PENTAMETHYLENE GLYCOL

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Page 1: PENTAMETHYLENE GLYCOL

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NEW CHEMICALS ^•IffllieDIiBiïŒiÎl^^e

1,5-PENTANEDIOL

H O * CHa CH2 · CHh CH2 · CH 2 O H

As a chemical intermediate, pentamethylene gly­col opens the door to a wealth of new organic compounds. Linear and cyclic esters and poly­esters are readily obtained by reaction with various acylating agents. A new class of high molecular weight linear polymers can be produced by heating with alkyl formais. Dehydration and oxidation yield tetrahydropyran and glutaric acid, re­spectively.

Esters and Polyesters of pentamethylene glycol are valuable plasticizers for certain types of resins and may find applications in the textile industry as plasticizers for fibers such as cotton, rayon, wool, mohair, silk and nylon, increasing their elasticity and flexibility. Cyclic esters may be useful in the preparation of perfumes.

AVAILABILITY: Limited quantities of this product are available for research and development. A request on your company letter­

head will bring further technical information and also a sample if desired. E. I. du Pont de Nemours

& Co. (Inc.), Electrochemicals Department, Field Research Section, Wilmington 98, Delaware.

Appearance . Colorless, viscous liquid Odor. . . . . . . . . . . . . . ο None Molecular Weight 104.15 Boiling Point 239°C. (462°F.) at 760 mm. Melting Point -21°to-23°C-Specific Gravity, 20°C./4°C 0.9938 Index o f Refraction, N20/D 1.4499 Hygroseopicity Less than half as hy­

groscopic as glycerol. Flash Point 125°C.(257°F.) Solubility Miscible in all proportions

with -water, methanol, ethanol, acetone and ethyl acetate. Solubility in diethyl ether at 2 5 ° C , ca. 1 1 % by weight. Insoluble in benzene, rrichloro-ethylene, methylene chloride, petroleum ether and fieptane.

for pentamethylene glycol may be found

in the following: Dyes

Paints Paper Films

Anti-freeze solutions Brake fluid compositions

Lubricating oils Steam-set inks

Leather treating and finishing compositions

As a plasticizer in certain adhesives and cellulose products

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DU PONT ELECTROCHEMICALS Field Research Section

B E T T E R T H I N G S F O R B E T T E R L I V I N G . . . T H R O U G H CHEMISTRY

Tune i n t o D u Pont " C a v a l c a d e of A m e r i c a " M o n d a y nights 8 P. M . , EST, N B C .

738 C H E M I C A L A N D E N G I N E E R I N G N E W S

PENTAMETHYLENE GLYCOL

APPLICATIONS

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