PENTAMETHYLENE GLYCOL
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Transcript of PENTAMETHYLENE GLYCOL
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1,5-PENTANEDIOL
H O * CHa CH2 · CHh CH2 · CH 2 O H
As a chemical intermediate, pentamethylene glycol opens the door to a wealth of new organic compounds. Linear and cyclic esters and polyesters are readily obtained by reaction with various acylating agents. A new class of high molecular weight linear polymers can be produced by heating with alkyl formais. Dehydration and oxidation yield tetrahydropyran and glutaric acid, respectively.
Esters and Polyesters of pentamethylene glycol are valuable plasticizers for certain types of resins and may find applications in the textile industry as plasticizers for fibers such as cotton, rayon, wool, mohair, silk and nylon, increasing their elasticity and flexibility. Cyclic esters may be useful in the preparation of perfumes.
AVAILABILITY: Limited quantities of this product are available for research and development. A request on your company letter
head will bring further technical information and also a sample if desired. E. I. du Pont de Nemours
& Co. (Inc.), Electrochemicals Department, Field Research Section, Wilmington 98, Delaware.
Appearance . Colorless, viscous liquid Odor. . . . . . . . . . . . . . ο None Molecular Weight 104.15 Boiling Point 239°C. (462°F.) at 760 mm. Melting Point -21°to-23°C-Specific Gravity, 20°C./4°C 0.9938 Index o f Refraction, N20/D 1.4499 Hygroseopicity Less than half as hy
groscopic as glycerol. Flash Point 125°C.(257°F.) Solubility Miscible in all proportions
with -water, methanol, ethanol, acetone and ethyl acetate. Solubility in diethyl ether at 2 5 ° C , ca. 1 1 % by weight. Insoluble in benzene, rrichloro-ethylene, methylene chloride, petroleum ether and fieptane.
for pentamethylene glycol may be found
in the following: Dyes
Paints Paper Films
Anti-freeze solutions Brake fluid compositions
Lubricating oils Steam-set inks
Leather treating and finishing compositions
As a plasticizer in certain adhesives and cellulose products
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DU PONT ELECTROCHEMICALS Field Research Section
B E T T E R T H I N G S F O R B E T T E R L I V I N G . . . T H R O U G H CHEMISTRY
Tune i n t o D u Pont " C a v a l c a d e of A m e r i c a " M o n d a y nights 8 P. M . , EST, N B C .
738 C H E M I C A L A N D E N G I N E E R I N G N E W S
PENTAMETHYLENE GLYCOL
APPLICATIONS
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