MATERIAL SAFETY DATA SHEET - Hanwha Chemicalhcc.hanwha.com/download/msds_cm150_eng.pdf · MATERIAL...

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MATERIAL SAFETY DATA SHEET 01. Identification of the substance or mixture and of the supplier A. GHS product identifier : HANOS CNT, MULTI-WALLED, CM-150 B. Recommended use of the chemical and restrictions on use ο Recommended use : Transparent conductive films, Composite, Secondary battery electrode conductive additive, Solar battery electrode additive, DMFC while- gold catalyst medium, EDLC electrode conductive additive, Lighting/BLU, Nano device ο Restrictions on use : Not Available. C. Manufacturer / Supplier / Distributor information ο Company: Hanwha Chemical Corporation ο Address: 3F SHINE BUILDING, 423-1, Cheongcheon-Dong, Bupyeong-Gu, Incheon, KOREA ο Emergency response number: (TEL) +82-32-513-7114 / (FAX) +82-32-513- 7986 ο Division: Bupyeong Plant 02. Hazards identification A. GHS classification of the substance/mixture ο Acute toxicity (dermal) : Category 5 ο Respiratory sensitization : Category 1 ο Skin sensitization : Category 1 ο Carcinogenicity : Category 2 ο Hazardous to the aquatic environment (acute hazard) : Category 2 B. GHS label elements, including precautionary statements ο Pictogram and symbol : ο Signal word : Danger ο Hazard statements : H313 : May be harmful in contact with skin. H317 : May cause an allergic skin reaction. H334 : May cause allergy or asthma symptoms or breathing difficulties if inhaled. H351 : Suspected of causing cancer. H401 : Toxic to aquatic life.

Transcript of MATERIAL SAFETY DATA SHEET - Hanwha Chemicalhcc.hanwha.com/download/msds_cm150_eng.pdf · MATERIAL...

Page 1: MATERIAL SAFETY DATA SHEET - Hanwha Chemicalhcc.hanwha.com/download/msds_cm150_eng.pdf · MATERIAL SAFETY DATA SHEET 01. Identification of the substance or mixture and of the supplier

MATERIAL SAFETY DATA SHEET

01. Identification of the substance or mixture and of the supplier

A. GHS product identifier : HANOS CNT, MULTI-WALLED, CM-150

B. Recommended use of the chemical and restrictions on use

ο Recommended use : Transparent conductive films, Composite, Secondary

battery electrode conductive additive, Solar battery electrode additive, DMFC while-

gold catalyst medium, EDLC electrode conductive additive, Lighting/BLU, Nano

device

ο Restrictions on use : Not Available.

C. Manufacturer / Supplier / Distributor information

ο Company: Hanwha Chemical Corporation

ο Address: 3F SHINE BUILDING, 423-1, Cheongcheon-Dong, Bupyeong-Gu,

Incheon, KOREA

ο Emergency response number: (TEL) +82-32-513-7114 / (FAX) +82-32-513-

7986

ο Division: Bupyeong Plant

02. Hazards identification

A. GHS classification of the substance/mixture

ο Acute toxicity (dermal) : Category 5

ο Respiratory sensitization : Category 1

ο Skin sensitization : Category 1

ο Carcinogenicity : Category 2

ο Hazardous to the aquatic environment (acute hazard) : Category 2

B. GHS label elements, including precautionary statements

ο Pictogram and symbol :

ο Signal word : Danger

ο Hazard statements :

H313 : May be harmful in contact with skin.

H317 : May cause an allergic skin reaction.

H334 : May cause allergy or asthma symptoms or breathing difficulties if inhaled.

H351 : Suspected of causing cancer.

H401 : Toxic to aquatic life.

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ο Precautionary statements

• Precaution

P201 : Obtain special instructions before use.

P202 : Do not handle until all safety precautions have been read and understood.

P261 : Avoid breathing dust/fume/gas/mist/vapours/spray.

P272 : Contaminated work clothing should not be allowed out of the workplace.

P273 : Avoid release to the environment.

P280 : Wear protective gloves/protective clothing/eye protection/face protection.

P281 : Use personal protective equipment as required.

P285 : In case of inadequate ventilation wear respiratory protection.

• Treatment

P302+P352 : If on skin: Wash with plenty of soap and water.

P304+P341 : If inhaled: If breathing is difficult, remove victim to fresh air and

keep at rest in a position comfortable for breathing.

P308+P313 : If exposed or concerned: Get medical advice/ attention.

P312 : Call a poison center or doctor/physician you feel unwell.

P321 : Specific treatment is urgent.

P333+P313 : If skin irritation or rash occurs: Get medical advice/attention.

P342+P311 : If experiencing respiratory symptoms: Call a poison center or

doctor/physician.

P363 : Wash contaminated clothing before reuse.

• Storage

P405 : Store locked up.

• Disposal

P501 : Dispose the contents/container in accordance with

local/regional/national/international regulations.

C. Other hazard information not included in hazard classification (NFPA)

ο Health : 2

ο Flammability : -

ο Reactivity : -

03. Composition/information on ingredients

Chemical Name Common Name(Synonyms) CAS number EC number Content(%)

Multi-Walled

Carbon Nanotubes

(MWCNT)

• Baytubes

• Baytubes C 150 P

• Baytubes C 150 HP

• Baytubes C 70 P

• Baytubes DP

- 936-414-1 > 90

Iron • Ferrum 7439-89-6 231-096-4 < 3

COBALT

• Cobalt metal powder

• Cobalt metal, dust and

fume

7440-48-4 231-158-0 < 4

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Aluminum • AL POWDER 7429-90-5 231-072-3 < 3

04. First aid measures

A. Eye contact

- Call emergency medical service.

- In case of contact with substance, immediately flush skin or eyes with running

water for at least 20 minutes.

B. Skin contact

- If skin irritation or rash occurs: Get medical advice/attention.

- Wash contaminated clothing before reuse.

- For hot product, immediately immerse in or flush the affected area with large

amounts of cold water to dissipate heat.

- Call emergency medical service.

- Remove and isolate contaminated clothing and shoes.

- In case of contact with substance, immediately flush skin or eyes with running

water for at least 20 minutes.

- For minor skin contact, avoid spreading material on unaffected skin.

C. Inhalation

- If inhaled: If breathing is difficult, remove victim to fresh air and keep at rest in a

position comfortable for breathing.

- If exposed or concerned: Get medical advice/ attention.

- If experiencing respiratory symptoms: Call a poison center or doctor/physician.

- Move victim to fresh air.

- Keep victim warm and quiet.

D. Ingestion

- If exposed or concerned: Get medical advice/ attention.

- Do not use mouth-to-mouth method if victim ingested or inhaled the substance;

give artificial respiration with the aid of a pocket mask equipped with a one-way

valve or other proper respiratory medical device.

E. Indication of immediate medical attention and notes for physician

- Exposures require specialized first aid with contact and medical follow-up .

- Ensure that medical personnel are aware of the material(s) involved and take

precautions to protect themselves.

05. Fire fighting measures

A. Suitable (and unsuitable) extinguishing media

- Use alcohol foam, carbon dioxide, or water spray when fighting fires involving this

material.

- Use dry sand or earth to smother fire.

B. Specific hazards arising from the chemical

- May decompose at high temperatures into forming toxic gases.

- Containers may explode when heated.

- Some of these materials may burn, but none ignite readily.

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- Non-combustible, substance itself does not burn but may decompose upon heating,

then produce corrosive and/or toxic fumes.

C. Special protective equipment and precautions for fire-fighters

- Rescuers should put on appropriate protective gear.

- Evacuate area and fight fire from a safe distance.

- Substance may be transported in a molten form.

- Dike fire-control water for later disposal; do not scatter the material.

- Move containers from fire area if you can do it without risk.

- Fire involving Tanks; Fight fire from maximum distance or use unmanned hose

holders or monitor nozzles.

- Fire involving Tanks; Cool containers with flooding quantities of water until well

after fire is out.

- Fire involving Tanks; Withdraw immediately in case of rising sound from venting

safety devices or discoloration of tank.

- Fire involving Tanks; ALWAYS stay away from tanks engulfed in fire.

- Fire involving Tanks; For massive fire, use unmanned hose holders or monitor

nozzles; if this is impossible, withdraw from area and let fire burn.

06. Accidental release measures

A. Personal precautions, protective equipment and emergency procedures

- Avoid breathing dust/fume/gas/mist/vapours/spray.

- Clean up spills immediately, observing precautions in Protective Equipment section.

- Eliminate all ignition sources.

- Stop leak if you can do it without risk.

- Do not touch damaged containers or spilled material unless wearing appropriate

protective clothing.

- Cover with plastic sheet to prevent spreading.

- Prevent dust cloud.

- Please note that there are materials and conditions to avoid.

B. Environmental precautions and protective procedures

- Prevent entry into waterways, sewers, basements or confined areas.

C. The methods of purification and removal

- Absorb spills with inert material (e.g., dry sand or earth), then place in a chemical

waste container.

- Absorb the liquid and scrub the area with detergent and water.

- Large Spill; Dike far ahead of liquid spill for later disposal.

- With clean shovel place material into clean, dry container and cover loosely; move

containers from spill area.

- Powder Spill; Cover powder spill with plastic sheet or tarp to minimize spreading

and keep powder dry.

- Small Spill; Take up with sand or other non-combustible absorbent material and

place into containers for later disposal.

07. Handling and storage

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A. Precautions for safe handling

- Do not handle until all safety precautions have been read and understood.

- Avoid breathing dust/fume/gas/mist/vapours/spray.

- Contaminated work clothing should not be allowed out of the workplace.

- Use only in a well-ventilated area.

- Follow all MSDS/label precautions even after container is emptied because they

may retain product residues.

- Use carefully in handling/storage.

- Loosen closure cautiously before opening.

- Avoid prolonged or repeated contact with skin.

- Do not enter storage area unless adequately ventilated.

- Please note that there are materials and conditions to avoid.

- Be careful to high temperature.

B. Conditions for safe storage

- Store locked up.

- Empty drums should be completely drained, properly bunged, and promptly

returned to a drum reconditioner, or properly disposed of.

08. Exposure controls/personal protection

A. Occupational Exposure limits

ο Korea regulation

- Iron : TWA = 1 mg/m³

- COBALT : TWA = 0.02 mg/m³

- Aluminum: TWA = 10 mg/m³ (metal dust)

ο ACGIH regulation

- COBALT : TWA = 0.02 mg/m³

- Aluminum: TWA = 1 mg/m³ (resp)

ο OSHA regulation

- COBALT :

PEL: TWA 0.1 mg/m³

- Aluminum:

TWA = 15 mg/m³ (total), TWA = 5 mg/m³ (resp)

ο NIOSH regulation

- COBALT :

REL = TWA 0.05 mg/m³, IDLH = 20 mg/m³

- Aluminum:

TWA = 10 mg/m³ (total), TWA = 5 mg/m³ (resp)

ο Biological exposure index : Not available

ο EU regulation

- Iron :

Czech Republic: OEL-TWA = 10 mg/m³ (dust)

Slovak Republic: OEL-TWA = 6 mg/m³ (total aerosol)

- Aluminum:

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Belgium: OEL-TWA = 10 mg/m³

Czech Republic: OEL-TWA = 10 mg/m³ (dust)

United Kingdom: WEL-TWA = 10 mg/m³ (inhal), WEL-TWA = 4 mg/m³

(resp)

ο Other

- Iron :

Russia: OEL-TWA = 10 mg/m³ (aerosol)

- Aluminum:

Australia: OEL-TWA = 10 mg/m³ (dust), OEL-TWA = 5 mg/m³ (welding

fume)

Canada: OEL-TWA = 10 mg/m³ (dust)

China: OEL-PC-TWA = 3 mg/m³ (total)

B. Appropriate engineering controls

- Use process enclosures, local exhaust ventilation, or other engineering controls to

control airborne levels below recommended exposure limits.

- If user operations generate dust, fume, or mist, use ventilation to keep exposure

to airborne contaminants below the recommended exposure limit.

C. Personal protective equipment

ο Respiratory protection

- Wear a adequate respiratory protection equipment with certificate of Korea

Occupational Safety & Health Agency, by considering physicochemical properties of

exposed particulate material.

- In case exposed to particulate material, the respiratory protective equipments as

follow are recommended. ;facepiece filtering respirator or air-purifying respirator,

high-efficiency particulate air(HEPA) filter media or respirator equipped with

powered fan, filter media of use(dust, mist, fume)

- In lack of oxygen(< 19.5%), wear the supplied-air respirator or self-contained

breathing apparatus.

ο Eye protection

- Wear breathable safety goggles to protect from particulate material causing eye

irritation or other disorder.

- An eye wash unit and safety shower station should be available nearby work place.

ο Hand protection

- Wear appropriate protective gloves by considering physical and chemical

properties of chemicals.

ο Body protection

- Wear appropriate protective clothing by considering physical and chemical

properties of chemicals.

09. Physical and chemical properties

A. Appearance :

ο Description : Solid (diameter : 5 ~ 1,300 ㎛)

ο Color : Black

B. Odor : Not available

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C. Odor threshold : Not available

D. pH : Not available

E. Melting point/freezing point : 3,675℃ (Graphite)

F. Initial boiling point and boiling range : 4,197℃ (Graphite)

G. Flash point : Not available

H. Evaporation rate : Not available

I. Flammability (solid, gas) : Not available

J. Upper/lower flammability or explosive limits : Not available

K. Vapor pressure : Not available

L. Solubility (ies) : Not available

M. Vapor density : Not available

N. Specific gravity : 1.6 ~ 1.9

O. Partition coefficient: n-octanol/water : 2.42 ± 0.11

P. Auto ignition temperature : Not available

Q. Decomposition temperature : Not available

R. Viscosity : Not available

S. Surface area : 220 m2/g

T. Molecular weight : 12

010. Stability and reactivity

A. Chemical stability and Possibility of hazardous reactions :

- May decompose at high temperatures into forming toxic gases.

- Containers may explode when heated.

- Some of these materials may burn, but none ignite readily.

- Non-combustible, substance itself does not burn but may decompose upon

heating, then produce corrosive and/or toxic fumes.

B. Conditions to avoid :

- ignition sources (heat, sparks or flames)

C. Incompatible materials :

- combustibles, reducing agents

D. Hazardous decomposition products :

- corrosive and/or toxic fume

- irritating, corrosive and/or toxic gases

011. Toxicological information

A. Information of Health Hazardous

ο Acute toxicity

• Oral : Not classified (ATEmix ≥ 5,160.61 mg/kg bw)

- Multi-Walled Carbon Nanotubes (MWCNT): Rat, LD50 ≥ 5,000 mg/kg

(GLP, OECD TG 423)

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- Iron : Rat, LD50 = 98,600 mg/kg (OECD TG 401)

- COBALT : Rat, LD50 = 6,171 mg/kg (GLP, OECD TG 401)

- Aluminum: Rat, LD50 > 15,900 mg/kg (OECD TG 401)(read across;

Fumed alumina)

• Dermal : Not classified (ATEmix > 2,077.88 mg/kg bw)

- Multi-Walled Carbon Nanotubes (MWCNT): Rat, LD50 > 2,000 mg/kg

(GLP, OECD TG 402)

- COBALT : Rat, LD50 > 2,000 mg/kg (GLP, OECD TG 402)

• Inhalation : Not classified (ATEmix > 62.38 mg/L)

- Multi-Walled Carbon Nanotubes (MWCNT): Rat, LD50(4hr) >

295.13 mg/m3 (GLP, OECD TG 403)

- Iron : Rat, LD50(4hr)> 122.47 mg/ m3

- Aluminum: Rat, LC50 (4hr) > 0.888 mg/L (OECD TG 403)

ο Skin Corrosion/ Irritation : Not classified

- Multi-Walled Carbon Nanotubes (MWCNT):

No systemic intolerance reactions were observed in rabbits. Therefore, MWCNT

is not irritating to the skin. (GLP , OECD TG 404)

- Iron : It is not skin irritation in rabbits. (OECD TG 404)

- COBALT : Cobalt powder is not irritating to the skin.

- Aluminum: Aluminum oxide is not considered to be a primary skin irritant.

(OECD TG 404)(Read across; aluminum oxide)

ο Serious Eye Damage/ Irritation : Not classified

- Multi-Walled Carbon Nanotubes (MWCNT) :

No systemic intolerance reactions were observed in rabbits. Therefore, MWCNT

is not irritating to the eyes. (GLP, OECD TG 405)

- Iron : It is not eye irritation in rabbits. (OECD TG 405)

- COBALT : No eye irritation/corrosion effects were observed. (GLP)

- Aluminum: No eye irritation/corrosion effects were observed. According to the

FDA standards applied, aluminum oxide is not consideration eye

irritant. (Read across; aluminum oxide)

ο Respiratory sensitization : Category 1

- COBALT : In a single-case study on occupational exposure to cobalt resinate via

inhalation, there was a positive finding in a bronchio-constriction test

(decrease of FEV1 by ca. 30%).

- Aluminum: Aluminum oxide was the least inflammatory material tested and led to

only weak effects on the mouse lung. (Read across; aluminum oxide)

ο Skin Sensitization : Category 1

- Multi-Walled Carbon Nanotubes (MWCNT): In a guinea pig maximization test,

MWCNT is not sensitizing to the skin.

(GLP, OECD TG 406)

- Iron : Iron oxides can be considered as non sensitizing. (OECD TG 406)

- COBALT : Cobalt sulfate has sensitizing potential with rabbits. (OECD TG 406)

- Aluminum: In test with guinea pigs, aluminum oxide has no sensitization potential

under the experimental conditions. (Read across; aluminum oxide)

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ο Carcinogenecity : Category 2

• IARC :

- COBALT : 2B

• ACGIH :

- COBALT : A3

- Aluminum: A4

ο Mutagenicity : Not classified

- Multi-Walled Carbon Nanotubes (MWCNT) : In vitro(Bacterial gene mutation

test(GLP, OECD TG 471), mammalian

cell mutation assay(GLP, OECD TG

476), mammalian chromosome

aberration test(GLP, OECD TG

473))tests, any mutagenic activity

was not observed.

- Iron : Iron powders gave negative response in the Ames test in vitro performed.

(OECD TG 471)

- COBALT : No statistically significant increases in mutant frequency were

observed in ‘in vitro’- Mammalian Cell Gene Mutation Test(GLP, OECD

TG 476) and ‘in vivo’-chromosome aberration assay(OECD TG 475).

- Aluminum: Negative reactions were observed in ‘in vitro’-mammalian cell gene

mutation assay with mouse lymphoma L5178Y cells(OECD TG 476,

GLP) and ‘in vivo’-micronucleus assay with rats (OECD TG 474,

GLP). (Read across; aluminum hydroxide, aluminum chloride,

aluminum oxide)

ο Reproductive toxicity : Not classified

- COBALT : After oral exposure with mice, no effects on cultured embryos were

observed and Foetal skeletal ossification was significantly delayed.

- Aluminum: No reproduction, breeding and early postnatal developmental

toxicity were observed in rats. (GLP, OECD TG 422)(Read across;

Aluminum chloride)

ο Specific target organ toxicity (single exposure) : Not classified

- Multi-Walled Carbon Nanotubes (MWCNT): After the oral and dermal exposure

with rats, there were no clinical

signs, gross pathological findings

observed. After the inhalation

exposure with rats, at 10 mg/m³,

discolorations of the lung (light gray

areas) were observed at the day 7

sacrifice. (GLP)

- Iron : Treatment of rats by intratracheal instillation with 1 or 5 mg/kg carbonyl

iron did not result in mortality or local effects in the lung (biochemical,

cytological and histopathological).

- Aluminum: In test using rats, clinical signs of depression, laboured respiration,

piloerection and hunched appearance were noted at the highest dose

15900 mg/kg(OECD TG 401). (Read across; fumed alumina)

ο Specific target organ toxicity (repeat exposure) : Not classified

- Multi-Walled Carbon Nanotubes (MWCNT): After the sub-chronic inhalation

exposure with rats, nasal and

pulmonary inflammatory responses

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were observed.

- Iron : In a sub-acute inhalation study with carbonyl iron, rats are manifested with

a clear inflammatory reaction in the lungs and no systemic endpoints were

investigated(NOAEC=5 mg/m3).

- COBALT : Some evidence of carcinogenic activity in rats based on increased

incidences of alveolar/bronchiolar neoplasms and pheochromocytomas

of the adrenal medulla may have been related to exposure

(LOAEC=0.31mg/L).

- Aluminum: In test using rats, no critical clinical signs of toxicity were reported

over the observation period(OECD TG 422, GLP). (Read across ;

aluminum chloride)

ο Aspiration Hazard : Not applicable

012. Ecological information

A. Ecological toxicity

00 - Acute toxicity : Category 2 (ATEmix > 1.586mg/L)

00 - Chronic toxicity : Not classified

ο Fish :

- Multi-Walled Carbon Nanotubes (MWCNT): 96 hr-LD50(Salmo gairdneri) > 100

mg/L (GLP, EU Method C.1)

- Iron : 96 hr-LC50(Salvelinus fontinalis) = 0.9 mg/L

- Aluminum: 96 hr-LC50(Pimephales promelas) > 218.64 mg/L (GLP)(Read across ;

aluminum chloride hexahydrate)

ο crustacean :

- Multi-Walled Carbon Nanotubes (MWCNT): 48 hr-EC50(Daphnia magna) > 100

mg/L (GLP, OECD TG 202)

- Iron : 96 hr-EC50 (Leptophlebia marginata L.) = 63.9 mg/L

- COBALT : 48 hr-EC50(Daphnia magna) > 100 mg/L (GLP, OECD TG 202)

ο Algae :

- Multi-Walled Carbon Nanotubes (MWCNT): 72 hr-EC50(other) = 134 mg/L (GLP,

OECD TG 201)

B. Persistence and degradability

ο Persistence : Not available

ο Degradability : Not available

C. Bioaccumulative potential

ο Bioaccumulation : Not available

ο Biodegradation : Not available

D. Mobility in soil : Not available

E. Other hazardous effect : Not available

013. Disposal considerations

A. Disposal method

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0 Waste must be disposed of in accordance with federal, state and local environmental

control regulations.

B. Disposal precaution

Consider the required attentions in accordance with waste treatment management

regulation.

014. Transport information

A. UN Number : Not applicable

B. UN Proper shipping name : Not applicable

C. Transport Hazard class : Not applicable

D. Packing group : Not applicable

E. Marine pollutant : Not applicable

F. Special precautions

in case of fire : Not applicable

in case of leakage : Not applicable

015. Regulatory information

① KOREA Regulatory information

A. Occupational Safety and Health Regulation :

ο Iron : Administration subject listed, Occupational exposure limits listed

ο COBALT : Work environment monitoring listed, Administration subject listed,

Health examination agent

ο Aluminum: Administration subject listed, Work environment monitoring listed,

Occupational exposure limits listed, Health examination agent

B. Toxic Chemical Control Act :

ο Iron : Existing Chemical Substance (KE-21059)

ο COBALT : Existing Chemical Substance (KE-06060)

ο Aluminum: Existing Chemical Substance (KE-00881)

C. Dangerous Material Safety Management Regulation : Not regulated

D. Wastes Control Act :

ο Aluminum: Controlled Wastes

② Foreign Regulatory Information

ο External information

• EU classification(classification) :

* Iron : Not classified

* COBALT : R42/43, R53

* Aluminum: F; R15-17 (aluminum powder (pyrophoric)) F; R11-15 (aluminum

powder (stabilized))

• EU classification(risk phrases) :

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* Iron : Not applicable

* COBALT : R42/43, R53

* Aluminum: R11, R15

• EU classification(safety phrases) :

* Iron : Not applicable

* COBALT : S2, S22, S24, S37, S61

* Aluminum: S2, S7/8, S43

• EU SVHC list : Not regulated

• EU Authorisation List :

* COBALT : Not regulated

• EU Restriction list :

* Aluminum: Regulated

• U.S.A management information (OSHA Regulation) : Not regulated

• U.S.A management information (CERCLA Regulation) : Not regulated

• U.S.A management information (EPCRA 302 Regulation) : Not regulated

• U.S.A management information (EPCRA 304 Regulation) : Not regulated

• U.S.A management information (EPCRA 313 Regulation) :

* COBALT : Regulated

* Aluminum: Regulated

• Substance of Roterdame Protocol : Not regulated

• Substance of Stockholme Protocol : Not regulated

• Substance of Montreal Protocol : Not regulated

③ Foreign Inventory Status

• Iron :

- U.S.A management information : Section 8(b) Inventory (TSCA): Present

- Australia management information : Inventory of Chemical Substances (AICS):

Present

- Canada management information : Domestic Substances List (DSL): Present

- China management information : Inventory of Existing Chemical Substances

(IECSC): Present

- New Zealand management information : Inventory of Chemicals (NZIoC):

Present

- Philippines management information : Inventory of Chemicals and Chemical

Substances (PICCS): Present

• Aluminum:

- U.S.A management information: : United States - Section 8(b) Inventory

(TSCA): Present

- Australia management information: : Inventory of Chemical Substances

(AICS): Present

- China management information: : Inventory of Existing Chemical Substances

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(IECSC): Present

- Canada management information: : Inventory Domestic Substances List

(DSL): Present

- New Zealand management information:

Inventory of Chemicals (NZIoC): HSNO Approval: HSR001263 (coated, PGII)

HSNO Approval: HSR001471, HSR001473 (coated, PGIII)

HSNO Approval: HSR001474 (pyrophoric)

HSNO Approval: HSR001472 (uncoated, PGII)

- Philippines management information: : Inventory of Chemicals and Chemical

Substances (PICCS): Present

016. Other information

A. Information source and references

REACH information on registered substances;

http://apps.echa.europa.eu/registered/registered-sub.aspx

U.S. National library of Medicine(NLM) Hazardous Substances Data Bank(HSDB);

http://toxnet.nlm.nih.gov/cgi-bin/sis/htmlgen?HSDB

National Institute of Technology and Evaluation(NITE);

http://www.safe.nite.go.jp/english/db.html

National Chemicals Information System; http://ncis.nier.go.kr/ncis/

National Institute of Food and Drug Safety Evaluation-Tox Info;

http://toxinfo.nifds.go.kr/Index

National Emergency Management Agency-Korea dangerous material inventory

management system; http://www.nema.go.kr/hazmat/main/main.jsp

The Chemical Database -The Department of Chemistry at the University of Akron;

http://ull.chemistry.uakron.edu/erd/

Korea Occupational Health & Safety Agency; http://www.kosha.net

Waste Control Act enforcement regulation attached [1]

B. Issuing date : 2012. 3. 22

C. Revision number and date

revision number :

date of the latest revision :

D. Others

• Since the user's working conditions are not known by us, the information supplied

on this safety data sheet is based on our current level of knowledge and on

national and community regulations.

• The product must not be used for any purposes other than those specified under

heading 1 without first obtaining written handling instructions.

• It is at all times the responsibility of the user to take all necessary measures to

comply with legal requirements and local regulations.

• The information given on this safety data sheet must be regarded as a description

of the safety requirements relating to our product and not a guarantee of its

properties.