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Page 1: Phase(Changes( - Weebly › uploads › 2 › 8 › 6 › 0 › ... · most of the water get there? A.) Water evaporates from the milk and condenses on the outside of the glass. B.)

Chapter  13  

Phase  Changes  

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ΔH  Quiz  

•  Calorimetry  •  Signs  for  ΔH  for  endo/exo  reac?ons  •  Poten?al  energy  diagrams  

•  ΔH  from  poten?al  energy  diagrams  

•  Thermochemical  stoichiometry  

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Two  basic  proper?es  of  the  gas  phase  are  

A.)  a  definite  shape  and  a  definite  volume  

B.)  a  definite  shape  but  no  definite  volume  

C.)  no  definite  shape  but  a  definite  volume  

D.)  no  definite  shape  and  no  definite  volume  

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Two  basic  proper?es  of  the  gas  phase  are  

A.)  a  definite  shape  and  a  definite  volume  

B.)  a  definite  shape  but  no  definite  volume  

C.)  no  definite  shape  but  a  definite  volume  

D.)  no  definite  shape  and  no  definite  volume  

SOLID  

LIQUID  

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Which  substance  has  vibra?ng  par?cles  in  regular,  fixed  posi?ons?  

A.)  Ca(s)  

B.)  Hg(l)  

C.)  Cl2(g)  

D.)  CaCl2(aq)  

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Which  substance  has  vibra?ng  par?cles  in  regular,  fixed  posi?ons?  

A.)  Ca(s)  

B.)  Hg(l)  

C.)  Cl2(g)  

D.)  CaCl2(aq)  

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The  circle  on  the  leP  shows  a  magnified  view  of  a  very  small  

por?on  of  liquid  water  in  a  closed  container.    

A.)    B.)    C.)    D.)    E.)    

What  would  the  magnified  view  show  aPer  the  water  evaporates?  

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Boiling  water  is  a  physical  change    

A,B,  and  D  -­‐    Water  molecules  are  not  decomposed  into  hydrogen  and  oxygen  gas  (hydrogen  is  flammable  and  oxygen  supports  combus?on,  if  these  gases  were  created  there  would  be  explosions  every  ?me  you  boiled  water)  

C  –  the  par?cles  do  not  vanish  (Law  of  Conserva?on  of  MaWer)  

E  –  when  water  molecules  boil,  they  remain  water,  the  par=cle  simply  move  farther  away  from  one  another  

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Which  grouping  of  the  three  phases  of  bromine  is  listed  in  order  from  leP  to  right  for  increasing  distance  between  bromine  

molecules?  

A.)  gas,  liquid,  solid    

B.)  liquid,  solid,  gas  

C.)  solid,  gas,  liquid    

D.)  solid,  liquid,  gas  

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Which  grouping  of  the  three  phases  of  bromine  is  listed  in  order  from  leP  to  right  for  increasing  distance  between  bromine  

molecules?  

A.)  gas,  liquid,  solid    

B.)  liquid,  solid,  gas  

C.)  solid,  gas,  liquid    

D.)  solid,  liquid,  gas  

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Par?cle  Movement  in  Phases  

 Solid       Par?cles  held  together  by  strong  forces  of  aWrac?on  

 Movement  is  restricted  to  vibra?ng  in  fixed  posi?ons  

 Definite  shape  and  volume  

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Par?cle  Movement  in  Phases  

 Liquid   Par?cles  have  aWrac?on  for  one  another   Par?cles  flow  around  each  other   Definite  volume,  takes  the  shape  of  its  container  

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Par?cle  Movement  in  Phases  

 Gas   Par?cles  have  no  aWrac?on  for  each  other   Par?cles  in  constant,  random  mo?on  

 Indefinite  shape  and  volume  (expands  to  fill  container)  

ANIMATION  

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Endothermic  Phase  Changes  

•  Solid    Liquid    – Mel?ng;  Fusion  

•  Liquid    Gas  – Boiling;  Vaporiza?on  

•  Solid    Gas  – Sublima?on  

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Exothermic  Phase  Changes  

 Gas    Liquid   Condensa?on  

 Liquid    Solid   Freezing;  Solidifica?on  

 Gas    Solid   Deposi?on  

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S  L  G  

ENDOTHERMIC  

NEEDS  ENERGY  

EXOTHERMIC  

RELEASES  ENERGY  

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Which  phase  change  is  an  exothermic  process?  

A.)  CO2(s)    CO2(g)  

B.)  NH3(g)    NH3(l)  

C.)  Cu(s)    Cu(l)  

D.)  Hg(l)    Hg(g)  

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Which  phase  change  is  an  exothermic  process?  

A.)  CO2(s)    CO2(g)  

B.)  NH3(g)    NH3(l)  

C.)  Cu(s)    Cu(l)  

D.)  Hg(l)    Hg(g)  

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Which  change  is  exothermic?  

A.)  freezing  of  water  

B.)  mel?ng  of  iron  

C.)  vaporiza?on  of  ethanol  

D.)  sublima?on  of  iodine  

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Which  change  is  exothermic?  

A.)  freezing  of  water  

B.)  mel?ng  of  iron  

C.)  vaporiza?on  of  ethanol  

D.)  sublima?on  of  iodine  

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A  1.0-­‐gram  sample  of  solid  iodine  is  placed  in  a  tube  and  the  tube  is  sealed  aPer  all  of  the  air  is  removed.  The  tube  and  the  solid  iodine  together  weigh  27.0  grams.      

A.)  less  than  26.0  grams.    B.)  26.0  grams.    C.)  27.0  grams.    D.)  28.0  grams.    E.)  more  than  28.0  grams.    

The  tube  is  then  heated  un?l  all  of  the  iodine  sublimes  and  the  tube  is  filled  with  iodine  gas.  

Will  the  weight  aPer  hea?ng  be:  

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A  1.0-­‐gram  sample  of  solid  iodine  is  placed  in  a  tube  and  the  tube  is  sealed  aPer  all  of  the  air  is  removed.  The  tube  and  the  solid  iodine  together  weigh  27.0  grams.      

A.)  less  than  26.0  grams.    B.)  26.0  grams.    C.)  27.0  grams.    D.)  28.0  grams.    E.)  more  than  28.0  grams.    

The  tube  is  then  heated  un?l  all  of  the  iodine  sublimes  and  the  tube  is  filled  with  iodine  gas.  

Will  the  weight  aPer  hea?ng  be:  

Par?cle  mass  does  not  depend  on  phase  

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Assume a beaker of pure water has been boiling for 30 minutes. What is in

the bubbles in the boiling water? A.) Air

B.) Oxygen gas and hydrogen gas

C.) Oxygen

D.) Water vapor

E.) Heat

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Assume a beaker of pure water has been boiling for 30 minutes. What is in

the bubbles in the boiling water? A.) Air

B.) Oxygen gas and hydrogen gas

C.) Oxygen

D.) Water vapor

E.) Heat

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A glass of cold milk sometimes forms a coat of water on the outside of the glass (Often referred to as 'sweat'). How does

most of the water get there?

A.) Water evaporates from the milk and condenses on the outside of the glass.

B.) The glass acts like a semi-permeable membrane and allows the water to pass, but not the milk.

C.) Water vapor condenses from the air. D.) The coldness causes oxygen and hydrogen from

the air combine on the glass forming water.

Page 26: Phase(Changes( - Weebly › uploads › 2 › 8 › 6 › 0 › ... · most of the water get there? A.) Water evaporates from the milk and condenses on the outside of the glass. B.)

A glass of cold milk sometimes forms a coat of water on the outside of the glass (Often referred to as 'sweat'). How does

most of the water get there?

A.) Water evaporates from the milk and condenses on the outside of the glass.

B.) The glass acts like a semi-permeable membrane and allows the water to pass, but not the milk.

C.) Water vapor condenses from the air. D.) The coldness causes oxygen and hydrogen from

the air combine on the glass forming water.

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You  take  a  swim  in  the  swimming  pool.  Although  it  is  a  hot  day  when  you  come  out,  

you  feel  cold.  Which  of  the  following  statements  is  TRUE?  

A.)  The  water  in  the  pool  is  warmer  than  the  air  

B.)  The  water  in  the  pool  is  colder  than  the  air  

C.)  The  water  on  your  skin  gets  cold  when  you  step  out  of  the  pool  

D.)  The  water  on  your  skin  evaporates  

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You  take  a  swim  in  the  swimming  pool.  Although  it  is  a  hot  day  when  you  come  out,  

you  feel  cold.  Which  of  the  following  statements  is  TRUE?  

A.)  The  water  in  the  pool  is  warmer  than  the  air  

B.)  The  water  in  the  pool  is  colder  than  the  air  

C.)  The  water  on  your  skin  gets  cold  when  you  step  out  of  the  pool  

D.)  The  water  on  your  skin  evaporates  

L    G  is  endothermic,  absorbing  heat  energy  from  your  body