Prefixes - faculty.mwsu.edufaculty.mwsu.edu/chemistry/randal.hallford/1244/all_equations.pdf ·...
Transcript of Prefixes - faculty.mwsu.edufaculty.mwsu.edu/chemistry/randal.hallford/1244/all_equations.pdf ·...
Prefixes
a=10−18, f=10−15, p=10−12, n=10−9, µ = 10−6, m=10−3, c=10−2, k=103, M=106, G=109, T=1012, P=1015
Physical Constants
k = 1/4πǫ0 = 8.988 GN·m2/C2 (Coulomb’s Law) ǫ0 = 1/4πk = 8.854 pF/m (permittivity of space)
e = 1.602× 10−19 C (proton charge)
me = 9.11× 10−31 kg (electron mass) mp = 1.67× 10−27 kg (proton mass)
Units and Conversions
NA = 6.02× 1023/mole (Avogadro’s #) 1 u = 1 g/NA = 1.6605× 10−27 kg (mass unit)
1.0 eV = 1.602× 10−19 J (electron-volt) 1 V = 1 J/C = 1 volt = 1 joule/coulomb
1 F = 1 C/V = 1 farad = 1 C2/J
1 A = 1 C/s = 1 ampere = 1 coulomb/second 1 Ω = 1 V/A = 1 ohm = 1 J·s/C2
Vectors
Written ~V or V, described by magnitude=V , direction=θ or by components (Vx, Vy).
Vx = V cos θ, Vy = V sin θ,
V =√
V 2x + V 2
y , tan θ =Vy
Vx
. θ is the angle from ~V to +x-axis.
Addition: A+B, head to tail. Subtraction: A−B is A+ (−B), −B is B reversed.
Trig summary
sin θ = (opp)(hyp) , cos θ = (adj)
(hyp) , tan θ = (opp)(adj) , (opp)2 + (adj)2 = (hyp)2.
sin θ = sin(180 − θ), cos θ = cos(−θ), tan θ = tan(180 + θ), sin2 θ + cos2 θ = 1.
Chapter 16 Equations
Charges:
Q = ±Ne, ∆Q1 +∆Q2 = 0, e = 1.602× 10−19 C.
Electric Force:
F = kQ1Q2
r2 , k = 8.988× 109 N·m2/C2, F = Q1Q2
4πǫ0r2, ǫ0 = 1
4πk = 8.854 pF/m.
~F = ~F1 + ~F2 + ~F3 + ... superposition of many forces.
Fx = F1x + F2x + F3x + ... superposition of x-components of many forces.
Fy = F1y + F2y + F3y + ... superposition of y-components of many forces.
Electric Field:
~E =~Fq , q= test charge. Or: ~F = q ~E.
| ~E| = E = k Qr2 = Q
4πǫ0r2, due to point charge. Negative Q makes inward ~E, positive Q makes outward ~E.
~E = ~E1 + ~E2 + ~E3 + ... superposition of many electric fields.
Ex = E1x + E2x + E3x + ... superposition of x-components of many electric fields.
Ey = E1y + E2y + E3y + ... superposition of y-components of many electric fields.
E = k Qr2 = electric field around a point charge or outside a spherical charge distribution.
Eq.-1
Chapter 17 Equations
Potential Energy and Work:
Wba = FEd cos θ = work done by electric force FE on test charge, in displacement d from a to b.
Wba = −q∆V = −q(Vb − Va) = work done by electric force on a test charge, moved from a to b.
∆PE = q∆V = q(Vb − Va) = change in electric potential energy of the system. Also: ∆PE = −Wba.
∆KE +∆PE = 0, or, ∆KE = −∆PE = −q∆V , principle of conservation of mechanical energy.
Potential:
∆V = ∆PEq = definition of change in electric potential.
∆V = Ed = potential change in a uniform electric field.
V = kQr = potential produced by a point charge or outside a spherical charge distribution.
PE = qV = potential energy for a test charge at a point in a field.
PE = kQ1Q2
r12= potential energy of a pair of charges.
Capacitance:
Q = CV , C = Kǫ0Ad = capacitor equations.
U = 12QV = 1
2CV 2 = 12Q2
C = stored energy.
E = Q/Aǫ0
= electric field strength very near a charged conductor.
Chapter 18 Equations
Electric current:
I = ∆Q∆t , or ∆Q = I∆t, definition of current.
V = IR, or I = V/R, Ohm’s law.
R = ρLA = calculation of resistance.
ρT = ρ0[1 + α(T − T0)] = temperature-dependent resistivity.
Electric power:
P = IV , P = I2R, P = V 2/R, P = instantaneous energy/time.
Alternating current:
V = V0 sin 2πft = time-dependent AC voltage. I = I0 sin 2πft = time-dependent AC current.
Vrms =√
V 2 = V0/√2 = root-mean-square voltage. Irms =
√
I2 = I0/√2 = root-mean-square current.
AC power in resistors:
P = 12I
20R = 1
2V20 /R = 1
2I0V0 = average power. P = I2rmsR = V 2rms/R = IrmsVrms = average power.
Eq.-2
V = k Qr = potential produced by a point charge or outside a spherical charge distribution.
PE = qV = potential energy for a test charge at a point in a field.PE = k Q1Q2
r12= potential energy of a pair of charges.
Capacitance:Q = CV , C = Kε0
Ad = capacitor equations.
U = 12QV = 1
2CV 2 = 12
Q2
C = stored energy.
E = Q/Aε0
= electric field strength very near a charged conductor.
Chapter 18 Equations
Electric current and power:I = ∆Q
∆t , ∆Q = I∆t current definition. V = IR, I = V/R Ohm’s law.R = ρL/A calculation of resistance. ρ = ρ0[1 + α(T − T0)] resistivity changes.P = IV , P = I2R, P = V 2/R. P = instantaneous work/time.
Alternating current:V = V0 sin 2πft = time-dependent AC voltage. I = I0 sin 2πft = time-dependent AC current.
Vrms =√
V 2 = V0/√
2 = root-mean-square voltage. Irms =√
I2 = I0/√
2 = root-mean-square current.AC power in resistors:
P = 12I2
0R = 12V 2
0 /R = 12I0V0 = average power. P = I2
rmsR = V 2rms/R = IrmsVrms = average power.
Chapter 19 Equations
Resistor CombinationsReq = R1 + R2 + R3 + ... (series) 1
Req= 1
R1+ 1
R2+ 1
R3+ ... (parallel)
Real batteriesVab = E − Ir (terminal voltage) Vab = IR (connected to load R)
Kirchhoff’s Rules∑∆V = 0 (loop rule, energy conservation)
∑I = 0 (node rule, charge conservation)
Chapter 20 Equations
Magnetic forces, torqueF = IlB sin θ (on a current) F = qvB sin θ (on a moving charge)F/l = µ0
2πI1I2
d (between currents) F = qvB = mv2/r (during cyclotron motion)τ = NBAI sin θ (torque on a coil) v = ωr = 2πfr = 2πr/T (circular motion)
Magnetic FieldsB = µ0
2πIr (due to long straight wire) B = µ0IN/l (inside a solenoid)
Right Hand RulesForce (thumb) = [I (4 fingers)] × [magnetic field (palm)] (force on a current)Force (thumb) = [qv (4 fingers)] × [magnetic field (palm)] (force on a moving charge)Current (thumb) ⇐⇒ [magnetic field (4 fingers)] (magnetic field around a wire)Current (4 fingers) ⇐⇒ [magnetic field (thumb)] (magnetic field inside a current loop)
Chapter 21 Equations
Faraday’s Induced EMFΦB = BA cos θ (magnetic flux) E = −N ∆ΦB
∆t (induced emf)E = Blv (moving conductor) E = NBAω sinωt (AC generator)V − E = IR (motor’s counter-emf) E1 = −M ∆I2
∆t (mutual inductance emf)VS/VP = NS/NP (transformer equation) IP VP = ISVS (power in = power out)
Eq.-2
Prefixes
a=10−18, f=10−15, p=10−12, n=10−9, µ = 10−6, m=10−3, c=10−2, k=103, M=106, G=109, T=1012, P=1015
Physical Constants
k = 1/4πε0 = 8.988 GNm2/C2 (Coulomb’s Law) ε0 = 1/4πk = 8.854 pF/m (permittivity of space)e = 1.602× 10−19 C (proton charge) µ0 = 4π × 10−7 T·m/A (permeability of space)me = 9.11× 10−31 kg (electron mass) mp = 1.67× 10−27 kg (proton mass)c = 3.00× 108 m/s (speed of light) c = 2.99792458× 108 m/s (exact value in vacuum)
Units
NA = 6.02× 1023/mole (Avogadro’s #) 1 u = 1 g/NA = 1.6605× 10−27 kg (mass unit)1.0 eV = 1.602× 10−19 J (electron-volt) 1 V = 1 J/C = 1 volt = 1 joule/coulomb1 F = 1 C/V = 1 farad = 1 C2/J 1 H = 1 V·s/A = 1 henry = 1 J/A2
1 A = 1 C/s = 1 ampere = 1 coulomb/second 1 Ω = 1 V/A = 1 ohm = 1 J·s/C2
1 T = 1 N/A·m = 1 tesla = 1 newton/ampere·meter 1 G = 10−4 T = 1 gauss = 10−4 tesla
Chapter 22 Equations
Electromagnetic waves:
| #E|/| #B| = c = 1/√ε0µ0, (fields) fλ = c (wave equation)
Energy density, intensity, power:
u = ε0E2 = B2
µ0(instantaneous energy density) u = 1
2ε0E20 = B2
02µ0
(average energy density)
I = uc = 12ε0E
20c (EM waves intensity) I = P/A = P/(4πr2) (intensity definition)
Chapter 23 Equations
Reflection, Mirrors:
θr = θi (angle of incidence = angle of reflection) f = r/2 (focal length of spherical mirror)1do
+ 1di
= 1f (mirror equation) m = −di/do = hi/ho (linear magnification)
di > 0 ⇒ real, light side. di < 0 ⇒ virtual, dark side.
m > 0 ⇒ upright. m < 0 ⇒ inverted.
|m| > 1 ⇒ magnified. |m| < 1 ⇒ diminished.
Refraction, Lenses:
n = c/v (index of refraction) n1 sin θ1 = n2 sin θ2 (Snell’s Law)1do
+ 1di
= 1f (lens equation) m = −di/do = hi/ho (linear magnification)
di > 0 ⇒ real image, light (opp.) side. di < 0 ⇒ virtual image, dark (same) side.
m > 0 ⇒ upright. m < 0 ⇒ inverted.
|m| > 1 ⇒ magnified. |m| < 1 ⇒ diminished.
Eq.-1
Chapter 24 Equations
Wave properties, interference:
λn = λvacuum/n (wavelength in a medium) ∆x = d sin θ (path difference in double slits)
d sin θ = mλ (double slits bright fringes) d sin θ = (m+ 1/2)λ (double slits dark fringes)
Diffraction:
D sin θ = mλ (single slit minima) y = L tan θ (position on a screen)
d sin θ = mλ (diffraction grating maxima) d = 1/(lines per meter).
Thin film interference:
∆x = path 1© - path 2© (path difference) reflect from higher n ⇒ extra λ/2 path change.
∆x = mλ (constructive interference) ∆x = (m+ 1/2)λ (destructive interference)
Polarization:
I = I0 cos2 θ (transmission thru polarizer) I = 12I0 (transmission of unpolarized light)
Chapter 25 Equations
Cameras
f/D = f-number, or lens aperture film exposure = exposure time / f-number.1do
+ 1di
= 1f (lens equation) m = −di/do = hi/ho (image size and magnification)
Lens power
P = 1/f (power in diopters).
Vision correction
Far point FP = ∞. (good vision) Near point = NP ≤ 25 cm. (good vision)
Nearsighted. Use lens to get FP=∞. Farsighted. Use lens to get NP=25 cm.
Simple magnifier
θ = h0NP (angular size viewed at NP.) θ′ = h0
d0(angular size viewed at any d0.)
M = θ′θ = NP
do(ang. Mag. viewed at any d0.) M = θ′
θ = NPf (ang. Mag. viewed at d0 = f .)
Telescopes
M = θ′θ = fobj
feye(angular magnification)
Eq.-2
Prefixesa=10−18, f=10−15, p=10−12, n=10−9, µ = 10−6, m=10−3, c=10−2, k=103, M=106, G=109, T=1012, P=1015
Physical Constants
k = 1/4πε0 = 8.988 GN·m2/C2 (Coulomb’s Law) ε0 = 1/4πk = 8.854 pF/m (permittivity of space)e = 1.602× 10−19 C (proton charge) µ0 = 4π × 10−7 T·m/A (permeability of space)me = 9.11× 10−31 kg (electron mass) mp = 1.67× 10−27 kg (proton mass)c = 3.00× 108 m/s (speed of light) c = 2.99792458× 108 m/s (exact value in vacuum)h = 6.62607× 10−34 J·s (Planck’s constant) h = 1.05457× 10−34 J·s (Planck’s constant/2π)σ = 5.67× 10−8 W/(m2·K4) (Stefan-Boltzmann const.) hc =1239.84 eV·nm (photon energy constant)
Units
NA = 6.02× 1023/mole (Avogadro’s #) 1 u = 1 g/NA = 1.6605× 10−27 kg (mass unit)1.0 eV = 1.602× 10−19 J (electron-volt) 1 V = 1 J/C = 1 volt = 1 joule/coulomb1 F = 1 C/V = 1 farad = 1 C2/J 1 H = 1 V·s/A = 1 henry = 1 J/A2
1 A = 1 C/s = 1 ampere = 1 coulomb/second 1 Ω = 1 V/A = 1 ohm = 1 J·s/C2
1 T = 1 N/A·m = 1 tesla = 1 newton/ampere·meter 1 G = 10−4 T = 1 gauss = 10−4 tesla
Chapter 22 Equations
Electromagnetic waves:| $E|/| $B| = c = 1/√ε0µ0, (fields) fλ = c (wave equation)
Approximate wavelengths λ for types of EM waves:0 (γ-rays) 30 pm (x-rays) 3 nm (uv) 400 nm (visible) 700 nm (ir) 300 µm (µ-waves) 3 cm (radio) ∞
−→ −→ −→ increasing wavelength −→ −→ −→
Chapter 26 Equations
Time dilation and length contraction:∆t = γ∆t0 = ∆t0/
√1− v2/c2 L = L0/γ = L0
√1− v2/c2
γ = 1/√
1− v2/c2 (relativistic factor) v/c =√
1− 1/γ2 (velocity)
Dyanmics, mass, energy:p = γm0v (relativistic momentum) mrel = γm0 (relativistic mass)E0 = m0c2 (rest energy) E = γm0c2 = mrelc2 (relativistic energy)KE = E −E0 = (γ− 1)m0c2 (kinetic energy) E = E0 + KE =
√p2c2 + m2c4 (relativistic energy)
Eq.-1
Chapter 27 Equations
Blackbody radiation, photons, photo-electric effect:λpT = 2.90 mm·K (Wien’s Law) I = σT 4 (intensity or power/area)E = nhf, n = 1, 2, 3... (quantized radiation energy) E = hc/λ = (1240 eV · nm)/λ (photons)E = hf = W0 + KEmax (photo-electrons) hc/λmax = W0 (work function)KEmax = eV0 (stopping potential) vmax =
√2KEmax/m (max. speed)
Momentum, matter waves:p = h/λ (photon momentum) λ′ = λ + h
mc (1− cos φ) (Compton effect)λ = h/p = h/(mv) (de Broglie wavelength) v =
√2q∆V/m (acceleration thru potential)
Bohr Model:hf = En − En′ (quantum jump) L = mvr = n h
2π (Bohr’s quantization)
rn = n2
Z r1 (Bohr radii) r1 = h2
4π2mke2 = 52.9 pm (1st Bohr radius)
En = −(13.6 eV)Z2
n2 (Bohr energies) En = 12mv2 − kZe2
rn(total energy)
n = 1, 2, 3, ... (Bohr’s quantum number)
Chapter 28 Equations
Wave functions:N ∝ I ∝ | $E|2 (photon detection) N ∝ |Ψ|2 (particle detection)
Heisenberg Uncertainty Principle:∆x ∆px ≥ h (uncertainty principle) h = h
2π = 1.05459× 10−34 J·s∆E ∆t ≥ h (energy-time form) (← These are approximate relations.)∆E = ∆m · c2 (Einstein’s mass-energy equivalence) (← This one is exact.)
Quantum numbers for atoms:principle quantum number n = 0, 1, 2, 3... En = −(13.6 eV)/n2 (energy of hydrogen states)orbital quantum number l = 0, 1, 2...(n− 1) L =
√l(l + 1) h (angular momentum mag.)
magnetic quantum number ml = −l to + l Lz = mlh (z-component of $L)spin quantum number ms = − 1
2 , + 12 Sz = msh (z-comp., spin angular momentum)
shell means a particular value of (n) is given. sub-shell means values of (n, l) are given.orbital means particular (n, l,ml) are given. state means particular (n, l,ml,ms) are given.l = 0, 1, 2, 3, 4, 5, 6... are indicated with respective letters: s, p, d, f, g, h,...Pauli exclusion principle: No two electrons in an atom can occupy the same quantum state.Subshells in order of increasing energy: 1s, 2s, 2p, 3s, 3p, 4s, 3d, 4p, 5s, 4d, 5p, 6s, 4f, 5d, 6p, 7s, 5f, 6d, 7p(They fill in order of increasing n + l, or increasing n if there is a tie.)
Eq.-2
Prefixes
a=10−18, f=10−15, p=10−12, n=10−9, µ = 10−6, m=10−3, c=10−2, k=103, M=106, G=109, T=1012, P=1015
Physical Constants
k = 1/4πε0 = 8.988 GN·m2/C2 (Coulomb’s Law) ε0 = 1/4πk = 8.854 pF/m (permittivity of space)e = 1.602× 10−19 C (proton charge) µ0 = 4π × 10−7 T·m/A (permeability of space)c = 3.00× 108 m/s (speed of light) c = 2.99792458× 108 m/s (exact value in vacuum)me = 9.1094× 10−31 kg = (electron mass) mp = 1.67262× 10−27 kg = (proton mass)mn = 1.67493× 10−27 kg = (neutron mass) hc = 1240 eV·nm (photon energy = hc/λ)h = 6.6262× 10−34 J·s (Planck’s constant) h = 1.05459× 10−34 J·s (Planck’s constant/2π)
Units
NA = 6.02× 1023/mole (Avogadro’s #) 1 u = 1 g/NA = 1.6605× 10−27 kg = 931.5 MeV/c2
1.0 eV = 1.602× 10−19 J (electron-volt) 1 V = 1 volt = 1 J/C = 1 joule/coulomb1 F = 1 farad = 1 C/V = 1 C2/J 1 H = 1 henry = 1 V·s/A = 1 J/A2
1 A = 1 ampere = 1 C/s = 1 coulomb/second 1 Ω = 1 ohm = 1 V/A = 1 J·s/C2
1 T = 1 tesla = 1 N/A·m = 1 newton/ampere·meter 1 G = 1 gauss = 10−4 T = 10−4 tesla1 Bq = 1 becquerel = 1 decay/s 1 Ci = 1 curie = 3.70× 1010 decays/s = 37.0 GBq
Some Masses (for neutral atoms)
electron = 0−1e = 0.00054858 u = 0.51100 MeV/c2 proton = 11p = p =1.007276 u = 938.27 MeV/c2
neutron = 10n = n = 1.008665 u = 939.57 MeV/c2 hydrogen = 1
1H = 1.007825 u = 938.78 MeV/c2
deuterium = 21H = d = 2.014102 u tritium = 3
1H = t = 3.016049 uhelium-3 = 3
2He = 3.016029 u helium-4 = 42He = α = 4.002603 u
Chapter 30 Equations
Nuclides:
A = N + Z, (mass, neutron, proton numbers) r = (1.2 fm) A1/3 (nuclear radius)
∆E =[(mass of parts) - (mass of nuclide)]c2 (binding energy)
Q = [Mparent −Mproducts]c2 (disintegration energy)
Half-life and decay constant
N = N0e−λt (decay of parent nuclei)∣∣∆N∆t
∣∣ = Nλ (radio-activity)
t = −1λ ln(N/N0) (time when N nuclei remain) M = Nm = mass = (# of nuclei)×(nuclear mass)
λT 12= ln 2 (decay constant, half-life) τ = 1
λ (mean life time)
#(146C)/#(126C) = 1.2× 10−12 (live carbon ratio) 1 year = 3.156× 107 seconds
Chapter 31 Equations
Reactions:
Q = [Mreactants −Mproducts]c2 (reaction energy)
Q > 0 (Q = mass converted to energy) Q < 0 (|Q| = threshold energy)
Energy, power and mass in nuclear reactors:
E = mc2 (Einstein’s mass-energy equivalence) P = E/t (power)
E = NQ [energy= (# of reactions)×(reaction energy)] 1 u · c2 = 931.5 MeV
M = Nm [mass used= (# of reactions)×(reaction mass)]
Eout = eEin [output energy = (efficiency)×(input energy)]
Eq.-1