Controlling Dust in Uranium Plants
Transcript of Controlling Dust in Uranium Plants
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Controlling Dust in Uranium Plants Radiation complicates ventilation and dust control
in large-scale processing of uranium, but standard industrial hygiene engineering principles still apply
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CHICAGO.—Refining uranium ores and concentrates on a large scale presents many ventilation and dust control problems. Even though radiation encountered necessitates extraordinarily stringent requirements, Catalytic Construction Co. approached the problem of designing a plant for AEC with the usual industrial hygiene engineering principles, company's H. I. Miller, Jr., told the 1954 Industrial Health Conference held here. Some idea of scope of the project may be gained from fact that cost for ventilation and dust control systems came to about $2 million for installation and 120 engineer-months effort for engineering design. This cost was a small fraction of total cost of plant.
Alpha rays from uranium are ordinarily harmless, but when particles emitting them are ingested they can be quite harmful. Daughter products in pitchblende give off beta rays which are also relatively harmless. However, gamma ray emitters are also present, and these can be quite dangerous. Product value and toxicity indicate dust-tight equipment so that as little dust as possible will have to be collected and rehandled. Buildings in which pitchblende is handled are walled off from rest of plant.
Use of tank car quantities of hydrofluoric acid does nothing to ease design problems, Miller notes. Most hydrofluoric is handled in wal led-up areas. Buildings where hydrofluoric is handled are ventilated so that there a r e 15 air changes per hour. This is on assumption that all equipment is t ight; for emergency use it is possible t o change air 60 times an hour. I t is readily seen that heat losses of some of these buildings are small compared to t h a t lost by exhausting air.
As an example of unusual difficulties to be solved, Miller told of cleaning exhaust from a rotary d ryer when feed might contain 5 to 10% dust-size particles. Temperature of exliaust air was ordinarily 400° F. , bu t on occasion it might reach 600° F . This hot air could not be sent directly to wet collector bu t must be first cooled to 180° F . A heat exchanger w a s needed to cool the stream. Cyclone separators had to be included in equipment . Because exhaust contained moisture, there was a question of dew point t o be considered and suitable instrumentation had to be provided so that heat exchanger would not cool air t o o much.
Fog Scrubbers . Dust collection, gas and mist scrubbing, and odor elimination are some applications of fog type
F. A. Thomas, Jr. (left), Georgia Tech, M. W. First, consultant, and Jack Baliff, New York State Department of Labor, tackle dust control in different ways. Thomas told the Industrial Health Conference of design of fog type scrubbers, First evaluated wet fiber filter, while Baliff described water spray system used in a rock-crushing plant
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scrubbers. Fog (generated either by passing scrubbing medium under high pressure through small orifices, or by introducing it under low pressure through jets into a high velocity air stream) comes in contact with gas stream being cleaned and particles or other impurities are removed. Present thinking, according to F. A. Thomas, Jr., Georgia Tech, is that impaction, wetting, and centrifugal action are probably most important mechanisms involved, although not enough is yet known to determine relative importance of these. Small particles (less than 10 microns) are difficult to separate from a gas stream merely by their inertia. In fog scrubbers, these particles combine with other particles or with drops of scrubbing medium to give a n e w particle having enough inertia to be centrifuged from stream.
For maximum impaction rate, fog particles should have a size distribution comparable with that of particular matter being removed. If spray drops are large, particles tend to flow around the drop. In removing gases of reacting chemicals from polluted air streams, fog scrubbers function by providing a large surface of scrubbing medium. Action might be primarily a surface phenomenon, but not entirely
so, Thomas says. Fact that fog scrubbing has been effective with oil mists indicates possible electrostatic effects.
Entrainment of scrubbing med ium in discharge air stream decreases wi th increasing pressures and air flow rates for moderate and high fog pressures. It increases to a maximum arid then decreases with increasing air flow rates for low and marginal fog pressure. Entrainment can be reduced or eliminated by using high pressure scrubbing section prior to discharge of air.
Fume Hoods . By measuring face velocity and observing smoke patterns in lab fume hoods with varying face velocities, cross draft velocities, thermal loadings, slot openings, entrance shapes, and other factors, H. F. Schulte, Los Alamos Scientific Laboratory, evaluated a number of hoods. H e found that an average face velocity of 100 ft. per minute and a minimum velocity of 80 ft. per minute at any point on hood face is necessary w h e n moderately toxic materials are handled .
Not only should attention b e paid to ordinary safety considerations w h e n locating a hood in the lab, but hood should b e placed so as to avoid cross drafts from air inlets and other sources of air disturbance. Schulte finds that w h e n velocity of cross current air
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equals or exceeds face velo-city, serious disturbances result. H e aJso points out that a radiator loc-ated near a hood loses almost all of i t s h_eat to exhaust.
Experiments with hot plates and Meeker burners d i d n o t adversely affect hood perfonrt ance as long as velocity w a s 10O ft. p>er m i n u t e . Doors do not contribute much t o function of hoods except US safety precautions. Corner posts create disturbances a s do sinks and other «depressions. 3Front side of a sink should be a t least 63 in. back from front of hood.
• Combustible gas d e t e c t o r s for installation in Class I, Group JD hazardous locations t o analyze a n d warn of dangerous concentrations o£ combustible gas have been listed for the first time by Underwriters' Labs, according to Mine Safety Appliances, manufacturers of the instruments. Company says its instruments have also received approval from Associated Factory Mutual F i r e Lalbs,
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• A fire-retard «ant paint- s a i d to combine superior flam«e resistance with durability, -wasbability, a n d attractiveness is available from Glidden Co. Called D u o - T e x , it is a res£n-base, intumescent t y p e intexior finish that immediately swe l l s anol chars on contact with flame to p r o v i d e a firm, insulating blanket of non comb Tistible ash . Avai l able in 12 pastel colors, it bears the label of Underwritexs' L a b s , according to Glidden. It can b>e appl ied by brush or spray. S 3
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1934 C H E M I C A L A N D E N G I N E E R I N G N E W S