ChemInform Abstract: Novel Tandem Cyclizations/Reaction with Electrophiles of α-Aminoalkyl...

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1999 pyrrole derivatives pyrrole derivatives R 0120 37 - 118 Novel Tandem Cyclizations/Reaction with Electrophiles of α- Aminoalkyl Radicals. This provides a new strategy for the synthesis of pyrrolidines with a functional group at C-3. The radicals are formed by treatment of the intermediate benzotriazoles [cf. (III)] with SmI 2 . (KATRITZKY, ALAN R.; FENG, DAMING; QI, MING; AURRECOECHEA, JOSE M.; SUERO, RUBEN; AURREKOETXEA, NATALIA; J. Org. Chem. 64 (1999) 9, 3335-3338; Cent. Heterocycl. Comp., Dep. Chem., Univ. Fla., Gainesville, FL 32611, USA; EN) 1

Transcript of ChemInform Abstract: Novel Tandem Cyclizations/Reaction with Electrophiles of α-Aminoalkyl...

Page 1: ChemInform Abstract: Novel Tandem Cyclizations/Reaction with Electrophiles of α-Aminoalkyl Radicals.

1999 pyrrole derivatives

pyrrole derivativesR 0120

37 - 118Novel Tandem Cyclizations/Reaction with Electrophiles of α-Aminoalkyl Radicals. — This provides a new strategy for the synthesisof pyrrolidines with a functional group at C-3. The radicals are formedby treatment of the intermediate benzotriazoles [cf. (III)] with SmI2. —(KATRITZKY, ALAN R.; FENG, DAMING; QI, MING; AURRECOECHEA,JOSE M.; SUERO, RUBEN; AURREKOETXEA, NATALIA; J. Org. Chem.64 (1999) 9, 3335-3338; Cent. Heterocycl. Comp., Dep. Chem., Univ. Fla.,Gainesville, FL 32611, USA; EN)

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