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FormulasShort AnswerCompetenciesProblems Units
Rate Law Expression
Rate = k[A]m[B]n…
ΔSrxn =
[Products] – [Reactants]
C6H14 + Cl2 –>
Cl |
CH3-CH2-CH-CH2-CH2-CH3
Radioactive Decay Formula
Ln(A/A0) = -kt
Nernst equation
E = E0 – .0592/n log (K)
Which electrolyte half-reaction is reversed in a spontaneous
electrolytic cell?
The half-reaction with the
least positive voltage.
How are electrons transferred in an oxidization half-
reaction?
The electrons are lost.
Bronsted-Lowry acid-base theory states:
The hydrogen donor is the acid and the hydrogen acceptor is
the base.
In net ionic equations, what is the rule for strong
substances?
Strong substances automatically dissociate
in water and do not form.
What are the four steps in balancing
half-reactions using the ion-electron
method?
1. Balance all elements except H and O.
2. Balance O with H2O.3. Balance H with H+.4. Balance the charges of
both sides by adding electrons to the more positive side.
Determine the pH of a solution
having [H+] = 5.7 x 10-3.
pH = 2.24
Experiment Initial [A] Initial Rate1 0.30 M 1.2 x 10-4 Msec2 0.60 M 2.4 x 10-4 Msec
Determine the order of the reaction with respect to A.
A is 1st order.
Give the oxidation number for Sulfur
in H2SO4.
S = 6+
[Co(NH3)2(ONO)4]I2
Name:Coordination Sphere:Center of Coordination:Ligands:Coordination Number:
Name = Diamminetetranitritocobalt(VI) IodineCoordination Sphere = [Co(NH3)2(ONO)4]2+
Center of Coordination = Co6+
Ligands = 2 NH3, 4 ONOCoordination Number = 6
Outline the synthesis for 2-propanone.
OH O
| ||
CH3CH2CH3 + [O] –> CH3CHCH3
Write the shorthand notation for a voltaic cell
using:Ag1+ +.80 Ag , Fe3+ .77 Fe2+
Fe2+/Fe3+//Ag1+/Ag
9642Mo –> 4
2He + _____
9240Zr
Determine the voltage associated with the
following half reaction at 25˚C if [I-] = 5.2 x 10-4.
I2(s) + 2e- -> 2I- E˚ = .54v
.73v
Give the straight chained structure for
ketoheptose
CH2O
|
C = O
|
H – C – OH
|
H – C – OH
|
H – C – OH
|
H – C – OH
|
CH2O
Write the balanced net ionic equation for the reactions expected
when aqueous solutions of each substance are mixed .
H2SO3 + NH3
H2SO3 + 2NH3 –> 2NH4+ + SO3
What is the units on a [H+]?
M
What is the unit of E˚?
v
What is Faraday’s constant?
9.65 x 104 C/mol e-
What unit is on the rate constant, k, for a reaction that
is 2nd overall order?
1/(Msec)
What are amperes?
C / sec
Final Jeopardy
The Category is:
Organic Chemistry
Outline a synthesis to make N,N,3-trimethylbutanamide
CH3 O CH3
| || |CH3-CH2-CH2-C-Cl + H-N-CH3 –>
CH3 O | ||CH3-CH2-CH2-C-N-CH3
| CH3