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Crystal structures of [IrCl2(NHCHPh)((dppm)(C(N2dppm))-κ3P,C,P′)]Cl·5.5MeCN and [IrI(NHCHPh)(((dppm)C(N2))-κ2P,C)(dppm-κ2P,P′)]I(I3)·0.5I2·MeOH·0.5CH2Cl2:
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