Beyond the Flyleaf

4
the Flyleaf Technique of Organic Chemistry. Vol. II. Catalytic, Photochemical, and Elec- trolytic Reactions. ARNOLD WEISSBER- GER, editor, xi -f- 219 pages. Inter- science Publishers, Inc., 215 Fourth Ave., New York, Ν. Υ., 1948. $5.00. 1 HIS book, which is Vol. II of the series "Technique of Organic Chemistry," contains three reviews: ''Catalytic Reac- tions" by V. I. Komarcwsky and C. H. Riesz; "Photochemical Reactions" by W. A. Noyes, Jr., and V. Boekelheide; and "Electrolytic Reactions' ' by Sherlock Swann, Jr. Vol. I, "Physical Methods of Organic Chemistry/ ' appeared in two parts (CHEM. ENG. NEWS 24, 100 [1946] and 24, 2108 [1946]). The title of the article on catalytic reac- tions is somewhat of a misnomer. It might better have been "Catalysts and Catalytic Apparatus." About 12 pages are devoted to a good summary of the gen- eral methods of preparing catalysts. Most of the remainder is an excellent descriptive and profusely illustrated review of the physical apparatus and equipment used in carrying out catalytic reactions at at- mospheric, subatmospheric, and superat- mospheric pressures, both in batch (the familiar and very useful Parr hydrogéna- tion apparatus is not mentioned) and con- tinuous flow systems. To this reviewer's knowledge, such information has not been published previously in one place and will be valuable to chemists contemplating the use of catalytic procedures. On the other hand, since space was apparently limited, it would probably have been preferable to have omitted many of the il- lustrations (particularly those taken from readily available primary references) and to have used the space (at least 15 pages would have been made available) for a n outline of the types of catalytic reactions and the techniques used in carrying them out in the laboratory. For example, fig- ures showing the cross sections of high- pressure valves are not as helpful to the practicing organic chemist as would be a discussion of the technique of carrying out reactions in the presence of liquid anhy- drous hydrogen fluoride. More examples of the applications of the various types of equipment as well as a comparative evalua- tion would have been desirable. The chapter on photochemical reactions is a very well-written and balanced dis- cussion of the types of photochemical reac- tions and of the apparatus and techniques. The value of this chapter lies not only in that it shows what can be done with photo- chemical reactions, but in that it stresses limitations of the method. The discussion of electrolytic reactions follows an outline similar to that used in the article on photochemical reactions. A perhaps unique feature of this article is that constant reference is made to three review articles on electro-organic chemical preparations which were published by Prof. Swann in the Transactions of the Electrochemical Society. These reprints, available (at a nominal price) from the University of Illinois, should be obtained and used in conjunction with the article in order to have a very comprehensive review of electrolytic reactions. Furthermore, some statements in the article are incom- plete without the aid of these reprints. Except for the omissions mentioned above, the book serves as very satisfac- tory review of the techniques of catalytic, photochemical, and electrolytic reactions. It will be consulted frequently by organic chemists, particularly those interested in synthesis. Louis SCHMERLING An Introduction to Comparative Bio- chemistry. ERNEST BALDWXN. x i i i -f- 164 pages. Macmillan C o . , 60 Fifth Ave., New York 11, Ν. Υ., 1948. $1.75. UNFORTUNATELY, comparative bio- chemistry, unlike comparative anatomy or physiology, has been a subject much neglected by both research workers and teachers. It is therefore gratifying that Dr. Baldwin's book has found enough readers to warrant a third, enlarged and revised, edition. The book itself gives an interesting sur- vey of the scope of comparative biochem- istry, and it should prove very helpful to students and others interested, but not specializing, in this field. It is well writ- ten, and the general bibliography which has been provided will assist traose readers who become sufficiently interested in the subject to follow it up. The various chap- ters give concise summaries of the bio- chemical relations which have been most studied, such as blood electrolytes, metabo- lism of nitrogenous compounds, respira- tion, and nutrition. It is t o b e regretted that the chapter on animal pigmentation had to be confined to an enumeration of more or less unrelated facts. The development of biochemical reac- tions in the course of evolution neces- sarily had a decisive influence on the reactions of biochemical systems as we orb- serve them today. It is to be hoped that ACETYLENE CHEMISTRY JULIUS WALTER REPPE P.B. REPORT—18152-s Have you ordered your copy of this important book which will be ready for distribution on April 15, 1949? For details of this publication may we refer you to our advertisement in CHEMICAL and ENGINEERING NEWS, February 28, 1949, issue, page 637. This book contains the complete text translation of the original report as written by Julius Walter Reppe. Heretofore, various important parts of the text as shown in the O. T. S. microfilm were found to be missing. This was due to the omission of parts of t h e translation as made by the original translator. In addition to the Table of Contents, this publication will also contain a complete index. * * * * CHARLES A. MEYER & CO., Inc. Translations and Technical Publications Grand Central Terminal Bldg. 25 Vanderbilt Ave. New York 17, Ν. Υ. V Ο L U M E 2 7, N O . 1 3 > . .MARCH 2 8, 1 9 4 9 Beyond 931

Transcript of Beyond the Flyleaf

the Flyleaf Technique of Organic Chemistry. Vol. II.

Catalytic, Photochemical, and Elec­trolytic Reactions. ARNOLD WEISSBER-GER, editor, xi -f- 219 pages. Inter-science Publishers, Inc., 215 Fourth Ave., New York, Ν . Υ., 1948. $5.00.

1 HIS book, which is Vol. II of the series "Technique of Organic Chemistry," contains three reviews: ''Catalytic Reac­tions" by V. I. Komarcwsky and C. H. Riesz; "Photochemical Reactions" by W. A. Noyes, Jr., and V . Boekelheide; and "Electrolytic Reactions' ' by Sherlock Swann, Jr. Vol. I, "Physical Methods of Organic Chemistry/ ' appeared in two parts (CHEM. E N G . N E W S 24, 100 [1946] and 24, 2108 [1946]).

The title of the article on catalytic reac­tions is somewhat of a misnomer. It might better have been "Catalysts and Catalytic Apparatus." About 12 pages are devoted to a good summary of the gen­eral methods of preparing catalysts. Most of the remainder is an excellent descriptive and profusely illustrated review of the physical apparatus and equipment used in carrying out catalytic reactions at at­mospheric, subatmospheric, and superat-mospheric pressures, both in batch (the familiar and very useful Parr hydrogéna­tion apparatus is not mentioned) and con­tinuous flow systems. T o this reviewer's knowledge, such information has not been published previously in one place and will be valuable t o chemists contemplating the use of catalytic procedures. On the other hand, since space was apparently limited, it would probably have been preferable to have omitted many of the i l­lustrations (particularly those taken from readily available primary references) and to have used the space (at least 15 pages would have been made available) for a n outline of the types of catalytic reactions and the techniques used in carrying them out in the laboratory. For example, fig­ures showing the cross sections of high-pressure valves are not as helpful to the practicing organic chemist as would be a discussion of the technique of carrying out reactions in t h e presence of liquid anhy­drous hydrogen fluoride. More examples of the applications of the various types of equipment as well as a comparative evalua­tion would have been desirable.

The chapter on photochemical reactions is a very well-written and balanced dis­cussion of the types of photochemical reac­tions and of the apparatus and techniques. The value of this chapter lies not only i n that i t shows what can be done with photo­

chemical reactions, but in that it stresses limitations of the method.

The discussion of electrolytic reactions follows an outline similar to that used in the article on photochemical reactions. A perhaps unique feature of this article is that constant reference is made to three review articles on electro-organic chemical preparations which were published by Prof. Swann in the Transactions of the Electrochemical Society. These reprints, available (at a nominal price) from the University of Illinois, should be obtained and used in conjunction with the article in order to have a very comprehensive review of electrolytic reactions. Furthermore, some statements in the article are incom­plete without the aid of these reprints.

Except for the omissions mentioned above, the book serves as very satisfac­tory review of the techniques of catalytic, photochemical, and electrolytic reactions. I t will be consulted frequently by organic chemists, particularly those interested in synthesis. Lou i s SCHMERLING

An Introduction to Comparative Bio­chemistry. E R N E S T BALDWXN. xiii -f-

164 pages. Macmillan C o . , 60 Fifth Ave., N e w York 11, Ν. Υ., 1948. $1.75.

U N F O R T U N A T E L Y , comparative bio­chemistry, unlike comparative anatomy or physiology, has been a subject much neglected by both research workers and teachers. It is therefore gratifying that Dr. Baldwin's book has found enough readers t o warrant a third, enlarged and revised, edition.

The book itself gives an interesting sur­vey of the scope of comparative biochem­istry, and it should prove v e r y helpful t o students and others interested, but not specializing, in this field. I t i s well writ­ten, and the general bibliography which has been provided will assist traose readers who become sufficiently interested i n the subject t o follow it up. The various chap­ters give concise summaries of the bio­chemical relations which have been most studied, such as blood electrolytes, metabo­lism of nitrogenous compounds, respira­tion, and nutrition. It is to b e regretted that the chapter on animal pigmentation had to b e confined to an enumeration of more or less unrelated facts.

The development of biochemical reac­tions in the course of evolution neces­sarily had a decisive influence o n the reactions of biochemical systems as w e orb-serve them today. I t is to b e hoped that

ACETYLENE CHEMISTRY JULIUS WALTER REPPE

P.B. REPORT—18152-s

Have you ordered your copy of this important book which will be ready for distribution on April 15, 1949? For details of this publication may we refer you to our advertisement in CHEMICAL and ENGINEERING NEWS, February 28, 1949, issue, page 637.

This book contains the complete text translation of the original report as written by Julius Walter Reppe. Heretofore, various important parts of the text as shown in the O. T. S. microfilm were found to be missing. This was due to the omission of parts of the translation as made by the original translator. In addition to the Table of Contents, this publication will also contain a complete index.

* * * *

CHARLES A. MEYER & CO., Inc. Translations and Technical Publications

Grand Central Terminal Bldg. 25 Vanderbilt Ave. New York 17, Ν. Υ.

V Ο L U M E 2 7, N O . 1 3 > . . M A R C H 2 8, 1 9 4 9

Beyond

931

BEYOND THE FLYLEAF

Dr. Baldwin's book will continue to stimulate intensified study of comparative biochemistry. With the aid of the tools of modern science this branch of biology will certainly further our understanding of all living matter. H. S. ANKER

Elements of Coal Chemistry. D. J. W. KREULEN. 204 pages. Nijgh & Van Ditmar N. V., Rotterdam-'s-Graven-hage, 1948. Fl. 18.25.

I HE publication of this monograph in English makes available in convenient form a résumé of many investigations pre­viously described mostly in the Dutch journals by the author. D. J. W. Kreulen, lecturer on fuel chemistry and technologv at the University of Utrecht, recently was honored on the occasion of the twenty-fifth anniversary of his establishment of the Laboratorium Voor Brandstof-en Olieonderzoek in Rotterdam.

Treatment of the subjects covered in the 17 chapters is not comprehensive and in certain cases not critical in the sense that other significant work on the same subject is not considered. Subjects in which the author has not been actively en­gaged are treated quite inadequately in the chapters assigned to them—e.g., the hy­drogénation of coal. However, those in­

terested in the chemistry of coal will be re­paid by reading t h e descriptions of Kreulen's own work, particularly on humic acids, the mechanism of coal oxidation, the spontaneous combustion of coal, coal ex­traction, and the properties and origin of coal bitumens. It would be an interesting exercise to reinterpret much of the data presented in terms of coal being a natural, thermally unstable polymer instead of the micellar structure of a disperse and con­tinuous colloidal system postulated by Kreulen.

The book is well printed. It lacks an index. The bibliographies at the end of each chapter arc highly selective. The English is generally good, th.ough, as may be expected in a foreign language, choice of words, spelling, and abbreviations are sometimes unusual. H. 1-1. LOWRY

The Marketing of Chemical Products. ROBERT S. ARIES and WILLIAM COPUL-

SKY. vi -h 149 pages. Overland Com­mercial Corp., 26 Court St . , Brooklyn 2, N .Y . ,1948 . $5.00.

DR ARIES' and Mr. Copulsky's book is intended to cover all factors bearing on the marketing of chemical products. Par­ticular emphasis is laid on the marketing of new products and on market research.

Dr. Baldwin's book will continue to stimulate intensified study of comparative biochemistry. With the aid of the tools of modern science this branch of biology will certainly further our understanding of all living matter. H. S. ANKER

Elements of Coal Chemistry. D. J. W. KREULEN. 204 pages. Nijgh & Van Ditmar N. V., Rotterdam-'s-Graven-hage, 1948. Fl. 18.25.

I HE publication of this monograph in English makes available in convenient form a résumé of many investigations pre­viously described mostly in the Dutch journals by the author. D. J. W. Kreulen, lecturer on fuel chemistry and technologv at the University of Utrecht, recently was honored on the occasion of the twenty-fifth anniversary of his establishment of the Laboratorium Voor Brandstof-en Olieonderzoek in Rotterdam.

Treatment of the subjects covered in the 17 chapters is not comprehensive and in certain cases not critical in the sense that other significant work on the same subject is not considered. Subjects in which the author has not been actively en­gaged are treated quite inadequately in the chapters assigned to them—e.g., the hy­drogénation of coal. However, those in­

terested in the chemistry of coal will be re­paid by reading t h e descriptions of Kreulen's own work, particularly on humic acids, the mechanism of coal oxidation, the spontaneous combustion of coal, coal ex­traction, and the properties and origin of coal bitumens. It would be an interesting exercise to reinterpret much of the data presented in terms of coal being a natural, thermally unstable polymer instead of the micellar structure of a disperse and con­tinuous colloidal system postulated by Kreulen.

The book is well printed. It lacks an index. The bibliographies at the end of each chapter are highly selective. The English is generally good, th.ough, as may be expected in a foreign language, choice of words, spelling, and abbreviations are sometimes unusual. H. 1-1. LOWRY

The Marketing of Chemical Products. ROBERT S. ARIES and WILLIAM COPUL-

SKY. vi -h 149 pages. Overland Com­mercial Corp., 26 Court St . , Brooklyn 2, N .Y . ,1948 . $5.00.

DR ARIES' and Mr. Copulsky's book is intended to cover all factors bearing on the marketing of chemical products. Par­ticular emphasis is laid on the marketing of new products and on market research.

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The book is recommended as the only available textbook dealing with the present trend toward orderly processes of chemical marketing. It is issued at an advantageous time when chemical companies are getting away from early marketing methods based on whim or guess and substituting well organized market studies by highly skilled personnel. The efforts of specific com­panies to systematize the introduction of new products is discussed and is especially useful· The bibliography of over 100 references will be helpful to those studying the subject. The authors in attempting to cover a field so broad have been forced to a coverage which in certain passages is en­tirely inadequate; in many cases the coverage is nothing more than an outline of the matter involved. The authors have relied on the authority of many references available in the literature of chemical marketing without a serious attempt at critical analysis or without an adequate description of the theories and practices involved. For this reason the subject matter is presented in a jumpy manner which at times is very difficult to follow. This approach has also led to some repeti­tion and even to some contradiction. The authors state in their preface that the present book is a preliminary version of one which will treat the broader aspects of chemical marketing and market research. More careful proofreading would eliminate many simple but confusing errors in the present edition. LAWRENCE FLETT

Industrial Hygiene and Toxicology FRANK A. PATTY, editor, xxvii -f- 531 pages. Interscience Publishers, Inc., 215 Fourth Ave., New York 3, Ν . Υ., 1948. $10.

L HE editor of "Industrial Hygiene and Toxicology" and his collaborators are to be congratulated on making available in concrete form the material which is com­prised under the general heading of indus­trial hygiene. The health of our industrial workers is a matter which has received a tremendous impetus during the past 25 years, and this increasing social conscious­ness is reflected in the extent t o which in­dustrial hygiene has grown. The scope of present volume is indicated by the follow­ing representative topics: industrial hy­giene—retrospect and prospect, records and reports, surveys and personnel, per­sonal and environmental factors in fatigue and competence, physiological effects of abnormal atmospheric pressure, action of toxic materials, sampling and analysis of atmospheric contaminants, radiant energy, ventilation, occupational dermatoses, fire and explosion hazards of gases, respiratory protective devices, and the role of dust in occupational disease.

The presentation of this material in a single volume will be of special value to the industrial hygienist who does not have an

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extensive library at his command. The descriptive material is clearly presented and well illustrated with charts, diagrams, and occasional photographs of factory operations. While all the sections are ample within the normal limitation of such a volume, the sections on fatigue b y Josef. Brozek, on the physiology of pressure by Heinz Specht, and on dust by Ε. Ε . Dart are especially commendable.

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Student Exchange The first annual report of the Interna­

tional Association for the Exchange of Students for Technical Experience, founded in 1948 by rO European countries and recently granted consultative status by UNESCO, has been published. The arrangements made in each of the coun­tries for students participating in the pro­gram, as well as the general aims of IAESTE, are outlined and the cooperating firms listed. Copies can be obtained from the secretary, J. Newby, Imperial College, South Kensington, London S.W.7, Eng­land.

Rubber Research Recent publications of Nederlandsch-

Indisch Instituut voor Rubberonderzoek, Buitenzorg, Java, are Bulletin N o . 48 "Centrifuging of Latex" by G. J. v a n der Bie (40 pages), N o . 55, "Natural Vulcani­zation Accelerators in Hevea Latex" by R. F. A. Altman (20 pages), and N o . 65, "Studies Made on Rubbers from various species of Hevea" by G. J. van der Bie (6 pages, in French). A list of other publica­tions of the institute is included in each bulletin.

Industrializing Israel That applied engineering and scientific

research will enable the new Jewish State to absorb large-scale immigration, revital­ize the Middle East, and become a power factor in the council of nations is the theme of the Technion Yearbook, published by the American Technion Society, 154 Nas­sau St., New York 7, Ν. Υ. The publica­tion contains articles by David Ben-Gur-ion, Prime Minister of Israel, Yaacov Dori, chief of the Israeli Defense Forces, F. J. Fohs, geologist, W. B. Ziff, aviation expert, and four college heads. Edited by Judah Wattenberg, it numbers 252 pages and in­cludes 22 original papers on topics pertain­ing to technical, industrial, and educa­tional progress in the U. S. and Israel. E . A. Hauser contributed an article on "Col­loid Chemistry of Soils." The three sec­

tions are devoted to "Israel's Resources and Potentialities," "Science and Tech­nology," a n d the activities of the American Technion Society, sponsor of the Tech­nion in Haifa, Israel's Institute of Tech­nology. T h e society is also dedicated to furthering the industrialization of the Jewish State. Copies are priced at $2.50 for noiimernbers.

Chemical Centennials A 20-page review of "Centennials, Ses-

quicentennials, and Bicentennials of Chem­ical Enterest during 1949" b y Ε. Η. Hunt­ress i s available as a reprint from the pro­ceedings o f the American Academy of Arts and Sciences, 28 Newbury St., Boston 16, Mass. Copies are priced at $1.00. It was t h e author's aim to supply science in general and chemistry in particu­lar with a memorandum of special an­niversaries falling in t h e current year.

Sugar Research Report Tt*e fifth report, that for 194& of the Su­

gar Hesearch Foundation, Inc., 52 Wall St., ZNew York 5, Ν . Υ., tabulates the projects being sponsored b y the founda­tion iind l ists its published works, as well as renewing the award and other programs and organization of the foundation. I t is 20 pages in length.

ASMBC Proceedings Proceedings of the 1948 annual meeting

of t h e American Society of Brewing Chem­ists htavebeen published, comprising 13 re­search papers and 11 subcommittee re­ports?. Requests for copies of the 166-page bookJet should b e addressed to the society at 64 East Tiàke St. , Chicago, 111.

Gas Turbines Copies o f BIOS Overall Report No. 12,

"Ger-man G a s Turbine Developments dur­ing "the period 1939—1945," can be ob­tained from British Information Services, 30 Rockefeller Plaza, New York 20, Ν . Υ. The booklet, illustrated, i s 46 pages in length and costs 35 cents.

New Books I Absorption Spectrophotometry. G. F.

LOTHIAN. 106 pages. Hilger & Watts, Ltd. ,London N . W. 1, England. $8.20.

The Chemistry and Physiology of Growth. K - PARPART, editor. 293 pages. Prince­t o n University Press, Princeton, N . J. $4.50.

An Introduction to Textile Bleaching. J. T. M A R S H . 525 pages. John Wiley & Sons., Inc., New York, Ν. Υ . $6.50.

Laboratory Outlines and Notebook for Organic Chemistry. C. E. BOORD, W \ R. B R O D E , and R . G. BOSSERT. 282 pa.ges, John Wiley & Sons, Inc., N e w York 16, N. Y . $3.00

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