Briefs
1
Γ -. ( intermediate staMmr pksticmr Properties of Jefferson Alkyl Phenol C-9 indicate a wide range of application as 1. an intermediate for non-ionic detergents 2. a stabilizer for ethyl cellulose 3. a plasticizer for cellulose esters 4. an intermediate for other plasticizers 5. a starting material for production of lubricating oil additives • and rubber chemicals 6. an antioxidant A typical description of Jefferson Alkyl Phenol C-9 is: You may secure technical information and experimental samples for research and product development by writing— on your company letterhead, please: Market Development Division. Compressor piping frames this picture -> of a Jefferson ethylene unit (purifi- F cation section) at Port Nechcs, Texas, Jefferson Chemical Company, Inc. 711 FIFTH AVENUE, NEW YORK 22, Ν. Υ. ESSENTIAL CHEMICALS FROM HYDROCARBON SOURCES Specific Gravity 20/4°C. Hydroxyl No. Color, Pt-Co Scale Refractive Index (20°C.) FlashPoint (TOC°F.) Distillation Range, °C ( Modified ASTM) IBP 5 ml. 50 ml. 95 ml. EP 0.949 255 200 1.5140 300 290.0 293.0 295.0 296.5 298.0 From recent literature Pour depressants for waxy lubricat- ing oils are prepared by treating an aliphatic substituted hydroxy aro- matic compound of formula R n ArOH with an acylating agent (i.e. sebacic acid chloride) in the presence of a Friedel-Craft catalyst. R is prefer- ably an alkyl group of less than 12 carbon atoms and η is 1 or 2. Two percent of the alkyl phenol deriva- tive depresses pour point of waxy oil from 30° F . t o - 5 ° F . Trialkyl phenyl phosphates of im- proved characteristics have been prepared by reacting alkyl phenols obtained from petroleum with phos- phorus oxychloride at a temperature of140°C. Such products have greater elec- trical resistance, higher viscosities, lower toxicities and lower density than phosphoric acid esters made from other alkyl phenols. Heavy metal salts of alkyl phenol sulfides have been prepared and are found useful as Diesel crank case lubricant additives. They are partic- ularly effective in inhibiting oxida- tion and the formation of gums. Resinous condensation products may be made by causing acetylene to react at a temperature between 150° C. and 300° C , and at super- atmospheric pressures with alkyl phenols having secondary or tertiary alkyl groups containing 3 to 12 car- bon atoms. A strongly alkaline cata- lyst is required. These developments are abstracted from recent publications or U. S. patents. The uses may suggest other applications of Jefferson Alkyl Phenol C-9 in your products or processes. VOLUME 28, NO. 19 MAY 8, 1950 1591 lUlUMiffl veu
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Transcript of Briefs
Γ-.
( intermediate staMmr pksticmr
Proper t ies of Jefferson Alkyl Pheno l C-9 indicate a w ide range of application as 1. an intermediate for non-ionic detergents 2. a stabilizer for ethyl cellulose 3. a plasticizer for cellulose esters 4. an intermediate for other plasticizers 5. a starting material for production of lubricating oil additives
• and rubber chemicals 6. an antioxidant
A typical description of
Jefferson Alkyl Phenol
C-9 is:
You m a y secure technical information and experimental samples for research and p roduc t development by writing— on your company le t te rhead, p lease : Market Deve lopment Division.
Compressor piping frames this picture -> of a Jefferson ethylene unit (purifi-F cation section) at Port Nechcs, Texas,
Jefferson Chemical Company, Inc. 711 FIFTH AVENUE, NEW YORK 22 , Ν. Υ.
ESSENTIAL CHEMICALS FROM HYDROCARBON SOURCES
Specific Gravity 20/4°C. Hydroxyl No.
Color, Pt-Co Scale Refractive Index (20°C.)
FlashPoint (TOC°F.) Distillation Range, °C
( Modified ASTM) IBP
5 ml. 50 ml. 95 ml.
EP
0.949 255 200 1.5140 300
290.0 293.0 295.0 296.5 298.0
From recent literature
Pour depressants for waxy lubricating oils are prepared by treating an aliphatic substituted hydroxy aromatic compound of formula RnArOH with an acylating agent (i.e. sebacic acid chloride) in the presence of a Friedel-Craft catalyst. R is preferably an alkyl group of less than 12 carbon atoms and η is 1 or 2. Two percent of the alkyl phenol derivative depresses pour point of waxy oil from 30° F. t o - 5 ° F .
Trialkyl phenyl phosphates of improved charac te r i s t ics have been prepared by reacting alkyl phenols obtained from petroleum with phosphorus oxychloride at a temperature of140°C.
Such products have greater electrical resistance, higher viscosities, lower toxicities and lower density than phosphoric acid esters made from other alkyl phenols.
Heavy metal salts of alkyl phenol sulfides have been prepared and are found useful as Diesel crank case lubricant additives. They are particularly effective in inhibiting oxidation and the formation of gums.
Resinous condensation products may be made by causing acetylene to react at a t empera tu re be tween 150° C. and 300° C , and at super-atmospheric pressures with alkyl phenols having secondary or tertiary alkyl groups containing 3 to 12 carbon atoms. A strongly alkaline catalyst is required.
These developments are abstracted from recent publications or U. S. patents. The uses may suggest other applications of Jefferson Alkyl Phenol C-9 in your products or processes.
V O L U M E 2 8 , N O . 1 9 M A Y 8, 1 9 5 0 1591
lUlUMiffl veu
