Download - ChemInform Abstract: Stereoselective Synthesis of Non Symmetric Dihydroxyethylene Dipeptide Isosteres via Epoxyalcohols Derived from α-Amino Acids.

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Page 1: ChemInform Abstract: Stereoselective Synthesis of Non Symmetric Dihydroxyethylene Dipeptide Isosteres via Epoxyalcohols Derived from α-Amino Acids.

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07 - 094Stereoselective Synthesis of Non Symmetric DihydroxyethyleneDipeptide Isosteres via Epoxyalcohols Derived from α-Amino Acids.— A novel approach to dihydroxyethylene isosteres potentially useful for newHIV-protease inhibitors is developed. Key step in the synthesis is a regio-and stereoselective reaction of the epoxyalcohol (I) with diethyl aluminumcyanide (II). — (BENEDETTI, FABIO; MAGNAN, MONICA; MIERTUS,STANISLAV; NORBEDO, STEFANO; PARAT, DJIANA; TOSSI, ALESSAN-DRO; Bioorg. Med. Chem. Lett. 9 (1999) 20, 3027-3030; Dip. Sci. Chim.,Univ. Trieste, I-34127 Trieste, Italy; EN)

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