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200 300 400 500 100 200 300 400 500 100 200 300 400 500 200 400 600 800 1000 100 200 300 400 500 100 Formulas Short Answer Competencies Problems Units

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Formulas. Short Answer. Competencies. Problems. Units. 100. 100. 100. 200. 100. 200. 200. 200. 400. 200. 300. 300. 300. 600. 300. 400. 400. 400. 800. 400. 500. 500. 500. 1000. 500. Rate Law Expression. Rate = k[A] m [B] n …. Δ S rxn =. [Products] – [Reactants]. - PowerPoint PPT Presentation

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FormulasShort AnswerCompetenciesProblems Units

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Rate Law Expression

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Rate = k[A]m[B]n…

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ΔSrxn =

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[Products] – [Reactants]

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C6H14 + Cl2 –>

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Cl |

CH3-CH2-CH-CH2-CH2-CH3

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Radioactive Decay Formula

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Ln(A/A0) = -kt

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Nernst equation

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E = E0 – .0592/n log (K)

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Which electrolyte half-reaction is reversed in a spontaneous

electrolytic cell?

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The half-reaction with the

least positive voltage.

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How are electrons transferred in an oxidization half-

reaction?

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The electrons are lost.

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Bronsted-Lowry acid-base theory states:

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The hydrogen donor is the acid and the hydrogen acceptor is

the base.

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In net ionic equations, what is the rule for strong

substances?

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Strong substances automatically dissociate

in water and do not form.

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What are the four steps in balancing

half-reactions using the ion-electron

method?

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1. Balance all elements except H and O.

2. Balance O with H2O.3. Balance H with H+.4. Balance the charges of

both sides by adding electrons to the more positive side.

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Determine the pH of a solution

having [H+] = 5.7 x 10-3.

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pH = 2.24

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Experiment Initial [A] Initial Rate1 0.30 M 1.2 x 10-4 Msec2 0.60 M 2.4 x 10-4 Msec

Determine the order of the reaction with respect to A.

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A is 1st order.

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Give the oxidation number for Sulfur

in H2SO4.

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S = 6+

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[Co(NH3)2(ONO)4]I2

Name:Coordination Sphere:Center of Coordination:Ligands:Coordination Number:

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Name = Diamminetetranitritocobalt(VI) IodineCoordination Sphere = [Co(NH3)2(ONO)4]2+

Center of Coordination = Co6+

Ligands = 2 NH3, 4 ONOCoordination Number = 6

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Outline the synthesis for 2-propanone.

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OH O

| ||

CH3CH2CH3 + [O] –> CH3CHCH3

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Write the shorthand notation for a voltaic cell

using:Ag1+ +.80 Ag , Fe3+ .77 Fe2+

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Fe2+/Fe3+//Ag1+/Ag

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9642Mo –> 4

2He + _____

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9240Zr

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Determine the voltage associated with the

following half reaction at 25˚C if [I-] = 5.2 x 10-4.

I2(s) + 2e- -> 2I- E˚ = .54v

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.73v

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Give the straight chained structure for

ketoheptose

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CH2O

|

C = O

|

H – C – OH

|

H – C – OH

|

H – C – OH

|

H – C – OH

|

CH2O

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Write the balanced net ionic equation for the reactions expected

when aqueous solutions of each substance are mixed .

H2SO3 + NH3

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H2SO3 + 2NH3 –> 2NH4+ + SO3

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What is the units on a [H+]?

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M

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What is the unit of E˚?

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v

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What is Faraday’s constant?

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9.65 x 104 C/mol e-

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What unit is on the rate constant, k, for a reaction that

is 2nd overall order?

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1/(Msec)

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What are amperes?

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C / sec

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Final Jeopardy

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The Category is:

Organic Chemistry

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Outline a synthesis to make N,N,3-trimethylbutanamide

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CH3 O CH3

| || |CH3-CH2-CH2-C-Cl + H-N-CH3 –>

CH3 O | ||CH3-CH2-CH2-C-N-CH3

| CH3