Methanol Fuel Cell System in China · issue. 9. Importance of clean energy ... Update Test Standard...

Methanol Fuel Cell System in China

Importance of clean energy

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1000000

2000000

3000000

4000000

5000000

6000000

7000000

2016.12.16 2016.12.17 2016.12.18 2016.12.19 2016.12.20

Mask sold from Internet (pcs)

PM2.5187μg/m3

PM2.5298μg/m3

PM2.5247μg/m3

PM2.5305μg/m3

PM2.5376μg/m3

Find out the PM2.5 Sources

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Take the action to resolve the problem

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CoalNatural Gas

MethanolGasolineDiesel

Natural Gas

Methanol

Battery

Hybrid

Fuel Cell

Heavy Oil

Natural Gas

Methanol

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Tendency is clear, there will be more and more green energy

‐4,70%

5,50%8,00%

1,70%

‐6,00%

‐4,00%

‐2,00%

0,00%

2,00%

4,00%

6,00%

8,00%

10,00%

Coal Oil Natural Gas Renewable

2016 changes vs 2015

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The “New Energy” is growing fast, which brings new industry

14,50%15,50%

17%18%

19,70%

0,00%

5,00%

10,00%

15,00%

20,00%

25,00%

2012年 2013年 2014年 2015年 2016年

2012‐2016 Renewable energy in percentage

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Methanol as “Clean Energy”

The market influenced the usage of Methanol in China

Methanol

Direct Burning

M100 Motor

M5, M15,M85 Mixture

Indirect Fuel processing

Chemical forming DME

Electro‐Chemical

DMFC

Reforming + Fuel Cell

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With more than 10 years push from Geely, there are hundreds M100 cars as taxis running in China. To refill is not a difficult issue.

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The distribution nets are already well developed for the consumers.

Pure Methanol Fuel(99.99%)

For Hot‐Pot, car, Motocycle, etc.

Not for drink!

Price: 12 RMB/4L

1.6 Euro/ 4L,0.4 Euro/L0.5 Euro/ kg

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Even when there are 42% methanol, it could not burn continuously

Pure Methanol Pre-Mixture (60%:40%)

Withfire

It burns Hard to burn

With cigerette

No burning No burning

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Direct burning for vehicle

Geely, car manufacturer, (the owner of Volvo car),Spent more than 10 years on research and developing methanol combustion engine and has now mature product on the market as Taxis etc.

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Direct burning

In compare to natural gas, the cost saved could up to 30%!

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Eletro-chemical using: DMFC

Market:

Remote hybrid system with Solar, Wind and Battery

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Eletro-chemical using: MFC

Methanol

Reformer

CH4O

PSA Palladium membran

LT PEM LT PEM HT PEM

H2 H2

H2, CO2, CO

H2

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Methanol

Reformer

CH4O

WGS + PrOX SelOX

LT PEM LT PEM

H2 H2

H2, CO2, CO

Methanation

LT PEM

H2

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Advantage:1. Pressure Swing

Adsorption is mature technology

2. Running cost is low

CH3OH Reformer

H2O

Burner

PSA

AirPure H299.99%

CO, MeOH, CO2, H2O

Disadvantage:1. The size of the equipment

is big2. Working in Batch process,

buffer tank is necessary

Application:

1. Hydrogen Fill station2. On‐Site Hydrogen

production

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Advantage:1. The Palladium membran

could be integrated to the reformer, which makes system compact

2. With high purity

CH3OH Reformer

H2O

Burner

Palladium Membran

AirPure H299.9999%

CO, MeOH, CO2, H2O

Disadvantage:1. Palladium membran is

very expensive2. High requirement on

Pressure, temperature, vapor etc. controll

Application:

1. CHP in house2. Mobile application

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Advantage:1. The waster heat of HT

PEM could be used for vaporization of MeOHWater mixture, to get higher system efficiency

2. System is compact

CH3OH Reformer

H2O

Burner

HT PEM

Air CO, CO2, H2O, H2

Disadvantage:1. HT‐PEM Stack is

expensive2. Long start time

Application:

1. Generator for replacediesel one

2. Mobile application

Heat

Vaporizer

HeatH2, CO2, CO

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Advantage:1. Low noble metal content2. Low total cost3. With pure MeOH possible4. Reformer is compact

CH3OH Reformer SelOX

Air

Disadvantage:1. Complicated control system2. High requirement on LT

PEM, special MEA is neccessary

Application:

1. CHP in house2. Mobile application

WGS + PrOX

Methanation

CO ‐> CO2

CO ‐> CH4

LT‐PEM

H2,CO2,N2,CO

H2O

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Market Chance for Fuel Cell

1998 2003 2009 2012 2014 2015

Founded inCanada

Facility in Suzhou,China

The first Fuel CellScooter/Bicycle

First PortableFC Generator

First FotovotaikFC Storage Sys.

First Methanol Reformed FC Bus

2016

First Methanol Reformed FC Truck

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1881823918

2900035000

2700032000 34000

44000

64000

77000

5853

15327

26685

6428

7348

9000

10000

11000

11000 8000

5000

8000

12000

1032

2645

6330

0

10000

20000

30000

40000

50000

60000

70000

80000

90000

100000

Mar‐16 Apr‐16 May‐16 Jun‐16 Jul‐16 Aug‐16 Sep‐16 Oct‐16 Nov‐16 Dec‐16 Jan‐17 Feb‐17 Mar‐17

2016‐2017 Sold EV in China

Pure EV Plug‐inHybrid EV

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According to the state regulation, there should be 5 Million stations by 2020

1. Long charging time

<200‐400 km

2. Short distance 3.Bad performance at low temperature

5.Capacity of Batteries degrade quickly

4.Batteries are too heavy 6.Charge stationsrequired

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Pure Hydrogen Vehicle is super, but there are something need to be considered.

H2 H2

1. Cost for fuel station is high

2.Safety issue, high requirement

3. Low energy density

only 80fillings

Safety

=

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Palcan as main player in MFC

Oil + BatteryHybrid

Pure Battery

EV

Fuel Cell EV

Prius

TeslaFuel Cell

Hybrid

Miria

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Backup power

Passenger Transportation Logistic Truck

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Engineering EV


PMS(Power)

BMS(Battery)

CMS

(Super Capacitor)

FMS(Fuel Cell)

1. Extend life time of battery

2. Smart manage energy recovery by braking

3. Balance of Fuel Cell and battery/Super capacitors

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The most import thing in China for new technology introduction

Certification of FC systemin Tianjin

Computer Systemin Beijing

Chinese VehicleTest Center

SpecialistDiscussion

Norm Update

Test StandardProcedure

Road Test> 15 000km

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A diesel MPV, with 1000 kWh energy stored in Methanol mixture

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A 7m long electrical bus, with Super Capacitor, only 1.7kWh energy

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With Dongfeng(East Wind), we Chengong(change Mind)

Methanol Fuel Cell System in China · issue. 9. Importance of clean energy ... Update Test Standard...

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