Acrylic Manomers

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4ic Available grades Tankcar Quantities Methyl Acrylate Ethyl Acrylate Methyl Methacrylate Drum Quantities Ethyl Methacrylate η-Butyl Methacrylate n-Hexyl Methacrylate n-Octyl Methacrylate n-Lauryl Methacrylate Methacrylic Acid—90% Typical Reactions Uses t CH No/ CH 2 + Jf CH 2 ArOH 4-CH 2 =CHCOOR H 2 S + CH 2 = CHC0OR - Ci 2 H 23 NH 2 + CH 2 =CHCOOR (CHs)s'NH + CH*=CHCOOR - C l f 3\ Pilot Plant Quantities η-Butyl Acrylate Isobutyl Acrylate 2-EthyIhexyl Acrylate n-Octyl Acrylate Acrylic Acid Calcium Acrylate Methacrylic Acid—Glacial ~»CH| CHCOOR II CH* I CH I CHa •*• ArOCHlaCHaCOOR -*- R0OCCH 2 CHa-S-CHaCHaCO0R •*- CiaHasNHCHjCHaCOOR CHMOa + CHa= CHCOOR CH 3 / HCI + CHa - CHCOOR -*- (CH 3 ) a NCH 2 CHaCOOR CH 3 . •*- CHs-C-CHaCHaCOOR «Oa -^CICHaCHaCOOR CH 2 = CHCO0C 2 H 5 KMn0 4 *» H0CHa-CHCO0CaH s HSCH 2 CH 2 CO0R S0 3 H CH 2 = C-C00H CI CH 2 = CHCOOR+ CI 2 NaOH -*• CICH2-CHCOOR -^ »- CH 2 =C-CO0R Polymerization reactions with other monomers. Chemical intermediate in organic synthesis. CHEMICALS FOR INDUSTRY Available now from two plants (Bristol, Pa. and ICnoxville, Term.) ^oe ROHM £- BMJ^S COM PARilf WASHINGTON SQUARE, PHILADELPHIA 5, PA. Rtpmcnialivn in principal furrign cotmtrin Write Dept. SP for new booklet: THE MONOME RIC ACRYLIC ESTERS \Ιίί\ί\ Λΐ¥·' Λ/^2 Irrté mfëffî •OÊÊ m wm m CD©/? θ Ο 0 Ο- 00

Transcript of Acrylic Manomers

Page 1: Acrylic Manomers

4ic

Available grades Tankcar Quantities Methyl Acrylate Ethyl Acrylate Methyl Methacrylate

Drum Quantities Ethyl Methacrylate η-Butyl Methacrylate n-Hexyl Methacrylate n-Octyl Methacrylate n-Lauryl Methacrylate Methacrylic Acid—90%

Typical Reactions

Uses

t CH No/

CH2 + Jf CH2

ArOH 4-CH2=CHCOOR

H2S + CH2 = CHC0OR -

Ci2H2 3NH2 + CH2=CHCOOR

(CHs)s'NH + CH*=CHCOOR -

C l f 3 \

Pilot Plant Quantities η-Butyl Acrylate Isobutyl Acrylate 2-EthyIhexyl Acrylate n-Octyl Acrylate Acrylic Acid Calcium Acrylate Methacrylic Acid—Glacial

~»CH| CHCOOR II CH* I CH I CHa

•*• ArOCHlaCHaCOOR

-*- R0OCCH2CHa-S-CHaCHaCO0R

•*- CiaHasNHCHjCHaCOOR

CHMOa + CHa= CHCOOR CH 3 /

HCI + CHa - CHCOOR

-*- (CH3)aNCH2CHaCOOR CH3 .

•*- CHs-C-CHaCHaCOOR

«Oa

-^CICHaCHaCOOR

CH2 = CHCO0C2H5 KMn04 *» H0CHa-CHCO0CaHs

HSCH2CH2CO0R S03H

CH2 = C-C00H

CI

CH2 = CHCOOR+ CI 2 NaOH

-*• CICH2-CHCOOR -^ »- CH 2=C-CO0R

Polymerizat ion reactions with other monomers. Chemical intermediate in organic synthes is .

CHEMICALS FOR INDUSTRY

Avai lable now from two p lants (Bristol , P a . and ICnoxville, Term.)

ROHM £- BMJ S C O M P A R i l f

WASHINGTON SQUARE, PHILADELPHIA 5, PA.

Rtpmcnialivn in principal furrign cotmtrin

Write D e p t . S P for n e w book le t : T H E M O N O M E R I C A C R Y L I C E S T E R S

\Ιίί\ί\ Λΐ¥·' Λ/^2

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