ChemInform Abstract: Enantioselective Synthesis of β-Amino Acids. Part 9. Preparation of...
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1999 amino acids, peptides amino acids, peptides U 0400 16 - 198 Enantioselective Synthesis of β-Amino Acids. Part 9. Preparation of Enantiopure α,α-Disubstituted β-Amino Acids from 1-Benzoyl-2(S)- tert-butyl-3-methylperhydropyrimidin-4-one. — The alkylated amino acid derivatives (I) are alkylated a second time via their corresponding enolates with high diastereoselectivity to give after hydrolysis enantiopure α,α-dialkyl β-amino acids. — (JUARISTI, EUSEBIO; BALDERAS, MARGARITA; RAMIREZ-QUIROS, YARA; Tetrahedron: Asymmetry 9 (1998) 21, 3881-3888; Dep. Quim., Cent. Invest. Estud. Avanzados, Inst. Politec. Nac., 07000 Mexico, Mex.; EN) 1
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Transcript of ChemInform Abstract: Enantioselective Synthesis of β-Amino Acids. Part 9. Preparation of...
![Page 1: ChemInform Abstract: Enantioselective Synthesis of β-Amino Acids. Part 9. Preparation of Enantiopure α,α-Disubstituted β-Amino Acids from 1-Benzoyl-2(S)-tert-butyl-3-methylperhydropyrimidin-4-one.](https://reader036.fdocument.org/reader036/viewer/2022080306/575003661a28ab114898ed31/html5/thumbnails/1.jpg)
1999 amino acids, peptides
amino acids, peptidesU 0400
16 - 198Enantioselective Synthesis of β-Amino Acids. Part 9. Preparation ofEnantiopure α,α-Disubstituted β-Amino Acids from 1-Benzoyl-2(S)-tert-butyl-3-methylperhydropyrimidin-4-one. — The alkylated aminoacid derivatives (I) are alkylated a second time via their corresponding enolateswith high diastereoselectivity to give after hydrolysis enantiopure α,α-dialkylβ-amino acids. — (JUARISTI, EUSEBIO; BALDERAS, MARGARITA;RAMIREZ-QUIROS, YARA; Tetrahedron: Asymmetry 9 (1998) 21, 3881-3888;Dep. Quim., Cent. Invest. Estud. Avanzados, Inst. Politec. Nac., 07000Mexico, Mex.; EN)
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