Beyond the Flyleaf
Transcript of Beyond the Flyleaf
the Flyleaf Technique of Organic Chemistry. Vol. II.
Catalytic, Photochemical, and Electrolytic Reactions. ARNOLD WEISSBER-GER, editor, xi -f- 219 pages. Inter-science Publishers, Inc., 215 Fourth Ave., New York, Ν . Υ., 1948. $5.00.
1 HIS book, which is Vol. II of the series "Technique of Organic Chemistry," contains three reviews: ''Catalytic Reactions" by V. I. Komarcwsky and C. H. Riesz; "Photochemical Reactions" by W. A. Noyes, Jr., and V . Boekelheide; and "Electrolytic Reactions' ' by Sherlock Swann, Jr. Vol. I, "Physical Methods of Organic Chemistry/ ' appeared in two parts (CHEM. E N G . N E W S 24, 100 [1946] and 24, 2108 [1946]).
The title of the article on catalytic reactions is somewhat of a misnomer. It might better have been "Catalysts and Catalytic Apparatus." About 12 pages are devoted to a good summary of the general methods of preparing catalysts. Most of the remainder is an excellent descriptive and profusely illustrated review of the physical apparatus and equipment used in carrying out catalytic reactions at atmospheric, subatmospheric, and superat-mospheric pressures, both in batch (the familiar and very useful Parr hydrogénation apparatus is not mentioned) and continuous flow systems. T o this reviewer's knowledge, such information has not been published previously in one place and will be valuable t o chemists contemplating the use of catalytic procedures. On the other hand, since space was apparently limited, it would probably have been preferable to have omitted many of the i llustrations (particularly those taken from readily available primary references) and to have used the space (at least 15 pages would have been made available) for a n outline of the types of catalytic reactions and the techniques used in carrying them out in the laboratory. For example, figures showing the cross sections of high-pressure valves are not as helpful to the practicing organic chemist as would be a discussion of the technique of carrying out reactions in t h e presence of liquid anhydrous hydrogen fluoride. More examples of the applications of the various types of equipment as well as a comparative evaluation would have been desirable.
The chapter on photochemical reactions is a very well-written and balanced discussion of the types of photochemical reactions and of the apparatus and techniques. The value of this chapter lies not only i n that i t shows what can be done with photo
chemical reactions, but in that it stresses limitations of the method.
The discussion of electrolytic reactions follows an outline similar to that used in the article on photochemical reactions. A perhaps unique feature of this article is that constant reference is made to three review articles on electro-organic chemical preparations which were published by Prof. Swann in the Transactions of the Electrochemical Society. These reprints, available (at a nominal price) from the University of Illinois, should be obtained and used in conjunction with the article in order to have a very comprehensive review of electrolytic reactions. Furthermore, some statements in the article are incomplete without the aid of these reprints.
Except for the omissions mentioned above, the book serves as very satisfactory review of the techniques of catalytic, photochemical, and electrolytic reactions. I t will be consulted frequently by organic chemists, particularly those interested in synthesis. Lou i s SCHMERLING
An Introduction to Comparative Biochemistry. E R N E S T BALDWXN. xiii -f-
164 pages. Macmillan C o . , 60 Fifth Ave., N e w York 11, Ν. Υ., 1948. $1.75.
U N F O R T U N A T E L Y , comparative biochemistry, unlike comparative anatomy or physiology, has been a subject much neglected by both research workers and teachers. It is therefore gratifying that Dr. Baldwin's book has found enough readers t o warrant a third, enlarged and revised, edition.
The book itself gives an interesting survey of the scope of comparative biochemistry, and it should prove v e r y helpful t o students and others interested, but not specializing, in this field. I t i s well written, and the general bibliography which has been provided will assist traose readers who become sufficiently interested i n the subject t o follow it up. The various chapters give concise summaries of the biochemical relations which have been most studied, such as blood electrolytes, metabolism of nitrogenous compounds, respiration, and nutrition. It is to b e regretted that the chapter on animal pigmentation had to b e confined to an enumeration of more or less unrelated facts.
The development of biochemical reactions in the course of evolution necessarily had a decisive influence o n the reactions of biochemical systems as w e orb-serve them today. I t is to b e hoped that
ACETYLENE CHEMISTRY JULIUS WALTER REPPE
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Have you ordered your copy of this important book which will be ready for distribution on April 15, 1949? For details of this publication may we refer you to our advertisement in CHEMICAL and ENGINEERING NEWS, February 28, 1949, issue, page 637.
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Dr. Baldwin's book will continue to stimulate intensified study of comparative biochemistry. With the aid of the tools of modern science this branch of biology will certainly further our understanding of all living matter. H. S. ANKER
Elements of Coal Chemistry. D. J. W. KREULEN. 204 pages. Nijgh & Van Ditmar N. V., Rotterdam-'s-Graven-hage, 1948. Fl. 18.25.
I HE publication of this monograph in English makes available in convenient form a résumé of many investigations previously described mostly in the Dutch journals by the author. D. J. W. Kreulen, lecturer on fuel chemistry and technologv at the University of Utrecht, recently was honored on the occasion of the twenty-fifth anniversary of his establishment of the Laboratorium Voor Brandstof-en Olieonderzoek in Rotterdam.
Treatment of the subjects covered in the 17 chapters is not comprehensive and in certain cases not critical in the sense that other significant work on the same subject is not considered. Subjects in which the author has not been actively engaged are treated quite inadequately in the chapters assigned to them—e.g., the hydrogénation of coal. However, those in
terested in the chemistry of coal will be repaid by reading t h e descriptions of Kreulen's own work, particularly on humic acids, the mechanism of coal oxidation, the spontaneous combustion of coal, coal extraction, and the properties and origin of coal bitumens. It would be an interesting exercise to reinterpret much of the data presented in terms of coal being a natural, thermally unstable polymer instead of the micellar structure of a disperse and continuous colloidal system postulated by Kreulen.
The book is well printed. It lacks an index. The bibliographies at the end of each chapter arc highly selective. The English is generally good, th.ough, as may be expected in a foreign language, choice of words, spelling, and abbreviations are sometimes unusual. H. 1-1. LOWRY
The Marketing of Chemical Products. ROBERT S. ARIES and WILLIAM COPUL-
SKY. vi -h 149 pages. Overland Commercial Corp., 26 Court St . , Brooklyn 2, N .Y . ,1948 . $5.00.
DR ARIES' and Mr. Copulsky's book is intended to cover all factors bearing on the marketing of chemical products. Particular emphasis is laid on the marketing of new products and on market research.
Dr. Baldwin's book will continue to stimulate intensified study of comparative biochemistry. With the aid of the tools of modern science this branch of biology will certainly further our understanding of all living matter. H. S. ANKER
Elements of Coal Chemistry. D. J. W. KREULEN. 204 pages. Nijgh & Van Ditmar N. V., Rotterdam-'s-Graven-hage, 1948. Fl. 18.25.
I HE publication of this monograph in English makes available in convenient form a résumé of many investigations previously described mostly in the Dutch journals by the author. D. J. W. Kreulen, lecturer on fuel chemistry and technologv at the University of Utrecht, recently was honored on the occasion of the twenty-fifth anniversary of his establishment of the Laboratorium Voor Brandstof-en Olieonderzoek in Rotterdam.
Treatment of the subjects covered in the 17 chapters is not comprehensive and in certain cases not critical in the sense that other significant work on the same subject is not considered. Subjects in which the author has not been actively engaged are treated quite inadequately in the chapters assigned to them—e.g., the hydrogénation of coal. However, those in
terested in the chemistry of coal will be repaid by reading t h e descriptions of Kreulen's own work, particularly on humic acids, the mechanism of coal oxidation, the spontaneous combustion of coal, coal extraction, and the properties and origin of coal bitumens. It would be an interesting exercise to reinterpret much of the data presented in terms of coal being a natural, thermally unstable polymer instead of the micellar structure of a disperse and continuous colloidal system postulated by Kreulen.
The book is well printed. It lacks an index. The bibliographies at the end of each chapter are highly selective. The English is generally good, th.ough, as may be expected in a foreign language, choice of words, spelling, and abbreviations are sometimes unusual. H. 1-1. LOWRY
The Marketing of Chemical Products. ROBERT S. ARIES and WILLIAM COPUL-
SKY. vi -h 149 pages. Overland Commercial Corp., 26 Court St . , Brooklyn 2, N .Y . ,1948 . $5.00.
DR ARIES' and Mr. Copulsky's book is intended to cover all factors bearing on the marketing of chemical products. Particular emphasis is laid on the marketing of new products and on market research.
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The book is recommended as the only available textbook dealing with the present trend toward orderly processes of chemical marketing. It is issued at an advantageous time when chemical companies are getting away from early marketing methods based on whim or guess and substituting well organized market studies by highly skilled personnel. The efforts of specific companies to systematize the introduction of new products is discussed and is especially useful· The bibliography of over 100 references will be helpful to those studying the subject. The authors in attempting to cover a field so broad have been forced to a coverage which in certain passages is entirely inadequate; in many cases the coverage is nothing more than an outline of the matter involved. The authors have relied on the authority of many references available in the literature of chemical marketing without a serious attempt at critical analysis or without an adequate description of the theories and practices involved. For this reason the subject matter is presented in a jumpy manner which at times is very difficult to follow. This approach has also led to some repetition and even to some contradiction. The authors state in their preface that the present book is a preliminary version of one which will treat the broader aspects of chemical marketing and market research. More careful proofreading would eliminate many simple but confusing errors in the present edition. LAWRENCE FLETT
Industrial Hygiene and Toxicology FRANK A. PATTY, editor, xxvii -f- 531 pages. Interscience Publishers, Inc., 215 Fourth Ave., New York 3, Ν . Υ., 1948. $10.
L HE editor of "Industrial Hygiene and Toxicology" and his collaborators are to be congratulated on making available in concrete form the material which is comprised under the general heading of industrial hygiene. The health of our industrial workers is a matter which has received a tremendous impetus during the past 25 years, and this increasing social consciousness is reflected in the extent t o which industrial hygiene has grown. The scope of present volume is indicated by the following representative topics: industrial hygiene—retrospect and prospect, records and reports, surveys and personnel, personal and environmental factors in fatigue and competence, physiological effects of abnormal atmospheric pressure, action of toxic materials, sampling and analysis of atmospheric contaminants, radiant energy, ventilation, occupational dermatoses, fire and explosion hazards of gases, respiratory protective devices, and the role of dust in occupational disease.
The presentation of this material in a single volume will be of special value to the industrial hygienist who does not have an
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Student Exchange The first annual report of the Interna
tional Association for the Exchange of Students for Technical Experience, founded in 1948 by rO European countries and recently granted consultative status by UNESCO, has been published. The arrangements made in each of the countries for students participating in the program, as well as the general aims of IAESTE, are outlined and the cooperating firms listed. Copies can be obtained from the secretary, J. Newby, Imperial College, South Kensington, London S.W.7, England.
Rubber Research Recent publications of Nederlandsch-
Indisch Instituut voor Rubberonderzoek, Buitenzorg, Java, are Bulletin N o . 48 "Centrifuging of Latex" by G. J. v a n der Bie (40 pages), N o . 55, "Natural Vulcanization Accelerators in Hevea Latex" by R. F. A. Altman (20 pages), and N o . 65, "Studies Made on Rubbers from various species of Hevea" by G. J. van der Bie (6 pages, in French). A list of other publications of the institute is included in each bulletin.
Industrializing Israel That applied engineering and scientific
research will enable the new Jewish State to absorb large-scale immigration, revitalize the Middle East, and become a power factor in the council of nations is the theme of the Technion Yearbook, published by the American Technion Society, 154 Nassau St., New York 7, Ν. Υ. The publication contains articles by David Ben-Gur-ion, Prime Minister of Israel, Yaacov Dori, chief of the Israeli Defense Forces, F. J. Fohs, geologist, W. B. Ziff, aviation expert, and four college heads. Edited by Judah Wattenberg, it numbers 252 pages and includes 22 original papers on topics pertaining to technical, industrial, and educational progress in the U. S. and Israel. E . A. Hauser contributed an article on "Colloid Chemistry of Soils." The three sec
tions are devoted to "Israel's Resources and Potentialities," "Science and Technology," a n d the activities of the American Technion Society, sponsor of the Technion in Haifa, Israel's Institute of Technology. T h e society is also dedicated to furthering the industrialization of the Jewish State. Copies are priced at $2.50 for noiimernbers.
Chemical Centennials A 20-page review of "Centennials, Ses-
quicentennials, and Bicentennials of Chemical Enterest during 1949" b y Ε. Η. Huntress i s available as a reprint from the proceedings o f the American Academy of Arts and Sciences, 28 Newbury St., Boston 16, Mass. Copies are priced at $1.00. It was t h e author's aim to supply science in general and chemistry in particular with a memorandum of special anniversaries falling in t h e current year.
Sugar Research Report Tt*e fifth report, that for 194& of the Su
gar Hesearch Foundation, Inc., 52 Wall St., ZNew York 5, Ν . Υ., tabulates the projects being sponsored b y the foundation iind l ists its published works, as well as renewing the award and other programs and organization of the foundation. I t is 20 pages in length.
ASMBC Proceedings Proceedings of the 1948 annual meeting
of t h e American Society of Brewing Chemists htavebeen published, comprising 13 research papers and 11 subcommittee reports?. Requests for copies of the 166-page bookJet should b e addressed to the society at 64 East Tiàke St. , Chicago, 111.
Gas Turbines Copies o f BIOS Overall Report No. 12,
"Ger-man G a s Turbine Developments during "the period 1939—1945," can be obtained from British Information Services, 30 Rockefeller Plaza, New York 20, Ν . Υ. The booklet, illustrated, i s 46 pages in length and costs 35 cents.
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LOTHIAN. 106 pages. Hilger & Watts, Ltd. ,London N . W. 1, England. $8.20.
The Chemistry and Physiology of Growth. K - PARPART, editor. 293 pages. Princet o n University Press, Princeton, N . J. $4.50.
An Introduction to Textile Bleaching. J. T. M A R S H . 525 pages. John Wiley & Sons., Inc., New York, Ν. Υ . $6.50.
Laboratory Outlines and Notebook for Organic Chemistry. C. E. BOORD, W \ R. B R O D E , and R . G. BOSSERT. 282 pa.ges, John Wiley & Sons, Inc., N e w York 16, N. Y . $3.00
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