Eastman Briefs FOR MARCH

1
FOR MARCH Ο Ο C Il II I c-c-c-c-o-c-c I c t-Butyι Acetoacetate Form liquid Specific gravity, 60°/80°F 0.965 Boiling point, 760 mm 17U°C. TBAA offers organic chemists a useful means of circumventing certain unwanted hydrolyses. You can alkylate it and convert to the alkylated acetone simply by heating with a trace of acid. Quick, simple, safe. Eastman Chemical Products, Inc. Kingsport, Tennessee B6S C I N=C-C-C-C-CHO C 4-Cyano-2,2-dimethylbutyraldehyde Form colorless to amber liquid Specific gravity, 20°/20°C 0.9U98 Boiling point, 5 mm 92-9i°C. Assay, minimum 96% To save breath we call this compound ibanitrile, or more simply, IBAN. Reactionsof ibanitrile—includ- ing hydrolysis, oxidation, reduction, and condensa- tion are shown in a technical data sheet. Use the handy coupon to obtain your copy. Eastman Chemical Products, Inc. Kingsport, Tennessee B68 C-C=C-CHO Crotonaldehyde Form liquid Specific gravity, 20°/20°C 0.869 Color, ΛΓΗΛ J^O ppm Assay, minimum, as water azeotrope 89 % Writing about crotonaldehyde is like writing a general organic text. So varied are its reactions that it and its derivatives find use in everything from food additives to textiles, gasoline to pickling agents. Eastman Chemical Products, Inc. Kingsport, Tennessee B66 c o c I II I HO-C-C-C-O-C-C-C-OH I I c c Hydroxy pi valy I Hy d roxy pi valate (Neo- pentyl Glycol Monohydroxy-pivalate) Form * .... , ..... crystalline solid Melting range 43-53°C. Boiling point, 760 mm 290°C. Molten color, ΑΡΗ A 90 ppm An interesting new glycol for developing polyester, urethane and other resins, plasticizers and more com- plicated molecules. HPHP offers a pleasing and useful near-symmetry based on the stable neopentyl configuration. The hydroxyls are nicely reactive, the internal ester link not overly so. Eastman Chemical Products, Inc. Kingsport, Tennessee B67 CO C C I II I I c=c-c-o-c-c-c-c-c I I C R RisOHorCH 2 C(CH 3 )COO Trimethyipentanediol Methacrylate Form liquid Ester ratio, approximate 70% di; 30% mono Inhibitor 20 ppm This mixture of monomers has obvious applications in polymerization reactions. T g of copolymers can be raised, solvent resistance improved, and nu- merous other rheological and chemical properties modified. The inhibitor is hydroquinone mono- methyl ether. Eastman Chemical Products, Inc. Kingsport, Tennessee B69 Chemicals Sales Development Dept. cc Eastman Chemical Products, Inc. subsidiary of Eastman Kodak Company Kingsport, Tennessee Please send more data on these chemicals: ΒββΠ ΒββΠ Ββ7Π ΒββΠ ΒβθΠ Company City Zip Code CUP AND FILE AOVERTISEMENTc C & Ε Ν 29 iEia.s'tm.a.rL B r i e f s State Name Title Address

Transcript of Eastman Briefs FOR MARCH

Page 1: Eastman Briefs FOR MARCH

FOR MARCH Ο Ο C Il II I

c-c-c-c-o-c-c I c

t -Buty ι A c e t o a c e t a t e Form liquid Specific gravity, 60°/80°F 0.965 Boiling point, 760 mm 17U°C. TBAA offers organic chemists a useful means of circumventing certain unwanted hydrolyses. You can alkylate it and convert to the alkylated acetone simply by heating with a trace of acid. Quick, simple, safe. E a s t m a n C h e m i c a l P r o d u c t s , I n c . K i n g s p o r t , T e n n e s s e e B 6 S

C I

N = C - C - C - C - C H O C

4 - C y a n o - 2 , 2 - d i m e t h y l b u t y r a l d e h y d e Form colorless to amber liquid Specific gravity, 20°/20°C 0.9U98 Boiling point, 5 mm 92-9i°C. Assay, minimum 96% To save breath we call this compound ibanitrile, or more simply, IBAN. Reactionsof ibanitrile—includ­ing hydrolysis, oxidation, reduction, and condensa­tion are shown in a technical data sheet. Use the handy coupon to obtain your copy.

E a s t m a n C h e m i c a l P r o d u c t s , I n c . K i n g s p o r t , T e n n e s s e e B 6 8

C - C = C - C H O

C r o t o n a l d e h y d e Form liquid Specific gravity, 20°/20°C 0.869 Color, ΛΓΗΛ J^O ppm Assay, minimum, as water azeotrope 89 % Writing about crotonaldehyde is like writing a general organic text. So varied are its reactions that it and its derivatives find use in everything from food additives to textiles, gasoline to pickling agents.

E a s t m a n C h e m i c a l P r o d u c t s , I n c . K i n g s p o r t , T e n n e s s e e B 6 6

c o c I II I

H O - C - C - C - O - C - C - C - O H I I

c c H y d r o x y pi va ly I Hy d r o x y pi va la te ( N e o -p e n t y l G l y c o l M o n o h y d r o x y - p i v a l a t e ) Form * . . . . , . . . . . crystalline solid Melting range 43-53°C. Boiling point, 760 mm 290°C. Molten color, ΑΡΗ A 90 ppm An interesting new glycol for developing polyester, urethane and other resins, plasticizers and more com­plicated molecules. HPHP offers a pleasing and useful near-symmetry based on the stable neopentyl configuration. The hydroxyls are nicely reactive, the internal ester link not overly so.

E a s t m a n C h e m i c a l P r o d u c t s , I n c . K i n g s p o r t , T e n n e s s e e B 6 7

C O C C I II I I

c=c-c-o-c-c-c-c-c I I

C R RisOHorCH2C(CH3)COO

T r i m e t h y i p e n t a n e d i o l M e t h a c r y l a t e Form liquid Ester ratio, approximate 70% di; 30% mono Inhibitor 20 ppm This mixture of monomers has obvious applications in polymerization reactions. Tg of copolymers can be raised, solvent resistance improved, and nu­merous other rheological and chemical properties modified. The inhibitor is hydroquinone mono-methyl ether. E a s t m a n C h e m i c a l P r o d u c t s , I n c . K i n g s p o r t , T e n n e s s e e B 6 9

Chemicals Sales Development Dept. c c

E a s t m a n C h e m i c a l P r o d u c t s , I n c . subsidiary of Eastman Kodak Company Kingsport, Tennessee Please send more data on these chemicals:

Β β β Π Β β β Π Β β 7 Π Β β β Π Β β θ Π

Company

City Zip Code

CUP AND FILE AOVERTISEMENTc

C & Ε Ν 29

iEia.s'tm.a.rL Br ie fs

State

Name

Title

Address