Post on 31-Jul-2020
Methanol Fuel Cell System in China
Importance of clean energy
2
1470588 1176471 1323529
4411765
6617647
0
1000000
2000000
3000000
4000000
5000000
6000000
7000000
2016.12.16 2016.12.17 2016.12.18 2016.12.19 2016.12.20
Mask sold from Internet (pcs)
PM2.5187μg/m3
PM2.5298μg/m3
PM2.5247μg/m3
PM2.5305μg/m3
PM2.5376μg/m3
Find out the PM2.5 Sources
3
Take the action to resolve the problem
4
Take the action to resolve the problem
CoalNatural Gas
MethanolGasolineDiesel
Natural Gas
Methanol
Battery
Hybrid
Fuel Cell
Heavy Oil
Natural Gas
Methanol
5
Take the action to resolve the problem
Tendency is clear, there will be more and more green energy
‐4,70%
5,50%8,00%
1,70%
‐6,00%
‐4,00%
‐2,00%
0,00%
2,00%
4,00%
6,00%
8,00%
10,00%
Coal Oil Natural Gas Renewable
2016 changes vs 2015
6
Take the action to resolve the problem
The “New Energy” is growing fast, which brings new industry
14,50%15,50%
17%18%
19,70%
0,00%
5,00%
10,00%
15,00%
20,00%
25,00%
2012年 2013年 2014年 2015年 2016年
2012‐2016 Renewable energy in percentage
7
Methanol as “Clean Energy”
The market influenced the usage of Methanol in China
Methanol
Direct Burning
M100 Motor
M5, M15,M85 Mixture
Indirect Fuel processing
Chemical forming DME
Electro‐Chemical
DMFC
Reforming + Fuel Cell
8
Importance of clean energy
With more than 10 years push from Geely, there are hundreds M100 cars as taxis running in China. To refill is not a difficult issue.
9
Importance of clean energy
The distribution nets are already well developed for the consumers.
Pure Methanol Fuel(99.99%)
For Hot‐Pot, car, Motocycle, etc.
Not for drink!
Price: 12 RMB/4L
1.6 Euro/ 4L,0.4 Euro/L0.5 Euro/ kg
10
Importance of clean energy
Even when there are 42% methanol, it could not burn continuously
Pure Methanol Pre-Mixture (60%:40%)
Withfire
It burns Hard to burn
With cigerette
No burning No burning
11
Direct burning for vehicle
Geely, car manufacturer, (the owner of Volvo car),Spent more than 10 years on research and developing methanol combustion engine and has now mature product on the market as Taxis etc.
12
Direct burning
In compare to natural gas, the cost saved could up to 30%!
13
Eletro-chemical using: DMFC
Market:
Remote hybrid system with Solar, Wind and Battery
14
Eletro-chemical using: MFC
Methanol
Reformer
CH4O
PSA Palladium membran
LT PEM LT PEM HT PEM
H2 H2
H2, CO2, CO
H2
15
Eletro-chemical using: MFC
Methanol
Reformer
CH4O
WGS + PrOX SelOX
LT PEM LT PEM
H2 H2
H2, CO2, CO
Methanation
LT PEM
H2
16
Eletro-chemical using: MFC
Advantage:1. Pressure Swing
Adsorption is mature technology
2. Running cost is low
CH3OH Reformer
H2O
Burner
PSA
AirPure H299.99%
CO, MeOH, CO2, H2O
Disadvantage:1. The size of the equipment
is big2. Working in Batch process,
buffer tank is necessary
Application:
1. Hydrogen Fill station2. On‐Site Hydrogen
production
17
Eletro-chemical using: MFC
Advantage:1. The Palladium membran
could be integrated to the reformer, which makes system compact
2. With high purity
CH3OH Reformer
H2O
Burner
Palladium Membran
AirPure H299.9999%
CO, MeOH, CO2, H2O
Disadvantage:1. Palladium membran is
very expensive2. High requirement on
Pressure, temperature, vapor etc. controll
Application:
1. CHP in house2. Mobile application
18
Eletro-chemical using: MFC
Advantage:1. The waster heat of HT
PEM could be used for vaporization of MeOHWater mixture, to get higher system efficiency
2. System is compact
CH3OH Reformer
H2O
Burner
HT PEM
Air CO, CO2, H2O, H2
Disadvantage:1. HT‐PEM Stack is
expensive2. Long start time
Application:
1. Generator for replacediesel one
2. Mobile application
Heat
Vaporizer
HeatH2, CO2, CO
19
Eletro-chemical using: MFC
Advantage:1. Low noble metal content2. Low total cost3. With pure MeOH possible4. Reformer is compact
CH3OH Reformer SelOX
Air
Disadvantage:1. Complicated control system2. High requirement on LT
PEM, special MEA is neccessary
Application:
1. CHP in house2. Mobile application
WGS + PrOX
Methanation
CO ‐> CO2
CO ‐> CH4
LT‐PEM
H2,CO2,N2,CO
H2O
20
Market Chance for Fuel Cell
1998 2003 2009 2012 2014 2015
Founded inCanada
Facility in Suzhou,China
The first Fuel CellScooter/Bicycle
First PortableFC Generator
First FotovotaikFC Storage Sys.
First Methanol Reformed FC Bus
2016
First Methanol Reformed FC Truck
21
Market Chance for Fuel Cell
1881823918
2900035000
2700032000 34000
44000
64000
77000
5853
15327
26685
6428
7348
9000
10000
11000
11000 8000
5000
8000
12000
1032
2645
6330
0
10000
20000
30000
40000
50000
60000
70000
80000
90000
100000
Mar‐16 Apr‐16 May‐16 Jun‐16 Jul‐16 Aug‐16 Sep‐16 Oct‐16 Nov‐16 Dec‐16 Jan‐17 Feb‐17 Mar‐17
2016‐2017 Sold EV in China
Pure EV Plug‐inHybrid EV
22
Market Chance for Fuel Cell
According to the state regulation, there should be 5 Million stations by 2020
1. Long charging time
<200‐400 km
2. Short distance 3.Bad performance at low temperature
5.Capacity of Batteries degrade quickly
4.Batteries are too heavy 6.Charge stationsrequired
23
Market Chance for Fuel Cell
Pure Hydrogen Vehicle is super, but there are something need to be considered.
H2 H2
1. Cost for fuel station is high
2.Safety issue, high requirement
3. Low energy density
only 80fillings
Safety
=
24
Palcan as main player in MFC
Oil + BatteryHybrid
Pure Battery
EV
Fuel Cell EV
Prius
TeslaFuel Cell
Hybrid
Miria
25
Palcan as main player in MFC
Backup power
Passenger Transportation Logistic Truck
26
Engineering EV
Palcan as main player in MFC
PMS(Power)
BMS(Battery)
CMS
(Super Capacitor)
FMS(Fuel Cell)
1. Extend life time of battery
2. Smart manage energy recovery by braking
3. Balance of Fuel Cell and battery/Super capacitors
27
Palcan as main player in MFC
The most import thing in China for new technology introduction
Certification of FC systemin Tianjin
Computer Systemin Beijing
Chinese VehicleTest Center
SpecialistDiscussion
Norm Update
Test StandardProcedure
Road Test> 15 000km
28
Palcan as main player in MFC
A diesel MPV, with 1000 kWh energy stored in Methanol mixture
29
Palcan as main player in MFC
A 7m long electrical bus, with Super Capacitor, only 1.7kWh energy
30
With Dongfeng(East Wind), we Chengong(change Mind)