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116 228 Chapter 22. Carbonyl Alpha-Substitution Reactions O ! " #!' "' #' H O carbonyl O H O Enol Enolate E O E+ E+ 229 Tautomers: isomers, usually related by a…

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1 2 Trimethyl, tributyl and triphenyltines- ters of 3- and 4- aminobenzoic acids have been synthesized and charac- terized by a variety of spectroscopic methods in- cluding…

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3 OHC OH O 1) CH3ONa, CH3OH 2) HCl, CH3OH O OH H3CO OH O HO OH 1 2 3 2 O CH3O–H O OH O O– OH 1) H+ O OH OH 2) β- H+ H+ O O OH H H H H HO O H+ H2O O O CH3OH O OH3CO H…

PGH2 PGF2α PI4,5P2 PI3,4,5P3 IP3+DG Ca2+ TG ! PGD2 PGE2 TXA2 PGI2 HO OH OH O O OH OH O O O O OH O OH OH O HO HO OH OH O HO O O OH O OH O OH HO OH O Figure 15-14a Molecular…