Halogen Free, High Elastic Modulus and Low CTE … Specifications *1) Heating Rate:10 /min. *2)...

Standard Specifications *1) Heating Rate:10℃/min. *2) Measured by Triplate-Line Resonator. 0.8mm thickness core is used depending on test item. Copperfoil Thickness 2μm 3μm 5μm 12μm (LP,PF) 2μm 3μm 5μm 12μm 18μm 35μm 70μm (STD,LP,PF) Code Name U0.03 U0.04 U0.05 T0.04 T0.05 T0.06 T0.07 M0.06 0.1 0.15 0.2 0.3 0.41 0.61 0.81 0.030±0.013mm 0.040±0.013mm 0.050±0.013mm 0.040±0.013mm 0.050±0.013mm 0.060±0.013mm 0.070±0.013mm 0.07±0.02mm 0.11±0.02mm 0.16±0.03mm 0.21±0.04mm 0.32±0.05mm 0.40±0.05mm 0.60±0.06mm 0.80±0.08mm Actual Thickness and Tolerance MCL-E-679FG MCL-E-679FGB (R) (S) (S) Part Number Type Halogen Free, High Elastic Modulus and Low CTE Multilayer Material MCL-E-679FG High Tg Glass Epoxy Multilayer Material (FR-4) MCL-E-679FGB〈Black Type〉 GEA-679FG〈Prepreg〉 ●Halogen free material for environmental concerns. CTE (Z-direction) is 50% lower than that of our standard FR-4. ●Elastic modulus is 20% higher than that of our standard FR-4. Even thin laminate has less warpage and deflection. Superior heat resistance for soldering(suitable for the lead free process). ●Surface roughness is 1/4 of our standard FR-4, and making fine pattern possible. ●Semiconductor packages.      (FC-BGA, BGA, CSP) ●Core material for HDI. Features Applications Item X Y Z 1MHz 1GHz *2 1MHz 1GHz *2 18μm 35μm ppm/℃ sec. min. cycles kN/m μm GPa Ω・cm Ω Ω Unit >300 >60 >60 340~360 >10 2~3 4.6~4.8 0.0080~0.0100 0.0160~0.0180 1×10 15 ~1×10 16 1×10 13 ~1×10 15 1×10 14 ~1×10 16 1×10 13 ~1×10 15 V-0 165~175 200~220 13~15 13~15 23~33 140~170 0.9~1.1 1.1~1.2 23~28 5.2~5.4 0.4~0.6 175~185 210~230 12~14 12~14 20~30 130~160 1.1~1.2 1.2~1.3 24~29 5.0~5.2 0.3~0.5 Actual Value Condition Test Method (IPC-TM-650) TMA DMA (30~120℃) (<Tg(>TgA TMA TGA 260℃ Reflow A A A C-96/20/65 C-96/20/65 C-96/35/90 C-96/20/65 C-96/20/65+D-2/100 E-24/50+D-24/23 A Tg CTE *1 Solder Heat Resistance(260℃) T-260(Without Copper) T-288(Without Copper) Decomposition Temperature(5% Weight Loss) Heat Resistance for HDI Process (Semi-Additive) Copper Peel Strength Surface Roughness (Ra) Flexural Modulus (Lengthwise) Dielectric Constant Dissipation Factor Volume Resistivity Surface Resistance Insulation Resistance Water Absorption Flammability (UL-94) MCL-E-679FG Type(R) MCL-E-679FG Type(S) 2.4.24 2.4.24 2.4.24.1 2.3.40 2.4.8 2.2.17 2.4.4 2.5.5.1 2.5.5.5 2.5.5.1 2.5.5.5 2.5.17 2.6.2.1 2.3.10 Characteristics ●Thin Laminate (t0.4mm) 2,3,5,12,18μm (STD,LP,PF) Note1) STD:Standard copper foil, LP:Low profile copper foil, PF:Hitachi profile-free copper foil. Note2) STD:12μm,18μm, 35μm, 70μm; LP:2μm, 3μm, 5μm, 12μm, 18μm; PF:2μm, 3μm, 5μm, 12μm. Please contact us for details. Note3) “U” for 1-ply; “T” for 2-ply. Note4) In case laminate thickness lies in between two thickness figures shown above, the tolerance of such laminate would be equal to the tolerance of the thicker one. Note5) The thickness means that of dielectric layer. 18

Transcript of Halogen Free, High Elastic Modulus and Low CTE … Specifications *1) Heating Rate:10 /min. *2)...

Page 1: Halogen Free, High Elastic Modulus and Low CTE … Specifications *1) Heating Rate:10 /min. *2) Measured by Triplate-Line Resonator. 0.8mm thickness core is used depending on

■Standard Specifications

*1) Heating Rate:10℃/min. *2) Measured by Triplate-Line Resonator.0.8mm thickness core is used depending on test item.

Copperfoil Thickness

2μm3μm5μm12μm

(LP,PF)

2μm3μm5μm12μm18μm35μm70μm

(STD,LP,PF)

Code NameU0.03U0.04U0.05T0.04T0.05T0.06T0.07M0.060.10.150.20.30.410.610.81

0.030±0.013mm0.040±0.013mm0.050±0.013mm0.040±0.013mm0.050±0.013mm0.060±0.013mm0.070±0.013mm0.07±0.02mm0.11±0.02mm0.16±0.03mm0.21±0.04mm0.32±0.05mm0.40±0.05mm0.60±0.06mm0.80±0.08mm

Actual Thickness and Tolerance

MCL-E-679FGMCL-E-679FGB

(R)(S)

(S)

Part Number Type

Halogen Free, High Elastic Modulus and Low CTE Multilayer Material

MCL-E-679FG

High Tg Glass Epoxy Multilayer Material(FR-4)

MCL-E-679FGB〈Black Type〉GEA-679FG〈Prepreg〉

●Halogen free material for environmental concerns. ●CTE (Z-direction) is 50% lower than that of our standard FR-4. ●Elastic modulus is 20% higher than that of our standard

FR-4. Even thin laminate has less warpage and deflection.●Superior heat resistance for soldering(suitable for the lead free

process).●Surface roughness is 1/4 of our standard FR-4, and making fine

pattern possible.

●Semiconductor packages.      (FC-BGA, BGA, CSP)

●Core material for HDI.

■Features ■Applications

Item

XY

Z

1MHz 1GHz*2

1MHz 1GHz*2

18μm 35μm

ppm/℃

sec.

min.

℃cycleskN/m

μmGPa

-Ω・cm

ΩΩ

%-

Unit

>300>60>60

340~360>10

2~3

4.6~4.80.0080~0.01000.0160~0.01801×1015~1×1016

1×1013~1×1015

1×1014~1×1016

1×1013~1×1015

V-0

165~175200~22013~1513~1523~33

140~170

0.9~1.11.1~1.2

23~285.2~5.4

0.4~0.6

175~185210~23012~1412~1420~30

130~160

1.1~1.21.2~1.3

24~295.0~5.2

0.3~0.5

Actual ValueCondition Test Method

(IPC-TM-650)TMADMA

(30~120℃)

(<Tg)(>Tg)A

TMA

TGA260℃ Reflow

A

AA

C-96/20/65

C-96/20/65

C-96/35/90

C-96/20/65C-96/20/65+D-2/100E-24/50+D-24/23A

Tg

CTE *1

Solder Heat Resistance(260℃)T-260(Without Copper)T-288(Without Copper)Decomposition Temperature(5% Weight Loss)Heat Resistance for HDI Process(Semi-Additive)Copper Peel Strength

Surface Roughness(Ra)Flexural Modulus(Lengthwise)

Dielectric Constant

Dissipation Factor

Volume ResistivitySurface ResistanceInsulation Resistance

Water AbsorptionFlammability(UL-94)

MCL-E-679FG Type(R) MCL-E-679FG Type(S)2.4.24

2.4.24

2.4.24.12.3.40

2.4.8

2.2.172.4.4

2.5.5.12.5.5.52.5.5.12.5.5.5

2.5.17

ーー

2.6.2.12.3.10

■Characteristics ●Thin Laminate (t0.4mm)

2,3,5,12,18μm(STD,LP,PF)

Note1) STD:Standard copper foil, LP:Low profile copper foil, PF:Hitachi profile-free copper foil.Note2) STD:12μm,18μm, 35μm, 70μm; LP:2μm, 3μm, 5μm, 12μm, 18μm; PF:2μm, 3μm, 5μm, 12μm. Please contact us for details. Note3) “U” for 1-ply; “T” for 2-ply.Note4) In case laminate thickness lies in between two thickness figures shown above, the tolerance of such laminate would be equal to the tolerance of the thicker one.Note5) The thickness means that of dielectric layer.

●Prepreg

Span : 10mmSpan : 15mmSpan : 20mmSpan : 25mmSpan : 30mmSpan : 35mmSpan : 40mm

0.030.040.060.10.030.030.030.040.060.1

(R)

(S)

75×7569×7253×5360×5895×9575×7575×7569×7253×5360×58

73±273±268±258±278±273±278±273±268±258±2

≦1.5

≦1.0

≦1.5

≦1.0

175±30165±30

155±30

175±30

165±30

(GBPE)(GRZPE)(GRROE)(GRSKE)(GSAPE)(GSBPE)(GSBSE)(GSZPE)(GSROE)(GSSKE)

0.0400.0480.0790.1270.0310.0400.0500.0480.0790.127

Type Yarn Content(warp×fill)

Resin Content(%)

Volation Content(%)

Gelation Time(sec.)

Dielectric Thickness(mm)*1()After pattern filling

PropertiesGlass Cloth

1027103710782116101710271027103710782116

StylePart Number

GEA-679FG

●Prepreg thickness after pattern filling(Inner layer copper 15μm)

T0.07

●Stiffness Properties

12

10

8

6

4

2

1

0U0.04 T0.04 U0.05 T0.06

Flex

ure(

mm

Thickness

Weight(1g)

Span

Flexure

*1)The dielectric thickness after lamination is defined as the thickness of one sheet of prepreg when the resin flow is 0%. This value changes depending on the press condition or inner layer pattern.

Test Method(IPC-TM-650) 2.3.16.1 2.3.19 2.3.18 -

Copper remain ratio(%)

prep

reg

thic

knes

s(μ

m)

60

50

40

30

20

10

0100 20 30 40 50 60 70 80 90 100

Prepreg Thickness

GSBSE

GSBPE

GSAPE

chan

ge ra

tio o

f con

duct

ive

resi

stan

ce(%

0 500 600 700 800 900 1000400300200100

Number of cycles

●Through-hole reliabilityTest condition:-55℃, 30min. ⇔150℃, 30min.Pattern:Wall to wall distance 0.3mm, Laminate thickness:t0.8mmPre-condition:260℃ reflow × 2times⇒Solder dipping(260℃ 10sec.)

20

15

10

5

0

-5

●:MCL-E-679FG Type(S)▲:MCL-E-679FG Type(R)

18

Page 2: Halogen Free, High Elastic Modulus and Low CTE … Specifications *1) Heating Rate:10 /min. *2) Measured by Triplate-Line Resonator. 0.8mm thickness core is used depending on

■Standard Specifications

*1) Heating Rate:10℃/min. *2) Measured by Triplate-Line Resonator.0.8mm thickness core is used depending on test item.

Copperfoil Thickness

2μm3μm5μm12μm

(LP,PF)

2μm3μm5μm12μm18μm35μm70μm

(STD,LP,PF)

Code NameU0.03U0.04U0.05T0.04T0.05T0.06T0.07M0.060.10.150.20.30.410.610.81

0.030±0.013mm0.040±0.013mm0.050±0.013mm0.040±0.013mm0.050±0.013mm0.060±0.013mm0.070±0.013mm0.07±0.02mm0.11±0.02mm0.16±0.03mm0.21±0.04mm0.32±0.05mm0.40±0.05mm0.60±0.06mm0.80±0.08mm

Actual Thickness and Tolerance

MCL-E-679FGMCL-E-679FGB

(R)(S)

(S)

Part Number Type

Halogen Free, High Elastic Modulus and Low CTE Multilayer Material

MCL-E-679FG

High Tg Glass Epoxy Multilayer Material(FR-4)

MCL-E-679FGB〈Black Type〉GEA-679FG〈Prepreg〉

●Halogen free material for environmental concerns. ●CTE (Z-direction) is 50% lower than that of our standard FR-4. ●Elastic modulus is 20% higher than that of our standard

FR-4. Even thin laminate has less warpage and deflection.●Superior heat resistance for soldering(suitable for the lead free

process).●Surface roughness is 1/4 of our standard FR-4, and making fine

pattern possible.

●Semiconductor packages.      (FC-BGA, BGA, CSP)

●Core material for HDI.

■Features ■Applications

Item

XY

Z

1MHz 1GHz*2

1MHz 1GHz*2

18μm 35μm

ppm/℃

sec.

min.

℃cycleskN/m

μmGPa

-Ω・cm

ΩΩ

%-

Unit

>300>60>60

340~360>10

2~3

4.6~4.80.0080~0.01000.0160~0.01801×1015~1×1016

1×1013~1×1015

1×1014~1×1016

1×1013~1×1015

V-0

165~175200~22013~1513~1523~33

140~170

0.9~1.11.1~1.2

23~285.2~5.4

0.4~0.6

175~185210~23012~1412~1420~30

130~160

1.1~1.21.2~1.3

24~295.0~5.2

0.3~0.5

Actual ValueCondition Test Method

(IPC-TM-650)TMADMA

(30~120℃)

(<Tg)(>Tg)A

TMA

TGA260℃ Reflow

A

AA

C-96/20/65

C-96/20/65

C-96/35/90

C-96/20/65C-96/20/65+D-2/100E-24/50+D-24/23A

Tg

CTE *1

Solder Heat Resistance(260℃)T-260(Without Copper)T-288(Without Copper)Decomposition Temperature(5% Weight Loss)Heat Resistance for HDI Process(Semi-Additive)Copper Peel Strength

Surface Roughness(Ra)Flexural Modulus(Lengthwise)

Dielectric Constant

Dissipation Factor

Volume ResistivitySurface ResistanceInsulation Resistance

Water AbsorptionFlammability(UL-94)

MCL-E-679FG Type(R) MCL-E-679FG Type(S)2.4.24

2.4.24

2.4.24.12.3.40

2.4.8

2.2.172.4.4

2.5.5.12.5.5.52.5.5.12.5.5.5

2.5.17

ーー

2.6.2.12.3.10

■Characteristics ●Thin Laminate (t0.4mm)

2,3,5,12,18μm(STD,LP,PF)

Note1) STD:Standard copper foil, LP:Low profile copper foil, PF:Hitachi profile-free copper foil.Note2) STD:12μm,18μm, 35μm, 70μm; LP:2μm, 3μm, 5μm, 12μm, 18μm; PF:2μm, 3μm, 5μm, 12μm. Please contact us for details. Note3) “U” for 1-ply; “T” for 2-ply.Note4) In case laminate thickness lies in between two thickness figures shown above, the tolerance of such laminate would be equal to the tolerance of the thicker one.Note5) The thickness means that of dielectric layer.

●Prepreg

Span : 10mmSpan : 15mmSpan : 20mmSpan : 25mmSpan : 30mmSpan : 35mmSpan : 40mm

0.030.040.060.10.030.030.030.040.060.1

(R)

(S)

75×7569×7253×5360×5895×9575×7575×7569×7253×5360×58

73±273±268±258±278±273±278±273±268±258±2

≦1.5

≦1.0

≦1.5

≦1.0

175±30165±30

155±30

175±30

165±30

(GBPE)(GRZPE)(GRROE)(GRSKE)(GSAPE)(GSBPE)(GSBSE)(GSZPE)(GSROE)(GSSKE)

0.0400.0480.0790.1270.0310.0400.0500.0480.0790.127

Type Yarn Content(warp×fill)

Resin Content(%)

Volation Content(%)

Gelation Time(sec.)

Dielectric Thickness(mm)*1()After pattern filling

PropertiesGlass Cloth

1027103710782116101710271027103710782116

StylePart Number

GEA-679FG

●Prepreg thickness after pattern filling(Inner layer copper 15μm)

T0.07

●Stiffness Properties

12

10

8

6

4

2

1

0U0.04 T0.04 U0.05 T0.06

Flex

ure(

mm

Thickness

Weight(1g)

Span

Flexure

*1)The dielectric thickness after lamination is defined as the thickness of one sheet of prepreg when the resin flow is 0%. This value changes depending on the press condition or inner layer pattern.

Test Method(IPC-TM-650) 2.3.16.1 2.3.19 2.3.18 -

Copper remain ratio(%)

prep

reg

thic

knes

s(μ

m)

60

50

40

30

20

10

0100 20 30 40 50 60 70 80 90 100

Prepreg Thickness

GSBSE

GSBPE

GSAPE

chan

ge ra

tio o

f con

duct

ive

resi

stan

ce(%

0 500 600 700 800 900 1000400300200100

Number of cycles

●Through-hole reliabilityTest condition:-55℃, 30min. ⇔150℃, 30min.Pattern:Wall to wall distance 0.3mm, Laminate thickness:t0.8mmPre-condition:260℃ reflow × 2times⇒Solder dipping(260℃ 10sec.)

20

15

10

5

0

-5

●:MCL-E-679FG Type(S)▲:MCL-E-679FG Type(R)

19