.84000

.86213

.92566

.94993

.00043

.01431

.04122

.23392

.29713

.33510

.39646

.43938

.54667

.60156

.65690

.70689

.76988

.84138

*

* *

*

* *

*

*

*

*

*

*

*

ROT/ \TIONAL

ASSIGNMENT

OP

OP

OP

OP

OP

OP

OP

OP

PP

OP

OP

OP

OP

OP

OP

OP

PP

3( 9)

3(10)

3(11)

3(12)

3(14)

3(17)

3(20)

3(21)

2(13)

3(22)

3(24)

3(25)

3(26)

3(27)

3(28)

3(29)

2(12)

BAND

NU5

NU5

NU5

NU5

NU5

NU5

NU5

NU5

NU5

NU5

NU5

NU5

NU5

NU5

NU5

NU5

NU5

ISOTOPIC

SPECIES

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1





663 612


212

LINE

NO.

61

62

63

64

65

66

67

68

WAVENUMBER

_ 1

CM

1424,

1425.

1425.

1425.

1425.

1425.

1425.

1425. ;VAC.

.92170

. 12424

. 15424

.24746

.35714

.37204

.40797

.49905

ROTATIONAL

BAND

ISOTOPIC

ASSIGNMENT

SPECIES





665 612


(NO 00

o cn

212

INE

WAVENUMBER

-1

NO.

CM

;VAC.

ROTATIONAL

BAND

ISOTOPIC

ASSIGNMENT

SPECIES

LINE

WAVENUMBER

-1

NO.

CM

;VAC.

ROTATIONAL

BAND

ISOTOPIC

ASSIGNMENT

SPECIES

1

2

3

4 5

6 7 8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

1425.77366

1425.87530

1426.06589

1427.06826

1427.38655

1427.41990

1427.49898

1427.74462

1428.03136

1428.24255

1428.29917

1428.36160

1428.40057

1428.54884

1429.05559

1429.10235

1429.12137

1429.27931

1429.38529

1429.41452

1429.60137

1430.00023

1430.10169

1430.20134

1430.24920

1430.37394

1430.77982

1430.83343

1431.08461

1431.12760

* *

*

* *

*

*

* * *

*

*

*

*

*

* *

*

*

PP

PP

PP

PP

RP

PP

PP

PP

PP

PP

RP

1(25)

2( 9)

1(23)

2( 8)

3( 5)

2( 7)

K21)

1(20)

2( 5)

1(19)

3( 8)

NU5

NU5

NU5

NU5

NU5

NU5

NU5

NU5

NU5

NU5

NU5

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

31

32

33

34

35

36

37

38

39

1431

1431

1431 .

1431 ,

1432

1432

1432

1432

1432 .20986 *

.36643 *

.85311 *

.92110

.05805

.15092 *

.27848 *

.36259 *

.75938

PP

RP

PP

1(18)

3( 9)

1(17)

NU5

CH3 35C1

NU5

CH3 35C1

NU5

CH3 35C1



- * : all given lines are selected according to intensity, halfwidth and symmetry criteria,

ines with an asterisk (*) are selected but not identified.

612


-3 O

00

o o

oo 212

LINE

WAVENUMBER

-1

NO.

CM

;VAC.

ROTATIONAL

BAND

ISOTOPIC

ASSIGNMENT

SPECIES

LINE

WAVENUMBER

-1

NO.

CM

;VAC.

ROTATIONAL

BAND

ISOTOPIC

ASSIGNMENT

SPECIES

1

2

3 4 5

6 7 8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

1432.

1432.

1433.

1433.

1433.

1433.

1433.

1434.

1434.

1434.

1434.

1435.

1435.

1435.

1435.

1435.

1435.

1435.

1435.

1435.

1435.

1435.

1435.

1435.

1435.

1435.

1435.

1436.

1436.

1436. .84342

.99255

.09079

.36231

.69388

.88592

.93114

.24280

.36545

.44181

.94978

.22053

.23904

.30920

.39952

.41167

.43704

.45159

.47821

.49436

.52294

.57113

.58792

.67759

.69089

.82026

.91568

.02920

.14983

.30997

* *

* * * *

* * *

* *

t *

*

*

* * * *

PP

OP

OP

OP

OP

OP

OP

OP

OP

OP

OP

1(15)

2( 2)

2( 6)

2( 9)

2(10)

2(11)

2(12)

2(13)

2(15)

2(22)

2(24)

NU5

NU5

NU5

NU5

NU5

NU5

NU5

NU5

NU5

NU5

NU5

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

1436.39349

1436.56488

1436.94193

1437.10013

1437.13288

1437.19418

1437.32462

1437.39393

1437.41930

1437.51141

1437.60026

1437.68415

1437.72461

1438.09830

1438.40930

1438.55881

1439.42742

1439.55017

1439.69139

1439.71938

OP 2(25)

OP 2(27)

NU5

CH3 35C1

NU5

CH3 35C1

PR 0(26)

PP 1( 9)

NU5

CH3 35C1

NU5

CH3 35C1





669 612


212

LINE

NO. 1

2

3 4 5

6 7 8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

WAVENUMBER

-1

CM ;VAC.

1440.20137

1440.24960

1440.41169

1440.78507

1440.93925

1441.19931

1441.27630

1441.47150

1441.57654

1441.68267

1441.74258

1442.29479

1442.43134

1442.49706

1442.54801

1442.85165

1443.01479

1443.05778

1443.06880

1443.10746

1443.12624

1443.18558

1443.37853

1443.52299

1443.82580

1443.88880

1443.94545

1444.06561

1444.10331

1444.30215

* *

*

*

* *

* *

*

* * *

* * * *

*

*

* * *

ROTATIONAL

ASSIGNMENT

PP

PR

PP

PR

PP

RP

PR

PP

RP

K 8)

0(23)

K 7)

0(21)

K 5)

2( 8)

0(19)

K 4)

2( 9)

BAND

NU5

NU5

NU5

NU5

NU5

NU5

NU5

NU5

NU5

ISOTOPIC

SPECIES

CH3 35C1

CH3 35C1

CH3 35C1

CH3 35C1

CH3 35C1

CH3 35C1

CH3 35C1

CH3 35C1

CH3 35C1

LINE WAVENUMBER

-1

NO.

CM ;VAC.

ROTATIONAL

BAND

ISOTOPIC

ASSIGNMENT

SPECIES

31

32

33

34

35

36

37

38

39

40

1444

1444

1444.

1444.

1444.

1445.

1445.

1446.

1446.

1446. .50029

.55449

.59902

.68984

.76597

.22937

.37752

.16064

.53006

.61939

* *

*

*

*

PR

PP

PR

PR

PP

0(18)

M 3)

0(17)

0(16)

K 1)

NU5

NU5

NU5

NU5

NU5

CH3

CH3

CH3

CH3

CH3

35C1

35C1

35C1

35C1

35C1

41

1447.04041 *

42 1447.06122 *

43

1447.09351 *

44 1447.48319

OP K 6)

NU5 CH3 35C1





671 612

§ X ABSORPTION o g X ABSORPTION o g X ABSORPTION o

212

LINE

NO. 1

2

3 4 5

6 7 8

9

10

1 1

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

WAVENUMBER

-1

CM

;VAC.

1447.52952

1447.66773

1447.69496

1447.71346

1447.77833

1448.01487

1448.03057

1448.04234

1448.06367

1448.08418

1448.38254

1448.43970

1448.53401

1448.54500

1448.77599

1448.94632

1448.97086

1449.12292

1449.35051

1449.59899

1449.72805

1449.86234

1449.98544

1450.02147

1450.22812

1450.27133

1450.35794

1450.37399

1450.42484

1450.44713

*

*

*

*

* * *

* * * * *

* * *

*

* *

ROTATIONAL

ASSIGNMENT

OP

OP

OP

OP

OP

OP

PR

OP

OP

PR

OP

OP

K

8)

1(13)

1(15)

1(20)

1(21)

K30)

0(13)

K37)

1(32)

1(25)

1(42)

1(43)

BAND

NU5

NU5

NU5

NU5

NU5

NU5

NU5

NU5

NU5

NU5

NU5

NU5

ISOTOPIC

SPECIES

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

LINE

NO.

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

WAVENUMBER

-1

CM

;VAC.

1450.52203

1450.86023

1451.08189

1451.28691

1451.42085

1451.85763

1452.37396

1452.41900

1452.62984

1452.68163

1452.76126

1452.78195

1453.41904

1453.46501

1453.51161

1453.53462

1453.62530

1453.75638

1454.22904

1454.30663

1454.34769

1454.35872

1454.62272

1454.67302

1454.73076

* *

*

* * * *

* * * *

*

* *

*

*

* *

ROTATIONAL

ASSIGNMENT

PR

PR

PR

PR

PR

PR

RP

1(24)

0( 8)

0( 7)

1(21)

0( 6)

1(20)

K

7)

BAND

NU5

NU5

NU5

NU5

NU5

NU5

NU5

ISOTOPIC

SPECIES

CH3 35C1

CH3 35C1

CH3 35C1

CH3 35C1

CH3 35C1

CH3 35C1

CH3 35C1





673 612

§ X ABSORPTION o g X ABSORPTION o § X ABSORPTION o

212

LINE

WAVENUMBER

ROTATIONAL

BAND

ISOTOPIC

-1

NO.

CM

;VAC.

ASSIGNMENT

SPECIES

1

2

3 4 5

6 7 8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

1455.

1455.

1455.

1455.

1456.

1456.

1456.

1456.

1457.

1457.

1457.

1457.

1457.

1457.

1457.

1457.

1458.

1458.

1458.

1458.

1459.

1459.

1459.

1459.

1459.

1459.

1459.

1459.

1459.

1459. .44142

.53664

.63269

.70453

.03834

.08196

.23452

.45315

.20961

.26915

.37237

.43578

.55865

.68786

.88330

.92334

.01164

.18703

.81689

.83472

.10747

.37167

.64848

.66587

.67488

.68416

.69359

.70328

.72310

.73383

*

*

* * * *

* * * *

*

* * * * * * *

RP

RP

PR

PR

OR

OR

OR

OR

OR

OR

OR

OR

K

8)

K

9)

1(16)

1(14)

0(33)

0(35)

0(36)

0(37)

0(38)

0(39)

0(41)

0(42)

NU5

NU5

NU5

NU5

NU5

NU5

NU5

NU5

NU5

NU5

NU5

NU5

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1





LINE

WAVENUMBER

ROTATIONAL

BAND

-1

NO.

CM

;VAC.

ASSIGNMENT

31

32

33

34

35

36

37

38

39

40

41

42

43

44

1459.

1459

1459,

1459.

1459.

1460.

1460.

1460.

1461 .

1461 .

1461 .

1461 .

1461 .

1462. .75436

.76506

.77607

.78730

.79873

.03033 *

.21833

.40546

.21753 *

.30812

.49471 *

.88326 *

.92119

.00180 *

OR

OR

OR

OR

OR

PR

RR

RR

PR

0(44)

0(45)

0(46)

0(47)

0(48)

1(13)

0( 0)

0( 1)

1(11)

NU5

NU 5

NU5

NU5

NU 5

NU5

NU5

NU5

NU5



ident i fied.

675

ISOTOPIC

SPECIES

CH3 35C1

CH3 35C1

CH3 35C1

CH3 35C1

CH3 35C1

CH3 35C1

CH3 35C1

CH3 35C1

CH3 35C1

612

ABSORPTION

σ> 212

INE

NO. 1

2

3 4 5

6 7

8

9

10

1 1

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

WAVENUMBER

-1

CM

;VAC.

1462.38276

1462.77730

1462.81311

1462.88579

1462.93298

1463.04776

1463.13599

1463.38546

1463.63655

1463.86527

1464.06067

1464.09259

1464.35928

1464.53359

1464.67929

1464.99206

1465.36306

1465.61553

1465.68256

1465.77682

1465.92987

1466.23288

1466.30885

1466.48133

1466.55377

1466.66395

1466.69832

1466.87376

1467.02722

1467.49396

*

*

*

*

*

*

* *

*

*

*

*

*

* *

* *

*

* *

*

ROTATIONAL

ASSIGNMENT

PR

RR

PR

RP

RR

RR

PR

RR

RR

1(10)

0(

K

3)

9)

1(17)

0(

0(

K

0(

0(

4)

5)

7)

6)

7)

BAND

NU5

NU5

NU5

NU5

NU5

NU5

NU5

NU5

NU5

ISOTOPIC

SPECIES

CH3 35C1

CH3 35C1

CH3 35C1

CH3 35C1

CH3 35C1

CH3 35C1

CH3 35C1

CH3 35C1

CH3 35C1

LINE

NO.

31

32

33

34

35

36

37

38

39

40

WAVENUMBER

_ 1

CM

;VAC.

1467.59514

1467.62570

1467.82348

1467.86408

1468.08724

1468.25730

1468.55880

1468.89425

1469.22939

1469.38002

* *

* *

* *

* * *

ROTATIONA

ASSIGNMEN

RR 0( 8)

SPECIES

NU5

CH3 35C1





612


212

LINE

NO.

WAVENUMBER

-1

CM

;VAC.

ROTATIONAL

BAND

ISOTOPIC

LINE

ASSIGNMENT

SPECIES

NO.

WAVENUMBER

-1

CM

;VAC.

ROTATIONAL

BAND

ISOTOPIC

ASSIGNMENT

SPECIES

1

2

3 4 5

6 7 8

9

10

1 1

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

1469.

1469.

1469.

1469.

1469.

1470.

1470.

1470.

1470.

1470.

1470.

1471 .

1471 .

1471 .

1471 .

1471 .

1471 .

1471 .

1471 .

1471 .

1471 .

1471 .

1471 .

1471 .

1471 .

1471 .

1471 .

1471 .

1471 .

1471 . 49766

54655

70379

73960

76097

19861

32551

36454

39204

51625

70565

16416

33136

39193

61588

63175

64280

66000

69101

72499

74149

76176

78014

80137

82190

84382

86664

88915

91437

93731

RR 0(10)

NU5

CH3 35C1

RR 0(11)

OR K

8)

OR 1( 9)

OR 1(12)

OR 1(13)

OR 1(14)

OR 1(15)

NU5

CH3 35C1

NU5

CH3 35C1

NU5

CH3 35C1

NU5

CH3 35C1

NU5

CH3 35C1

NU5

CH3 35C1

NU5

CH3 35C1

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

1471 .

1472.

1472.

1472.

1472.

1472.

1472.

1472.

1472.

1472.

1472.

1472.

1472.

1472.

1472.

1472.

1472.

1472.

1472.

1472.

1473.

1473.

1473.

1473.

1473.

1473.

1473.

1473.

1474

1474, .96505

. 13483

. 14856 *

.15957 *

. 19747

,22151 *

.33156

.40308

.42644 *

.47765

.57767 *

.63570 *

.71921 *

.74068 *

.80580 *

.89525 *

.91539 *

.94532

.96876 *

.98794 *

.00725 *

.25932 *

.38871 *

.60742 *

.63427

.72131 *

.79162 *

.95743 *

.01593 *

.12518 *

OR 1(17)

OR 1(20)

OR K21)

OR 1(23)

OR K24)

OR K25)

NU5

NU5

CH3 35C1

CH3 35C1

NU5

CH3 35C1

NU5

CH3 35C1

NU5

CH3 35C1

NU5

CH3 35C1

PR 2(12)

NU5

CH3 35C1

RR 0(14)

NU5

CH? 35C1





679 612


CO O 212

LINE

WAVENUMBER

-1

NO.

CM

;VAC.

ROTATIONAL

BAND

ISOTOPIC

ASSIGNMENT

SPECIES

61

62

63

64

65

66

67

68

69

70

71

72

73

74

1474.14094

1474.18651

1474.27430

1474.64178

1474.94046

1475.02557

1475.44532

1475.61122

1475.98677

1476.22205

1476.27615

1476.57699

1476.60696

1476.80232

*

* * *

* *

* *

*

*

RR

RR

RR

RR

K

2)

0(16)

H

4)

0(17)

NU5

CH3 35C1

NU5

CH3 35C1

NU5

CH3 35C1

NU5

CH3 35C1





681 612

§ X ABSORPTION c § X ABSORPTION o § X ABSORPTION o

CD 212

INE

NO. 1

2

3 4 5

6 7

8

9

10

1 1

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

WAVENUMBER

-1

CM ;VAC.

1476.89131

1477.10959

1477.20354

1477.58371

1477.60729

1477.79870

1478.19000

1478.61230

1478.70901

1478.78427

1479.11640

1479.18138

1479.48825

1479.87928

1479.96230

1480.17757

1480.38899

1480.63622

1480.71146

1481.17841

1481.29247

1481.45704

1481.65495

1481.75041

1482.16513

1482.19858

1483.10732

1483.19380

1483.30317

1483.64804

* *

* *

*

* * * *

*

*

*

* * * * *

* * *

* * *

ROTATIONAL

ASSIGNMENT

RR

RR

RR

RR

RR

RR

OR

1( 5)

K 6)

0(19)

K 7)

1(10)

1(12)

2(13)

BAND

ISOTOPIC

SPECIES

NU5 CH3 35C1

NU5 CH3 35C1

NU5 CH3 35C1

NU5 CH3 35C1

NU5 CH3 35C1

NU5 CH3 35C1

NU5 CH3 35C1

LINE WAVENUMBER

-1

NO.

CM ;VAC.

ROTATIONAL BAND

ISOTOPIC

ASSIGNMENT

SPECIES

31

32

33

34

35

36

37

38

39

40

1483,

1483,

1483

1483,

1483

1484,

1484.

1484,

1484,

1484. .70584

.87100

.89740

.90893

.96145

.00066

.01716

.07424

. 11365

. 13442 * * *

*

*

OR

OR

OR

OR

OR

2(19)

2(20)

2(21)

2(22)

2(23)

NU5

NU5

NU5

NU5

NU5

CH3

CH3

CH3

CH3

CH3

35C1

35C1

35C1

35C1

35C1




Ines with an asterisk (*) are selected but not identified.

612

Noiiddosav x §

212

LINE

NO. 1

2

3 4 5

6 7 8

9

10

1 1

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

WAVENUMBER

-1

CM

;VAC.

1484.17391

1484.19725

1484.20824

1484.26254

1484.30165

1484.33039

1484.36931

1484.40078

1484.43940

1484.47366

1484.51266

1484.58666

1484.62702

1484.70739

1484.79028

1484.93298

1485.05369

1485.14639

1485.16037

1485.22705

1485.24153

1485.33905

1485.38751

1485.43907

1485.54145

1485.58727

1485.64605

1485.77394

1485.84972

1486.05176

*

*

*

*

*

*

*

*

*

*

*

*

*

*

* *

* *

*

*

* *

ROTATIONAL

ASSIGNMENT

OR

OR

OR

OR

OR

OR

RR

PR

2(24)

2(25)

2(26)

2(27)

2(28)

2(30)

1(14)

3(11)

BAND

ISOTOPIC

SPECIES

NU5

CH3 35C1

NU5

CH3 35C1

NU5

CH3 35C1

NU5

CH3 35C1

NU5

CH3 35C1

NU5

CH3 35C1

NU5

CH3 35C1

NU5

CH3 35C1

LINE

NO.

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

WAVENUMBER

-1

CM

;VAC.

1486.23464

1486.25014

1486.81437

1486.93493

1486.98073

1487.27742

1487.69111

1487.82050

1487.85899

1487.88060

1488.18056

1488.30905

1488.61579

1488.75604

1488.78304

1488.90775

1489.54319

1489.59873

1489.68804

1489.96036

1490.38335

1490.47291

1490.49207

1490.59550

1491.01702

1491.40537

ROTATIONAL

BAND

ISOTOPIC

ASSIGNMENT

SPECIES

RR 2( 3)

RR 2( 4)

PR 3( 8)

RR 2( 5)

RR 1(18)

RR 2( 6)

RR 2( 7)

NU5

CH3 35C1

NU5

CH3 35C1

NU5

CH3 35C1

NU5

CH3 35C1

NU5

CH3 35C1

NU5

CH3 35C1

NU5

CH3 35C1

- "LINE NO.·": serial number identifying the spectral line in the map on the opposite page.




685 612

οο 05 212

LINE

NO. 1

2

3 4 5

6 7 8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

WAVENUMBER

_ 1

CM

1491

1491 .

1492.

1492.

1492.

1492.

1492.

1492.

1493.

1493.

1493.

1493.

1493.

1493.

1493.

1494.

1494.

1494,

1494.

1494.

1494.

1495.

1495.

1495.

1495.

1495.

1495

1495.

1495.

1495. ;VAC.

.50562

.74674

.07753

.13611

.28521

.34042

.41815

.69846

.14183

.18530

.27799

.33324

.52365

.65271

.83878

.08788

.25072

.57764

.60969

.69373

.99276

.17068

.22967

.24163

.31319

.38087

.39268

.40847

.42377

.43831

*

* *

*

*

*

*

*

*

*

*

*

*

*

*

*

ROTATIONAL

ASSIGNMENT

RR

RR

RR

RR

RR

RR

RR

RR

RR

OR

OR

OR

OR

OR

2( 8)

1(21)

2( 9)

1(22)

2(10)

1(23)

2(11)

1(24)

2(12)

3( 4)

3( 5)

3( 9)

3(12)

3(13)

BAND

NU5

NU5

NU5

NU5

NU5

NU5

NU5

NU 5

NU5

NU5

NU5

NU5

NU5

NU5

ISOTOPIC

SPECIES

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

LINE

NO.

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

WAVENUMBER

-1

CM

;VAC.

ROTATIONAL

BAND

ISOTOPIC

ASSIGNMENT

SPECIES

1495.

1495.

1495.

1495.

1495.

1495.

1495.

1496.

1496.

1496.

1496.

1496.

1496.

1496.

1496.

1496.

1496.

1496.

1496.

1496.

1496.

1496.

1496.

1496.

1496.

1497.

1497.

1497.

1497.

1497. 45725

47045

49312

50489

53135

75786

80954

09299

10534

12958

17105

35746

38206

45684

53261

65937

69457

73963

77769

80973

82187

86315

90623

95084

96241

01784

04060

05409

13249

22633

OR 3(14)

OR 3(15)

OR 3(16)

OR 3(21)

OR 3(22)

RR 2(13)

OR 3(27)

OR 3(28)

RR 2(14)

NU5

NU5

NU5

NU5

NU5

NU5

NU5

CH3 35C1

CH3 35C1

CH3 35C1

CH3 35C1

CH3 35C1

CH3 35C1

CH3 35C1

NU5

CH3 35C1

NU5

CH3 35C1





687 612

ABSORPTION X ABSORPTION o § X ABSORPTION o

oo

o en

s oo

212

LINE

NO.

61

62

63

64

65

66

67

68

69

WAVENUMBER

_ 1

CM

1497.

1497

1497

1497,

1497

1497.

1498.

1498.

1498. ; VAC.

.42029

.43519

.49636

.52036

.62250

.79770

.46380

.51721

.63518

*

* *

* * * * * *

ROTATIONAL

BAND

ISOTOPIC

ASSIGNMENT

SPECIES





689 612

§ X ABSORPTION o

o o

212

LINE

NO. 1

2

3 4 5

6 7 8

9

10

1 1

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

WAVENUMBER

-1

CM

;VAC.

1498.95734

1499.43385

1499.55161

1499.60240

1499.62842

1499.67477

1499.80642

1499.91286

1500.31592

1500.40654

1500.47014

1500.51505

1500.57564

1500.69071

1500.74067

1500.87074

1501.15992

1501.40391

1501.47882

1501.67718

1501.78224

1502.31384

1502.35957

1502.38430

1502.61600

1502.87663

1503.18817

1503.23908

1503.29202

1503.33990

*

* *

* *

* * * * *

*

* * *

* * *

* * *

*

ROTATIONAL

ASSIGNMENT

RR

RR

RR

RR

RR

RR

RR

RR

RR

3( 4)

2(17)

3( 5)

2(18)

3( 6)

2(19)

3( 7)

2(20)

3( 8)

BAND

NU5

NU5

NU5

NU5

NU5

NU5

NU5

NU5

NU5

ISOTOPIC

SPECIES

ÖH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

LINE

NO*.

31

32

33

34

35

36

37

38

39

40

41

42

43

44

WAVENUMBER

-1

CM

;VAC.

1503.55708

1503.70440

1503.75952

1503.97425

1504.08360

1504.32285

1504.50044

1504.98110

1505.09582

1505.11428

1505.30838

1505.44588

1505.88081

1505.89837

* * *

t *

*

t *

* *

ROTATIONAL

ASSIGNMENT

RR

RR

RR

RR

2(21 )

2(22)

3( 10)

2(23)

BAND

NU5

NU5

NU5

NU5

ISOTOPIC

SPECIES

CH3 35C1

CH3 35C1

CH3 35C1

CH3 35C1





691 612

05 CO 212

LINE

WAVENUMBER

-1

NO.

CM

;VAC.

ROTATIONAL

BAND

ISOTOPIC

ASSIGNMENT

SPECIES

LINE

WAVENUMBER

-1

NO.

CM

;VAC.

ROTATIONAL

BAND

ISOTOPIC

ASSIGNMENT

SPECIES

1

2

3 4 5 6 7 8

9

10

1 1

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

1506.

1506.

1506.

1506.

1506.

1506.

1507.

1507.

1507.

1507.

1507.

1507.

1507.

1507.

1507.

1507.

1507.

1508.

1508.

1508.

1508.

1508.

1508.

1509.

1509.

1509.

1510.

1510.

1510.

1510. .17701

.26854

.29627

.39363

.78261

.94560

.12906

.25641

.27077

.31069

.33163

.39475

.41351

.53387

.68648

.86427

.94199

.20958

.43550

.67968

.78519

.83456

.85226

.24973

.27530

.70841

.08037

.20599

.27329

.63371

* * *

*

*

*

* * *

* *

*

*

*

*

RR

OR

OR

OR

OR

OR

RR

OR

OR

RR

PR

RR

RR

RR

RR

2(24)

4( 6)

4(14)

4(18)

4(19)

4(21)

3(13)

4(30)

4(34)

3(14)

5(11)

2(27)

3(15)

2(28)

3(16)

NU5

NU5

NU5

NU5

NU5

NU5

NU5

NU5

NU5

NU5

NU5

NU5

NU5

NU5

NU5

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

1510.

151 1 .

151 1 .

151 1 .

1511 .

1511 .

151 1 .

1512.

1512.

1512.

1513.

1513.

1513.

1513.

1513.

1513.

1513. .71620

.16431

.32259

.36613

.56105

.66002

.76749

.12471

.23671

.49049

.08715

.10612

. 15274

. 16731

.28194

.42203

.46293

*

*

* *

*

*

* *

*

*

RR

RR

RR

RR

RR

RR

RR

2(29)

4( 4)

3(17)

2(30)

3(18)

4( 6)

3(19)

NU5

NU5

NU5

NU5

NU5

NU5

NU5

CH3

CH3

CH3

CH3

CH3

CH3

CH3

35C1

35C1

35C1

35C1

35C1

35C1

35C1




Lines with an asterisk (*) are selected.but not identified.

693 612

§ X ABSORPTION o § X ABSORPTION o g X ABSORPTION o

DO JO

00

O

212

LINE

NO. 1

2

3 4 5

6 7 8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

WAVENUMBER

_ f

CM

1513.

1514.

1514.

1514.

1514.

1514.

1515.

1515.

1515.

1516.

1516.

1516.

1517.

1517.

1517.

1517.

1518.

1518.

1518.

1518.

1518.

1518.

1518.

1518.

1518.

1518.

1518,

1519.

1519.

1519, ;VAC.

,99551

.05164

,07091

,31382

,35557

,88692

.16667

,88453

,91257

.22866

.79431

.95672

.16812

.57245

.70603

.92893

.10953

.54603

.58030

.64656

.68971

.70070

.71573

.73072

.74270

.86973

.99436

.02494

.03955

.05291

* *

*

*

*

*

*

*

*

*

*

*

*

ROTATIONAL

ASSIGNMENT

RR

RR

RR

RR

RR

RR

RR

RR

OR

OR

OR

OR

OR

OR

OR

OR

RR

4( 7)

3(20)

4( 9)

3(22)

4( 10)

3(23)

4(11)

3(24)

5( 7)

5( 9)

5(12)

5(14)

5(15)

5(19)

5(22)

5(23)

3(25)

BAND

NU5

NU5

NU5

NU5

NU5

NU5

NU5

NU5

NU5

NU5

NU5

NU5

NU5

NU5

NU5

NU5

NU5

ISOTOPIC

SPECIES

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

LINE

WAVENUMBER

-1

NO.

CM

;VAC.

ROTATIONAL

BAND

ISOTOPIC

ASSIGNMENT

SPECIES

31

32

33

34

35

36

37

38

39

40

41

42

1519.

1519.

1519.

1519.

1519.

1519.

1519.

1519.

1519.

1519.

1520.

1520. .08668

. 11375

.13551

.16064

.18623

.29291

.40642

.61857

.78604

.87901

.45271

.54952

*

* * * * * * *

*

OR

OR

RR

5(24)

5(25)

4(14)

NU5

NU5

NU5

CH3

CH3

CH3

35C1

35C1

35C1





695 612


212

INE

NO. 1

2

3 4 5

6 7 8

9

10

1 1

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

WAVENUMBER

_ -1

CM

1520.

1520.

1521 .

1521 .

1522.

1522.

1522.

1522.

1522.

1522.

1523.

1523.

1523.

1524.

1524.

J524.

1525.

1525.

1525.

1525.

1525,

1526,

1526

1526

1526

1526

1527

1527

1527

1527

;VAC.

.85675

.94522

.37188

.89409

.08492

.29282

.41695

.81764

.84484

.99252

.21534

.35322

.85029

.13940

.70315

.75110

.23076

.59104

.70759

.72304

.99085

. 17212

.55688

.63460

.66521

.91703

.11484

.46273

.62457

.84164

*

*

* *

* *

*

*

*

*

* *

*

* *

*

*

ROTATIONAL

ASSIGNMENT

RR

RR

RR

RR

RR

RR

RR

RR

RR

RR

RR

RR

RR

3(27)

4(15)

3(28)

4(16)

4(17)

5( 5)

4(18)

5( 6)

4(20)

5( 8)

4(21)

5( 9)

4(22)

BAND

NU5

NU5

NU 5

NU5

NU5

NU5

NU5

NU5

NU5

NU5

NU5

NU5

NU5

ISOTOPIC

SPECIES

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

LINE

WAVE NUMBER

-1

NO.

CM

;VAC.

31

1528.05930

ROTATIONAL

BAND

ISOTOPIC

ASSIGNMENT

SPECIES





697 612


oo 212

LINE

NO. 1

2

3 4 5

6 7

8

9

10

1 1

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

WAVENUMBER

_ 1

CM

1528.

1528.

1528.

1528.

1529.

1529.

1529.

1529.

1529.

1530.

1530.

1530.

1530.

1530.

1530.

1530.

1530.

1530.

1530.

1530.

1530.

1530.

1530.

1530.

1530.

1530.

1530.

1530.

1530.

1530. ;VAC.

.26557

.37053

.45217

.75951

.00538

.16062

.34368

.54817

.65026

.03736

.07266

.11523

.15200

.22212

.28668

.32151

.33789

.35807

.37144

.39648

.66264

.69917

.71288

.74748

.76472

.81829

.83426

.84888

.87347

.90189

*

*

*

* * *

*

*

*

* * *

+ * * * * *

*

ROTATIONAL

ASSIGNMENT

RR

RR

RR

OR

OR

OR

OR

OR

OR

OR

OR

5(10)

4(23)

4(24)

6( 8)

6(10)

6(12)

6(16)

6(18)

6(19)

6(20)

6(21)

BAND

NU5

NU5

NU5

NU5

NU5

NU5

NU5

NU5

NU5

NU5

NU5

ISOTOPIC

SPECIES

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

LINE

NO.

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

WAVENUMBER

_ 1

CM

1530

1530

1531

1531

1531

1531

1531

1531

1531

1531

1532

1532

1532

1532,

1532

1533

1533

1534

1534

1534

1534

1535

;VAC.

.93019

.98847

.04834

.17268

.30286

.34770

.37005

.47795

.58054

.68930

.01964

.44511

.60469

.75780

.93627

.53636

.66115

.38407

.47468

.56622

.77468

.41708

* * * *

* * * * *

*

*

*

* *

*

ROTATIONAL

ASSIGNMENT

RR

RR

RR

RR

RR

RR

RR

5(14)

4(27)

5(15)

4(28)

4(29)

5(17)

4(30)

BAND

NU5

NU5

NU5

NU5

NU5

NU5

NU5

ISOTOPIC

SPECIES

CH3

CH3

CH3

CH3

CH3

CH3

CH3

35C1

35C1

35C1

35C1

35C1

35C1

35C1





699 612

8 X ABSORPTION o 8 X ABSORPTION o 8 * ABSORPTION o

3D JD

O O

cn

s 212

INE

NO. 1

2

3 4 5

6 7 8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

WAVENUMBER

-1

CM

;VAC.

1535.69637

1536.19221

1536.22599

1536.32869

1536.36214

1536.38118

1537.12679

1537.29099

1537.54463

1537.96698

1538.02931

1538.47108

1538.85688

1538.93357

1539.39913

1539.74833

1539.83947

1540.02911

1540.16278

1540.64141

1540.74707

1540.94470

1541.11703

1541.25968

1541.45396

1541.47462

1541.54630

1541.60247

1541.69904

1541.77179

*

*

*

*

*

*

*

*

* *

*

*

*

* *

ROTATIONAL

ASSIGNMENT

RR

RR

RR

RR

RR

RR

RR

RR

RR

RR

RR

OR

OR

OR

OR

5(18)

6( 6)

4(31)

6( 7)

5(20)

6( 8)

5(21)

5(22)

6(10)

6(11)

5(24)

7(11)

7(12)

7(15)

7(17)

BAND

NU5

NU5

NU5

NU 5

NU5

NU5

NU5

NU5

NU5

NU 5

NU5

NU5

NU5

NU5

NU5

ISOTOPIC

SPECIES

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

LINE

NO.

31

32

33

WAVENUMBER

-1

CM

;VAC.

1541.81051

1541.85078

1542.33823

ROTATIONAL

BAND

ISOTOPIC

ASSIGNMENT

SPECIES





612

ä 212

LINE

WAVENUMBER

-1

NO.

CM

;VAC

ROTATIONAL

BAND

ISOTOPIC

ASSIGNMENT

SPECIES

1

2 3

4 5

6 7 8

9

10

11

12

13

14

15

16

17

18

19

1543.

1543.

1543.

1544.

1544.

1544.

1544.

1545.

1546.

1546.

1546.

1547.

1547.

1548.

1548.

1548.

1548.

1549.

1549. . 12599

.33024

.69966

.06116

.22947

.39373

.99774

.93551

.22652

.87408

.93628

. 14519

.81481

.06538

.45598

.49045

.98700

.39152

.91005

* * * * *

* *

*

*

*

*

RR

RR

RR

RR

RR

RR

RR

RR

6(15)

6(17)

6(18)

6(19)

7( 7)

6(20)

7( 8)

6(21)

NU5

NU5

NU5

NU5

NU5

NU5

NU5

NU5

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1







identified.

703 612

§ % ABSORPTION o § % ABSORPTION o 8 * ABSORPTION o

S 212

LINE

NO. 1

2

3

4 5

6 7 8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

WAVENUMBER

_ 1

CM

1550.

1550.

1550.

1550.

1551 .

1551.

1551 .

1551 .

1552.

1552.

1552.

1552.

1552.

1552.

1552.

1552.

1552.

1552.

1553.

1553.

1553.

1553.

1553,

1554.

1554

1554.

1555.

1555.

1555.

1556, ;VAC.

.29423

.56533 *

.64185 *

.83454

.12111 *

. 19841

.58609 *

.76040

.01251 *

.10426

.53127 *

.68735

.70258

.72167

.74228

.78839

.86925

.93004

.07082

.19136

.30076 *

.61614

.92021

.54597 *

.69507 *

.83054

.13123 *

.47712 *

.74221

.04810 *

ROTATIONAL

ASSIGNMENT

RR

RR

RR

RR

RR

RR

OR

OR

OR

OR

OR

OR

OR

OR

RR

RR

RR

RR

7( 9)

6(22)

7(10)

6(23)

7(11)

6(24)

8(11)

8(12)

8(13)

8(15)

8(18)

8(20)

8(24)

8(27)

6(25)

7(13)

7(14)

7(15)

BAND

NU5

NU5

NU5

NU5

NU5

NU5

NU5

NU 5

NU5

NU5

NU5

NU5

NU5

NU5

NU5

NU5

NU5

NU5

ISOTOPIC

SPECIES

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

LINE

WAVE NUMBER

-1

NO.

CM

;VAC.

31

1556.40942

32

1556.65535

33

1556.96604

34

1557.34297

35

1557.39028

ROTATIONAL

ASSIGNMENT

RR 7(16)

BAND

ISOTOPIC

SPECIES

NU5

CH3 35C1





705 612

§ % ABSORPTION o § % ABSORPTION o § % ABSORPTION o

o DO

o o

212

LINE

NO. 1

2

3 4 5

6 7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

WAVENUMBER

_ 1

CM

1557.

1559.

1559.

1560.

1560.

1561 .

1561 .

1561 .

1561 .

1561 .

1562.

1562.

1562.

1562.

1563.

1563.

1563.

1563.

1563.

1563.

1564.

1564

1564

1564.

1564

;VAC.

.88529

.19361

.21358

.15062

.60605

.00215

.08857

.24160

.49298

.54227

.02762

.16274

.44489

.96776

.08518

.27102

.34902

.85428

.87340

.99107

.04789

.11041

. 17827,

.21431

.50339

* * * * * * *

t *

* * * * * *

*

ROTATIONAL

ASSIGNMENT

RR

RR

RO

OR

OR

OR

OR

OR

RO

8( 9)

8(11)

9(12)

9(13)

9(18)

9(20)

9(22)

9(24)

9(25)

BAND

NU5

NU5

NU5

NU5

NU5

NU5

NU5

NU5

NU5

ISO-rOPIC

SPECIES

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1





707 612


A

o o Ol

212

LINE

WAVE NUMBER

-1

NO.

CM

;VAC.

ROTATIONAL

BAND

ISOTOPIC

ASSIGNMENT

SPECIES

1

2

3 4 5

6 7

8

9

10

11

12

13

14

15

16

1564.

1565.

1565.

1565.

1566.

1566.

1566.

1566.

1567.

1567.

1567.

1568.

1569.

1570.

1570.

1571 .

.93376

.16128

.79360

.85979

.06947

.78704

.84283

.97900

.68169

.71531

.88988

.80193

.57449

.50673

.62991

.54569

*

*

*

* *

* *

* *

RR

RR

RR

RR

RR

RR

RR

8(13)

8(14)

8(15)

8(16)

8(17)

8(19)

8(20)

NU5

NU5

NU 5

NU5

NU5

NU5

NU5

CH3

CH3

CH3

CH3

CH3

CH3

CH3

35C1

35C1

35C1

35C1

35C1

35C1

35C1





709 612


212

LINE

WAVENUMBER

-1

NO.

CM

;VAC.

ROTATIONAL

BAND

ISOTOPIC

ASSIGNMENT

SPECIES

1

2

3 4 5

6 7

8

9

10

1 1

12

13

14

15

16

17

1572.

1572.

1572.

1573.

1573.

1573.

1574.

1574.

1574,

1575.

1576.

1577.

1577,

1577

1578.

1578.

1579 .46271

.63954 *

.67520

.38089

.52647 *

.57645

.30022

.41463 *

.47893

.22063

.28777

.06472 *

.08639 *

.19407

.87348 *

.91283

.01026

RR

RR

RR

RR

RR

RR

RR

RR

RR

RR

RR

8(21)

9( 9)

8(22)

9(10)

8(23)

9(11)

8(24)

9(13)

9(14)

8(28)

9(16)

NU5

NU5

NU5

NU5

NU5

NU5

NU5

NU5

NU5

NU5

NU5

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1





711 612

§ % ABSORPTION o § % ABSORPTION o § % ABSORPTION o Γ

o o 4\ -J —) o JD DO CO 00

O O

cn o 13

212

LINE

NO. 1

2

3

4 5

6 7 8

9

10

11

12

13

14

15

WAVENUMBER

-1

CM

;VAC.

1579.76862 *

1579.83858

1579.92004

1580.66494 *

1580.76511 *

1580.83108

1581.56236 *

1581.69244 *

1581.74327

1582.62104 *

1582.65653

1583.57075

1584.59061

1585.49167

1586.39380

ROTATIONAL

ASSIGNMENT

RR

RR

RR

RR

RR

RR

8(29)

9(17)

9(18)

9(19)

9(20)

9(21)

RR10O0)

RR10(11)

RR10(12)

BAND

NU5

NU5

NU5

NU5

NU5

NU5

NU5

NU5

NU5

ISOTOPIC

SPECIES

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

CH3

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1

35C1





713 612


4

o o

212

LINE

NO. 1

2

3

4 5

6 7 8

9

10

1.1

12

13

WAVENUMBER

_ 1

CM

1587,

1587,

1588,

1589.

1589,

1589,

1590,

1590,

1591

1592,

1592,

1593,

1593, ; VAC.

.23835

.29711

.15779

.07808

.10727

.99925

.01397

.92146

.83050

.74037

.76791 *

.65125

.69241 *

ROTATIONAL

ASSIGNMENT

RR 9(25)

RR10(13)

RR 9(26)

RR 9(27)

RR10(15)

RR 9(28)

RR10(16)

RR10(17)

RR10(18)

RR10(19)

RR10(20)

BAND

NU5

NU5

NU5

NU5

NU5

NU 5

NU5

NU5

NU5

NU5,

NU5

ISOTOPIC

SPECIES

CH3 35C1

CH3 35C1

CH3 35C1

CH3 35C1

CH3 35C1

CH3 35C1

CH3 35C1

CH3 35C1

CH3 35C1

CH3 35C1

CH3 35C1





715 612

Handbook of Infrared Standards II || METHYL CHLORIDE SPECTRAL MAPS AND WAVENUMBER DATA: 6.2...

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Transcript of Handbook of Infrared Standards II || METHYL CHLORIDE SPECTRAL MAPS AND WAVENUMBER DATA: 6.2...