Table of Contents
Transcript of Table of Contents
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Science g e t s α voice in nat ional policymaking as President Eisenhower appoints MIT president James R. Killian, Jr., to new post of Presidential science adviser. Scientists approve the move but wonder whether this is the answer to long range problems of U. S. science. Page 25.
F E A T U R E Magnesium's chemical and nonstructural uses are growing faster than the industry as a whole. At present over a third of primary production is going into chemical uses—titanium tetrachloride reduction and Grignard reagents. Page 72.
I N D U S T R Y & B U S I N E S S Pe t ro leum produc ts sales lag this yea r . Some declines are blamed on industrial production drop, but lack of gasoline consumption growth confounds the oil industry. Page 28. More of t he same—process firms indict high cos t s for eroding earnings so far this year. Some third-quarter reports take earnings for first nine months ahead of last year, but many others show drops. Page 30.
M A R K E T S Influenza, the Asian type and ordinary kinds, has people running to the corner drugstore for aspirin. Result: record aspirin production. Trend to aspirin for rheumatism and arthritis also ups output. Page 36.
M A N A G E M E N T Four factors wil l influence industrial relations of the future, says Labor Secretary Mitchell. Principal one: public insistence that labor and management conduct their business for public good. Page 39.
G O V E R N M E N T Slowdown in U. S. atomic power development may lie ahead unless we have a reactor system that can be exploited on a large scale in 1963. AEC's solution: push development of water cooled and moderated reactors to meet the atomic power timetable. Page 42.
RESEARCH U. S. drug companies will spend 7 .5% of sales this year for research—$127 million in all. This is $17 million more than last year. Main objects of this research are new drugs, better drugs, and cheaper drugs. Page 48. Organic materials capable of withstanding 1000° F. for prolonged periods of time are goal of chemists working in the lubrication field. The high-temperature goal of 500° F. set two years ago for 1965 already has been met. Page 49.
P R O P U C T I O N "Packaged" reprocessing plants seem a likely a n s w e r to the question, "Where will spent power reactor fuels be processed?" Such a plant could get additional revenue from the recovery of radioactive isotopes. Page 50.
C H EM ICALS Two new silicone fluids—lubricants for the jet age—are stable to oxygen, perform at 700° F . General Electric designs new testing equipment to check silicones at higher temperatures than standard testers can take. Page 53.
EQUIPMENT Speedy turbine mixer emigrates from Europe, is licensed by Swedish inventor for U. S. manufacture. Although still under test, the unit shows good results in mixing concrete, looks promising for chemicals. Page 56.
AND Nalco has antifoams to stop foaming in virtually any a q u e o u s solution • Antifoams to perform at any pH • Both oil base and wa te r base anti-foams • Antifoams t h a t a r e s e l f - emu l s i fy ing wi th wa te r • Autifoams with exceptional
t e m p e r a t u r e s tabi l i ty • We will gladly send you technical d a t a • Just descr ibe your foaming p rob l em so we will b e bet ter a b l e to help yon •
NATIONAL AL UMINATE
6199 WeSt 66th:Place, Chicago 38, Illinois' NORTHVVESTÉRN U.S HAWAll ALASKÀ :^
t Flox Company, )nt., Minneapolis; Minrtl
•;: - Alchènï. Liniifeêl Burlington, Ontpnor:.
N O V . 18, 1957 C & E N 3
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CYANOETHYLATION
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Keeping Tabs on ACRYLONITRILE There are a great number of compounds, both organic and inorganic, possessing labile hydrogen atoms wh ich add readily to the carbon-carbon double bond of Acrylonitr i le. This reaction i s commonly known as "cyanoethy la t ion" .
The compounds that have been added to Acrylonitr i le to produce cyanoethyl derivatives may be classified according to the atom attached t o the reactive hydrogen. Thus, examples of cyanoethylat ion of compounds conta in ing As-H, B-H, Br-H,C-H,CI-H, N-Η,Ο-Η, P-H,S-H, Si-H, and Sn-H have been reported. Among the specif ic classes of compounds that
undergo cyanoethylation are a var iety of amines, amides, alcohols, mercaptans, aldehydes, ketones, esters, inorganic acids and their salts.
The cyanoethylation reaction usually requires an alkaline medium (about pH 11-13). However, some aromatic and heterocyclic amines require an acidic catalyst such as acetic acid.
Synthesis problems? Cyanoethylat ion may offer an economical route to profitable new products. Your nearest Cyan-amid Petrochemicals representative wil l be glad to show you the way.
Write for the 78-page "Polym e r s a n d Copo l ymers of A c r y l o n i t r i l e , " d e t a i l i n g many experimental procedures, l is t ing hundreds of polymer systems and suggesting many applications. American Cyanamid Company, P e t r o c h e m i c a l s Dep a r t m e n t , 30 Rocke fe l l e r Plaza, New York 20, Ν. Υ.
ACRYLO TECHNICAL CENTER
Note: The foregoing· shal l not be construed to imply the non-existence of any re levant patents nor t o constitute a permission. Inducement or recOUU mendatlon to practice any Invention covered by any patent owned by American Cyanamid or b y otfaers, without authority from tho owner of the patent .
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Hie Chemical World Ms Week C O N Τ Ι Ν U E D
I N T E R N A T I O N A L No slowdown is seen in radioisotopes production a t Britain's Radiochemical Center a t Amersham. Sales now run over $1.25 million a year, with 70% of the output exported. Page 80.
EDU CAT ι ON High schools short on science teachers will welcome a new series of films made at the University of Florida. These sound-and-color films, to be available next year, make up an entire course in high school chemistry. Page 88. Business can still place college graduates with no trouble. Annual survey shows that only 66% of the technical openings and 80% of the nontechnical were filled this year. Page 90. Only α fifth of U. S. graduate students have enrolled in the physical sciences, NSF survey shows. Chemistry brightens the picture, however, by making the best showing. Page 90.
ACS N E W S Ten years of chemical progress are assembled in Chemical Abstracts Fifth Decennial Index, coming out over the next four years. Formula and numerical patent indexes supplement author and subject entries in this 19-volume decennial. Page 10O.
ASS OC I ATI Ο Ν s Molecular Physics in Chemical Engineering will be the topic of the "Christmas" Symposium being lined up by the ACS Division of Industrial and Engineering Chemistry. Page 108.
CHEUICAUND ENGINEERING
NEWS the newsmagazine of the chemical world VOLUME 35, NUMBER 46 NOVEMBER 18, 1957
Mg Chemical/Metallurgical Uses Grow . . C. K. Bjork and P. F. George CA's Perennial Decennial E. J. Crane ACS News . . Associations . . Books Chemical World Chemicals . . . Concentrates Editorial . . Education . . Equipment . . . Government Industrial Lîtera
This Week
ture . . . .
100 108 96
3 53 23
7 88 56 42 62
72 100 28 80 9
39 36
Industry & Business International Letters Management . . . . . Markets News Focus 134 News-Scripts 136 People I 14 Production 50 Research 48 Secretary's Office 106
© Copyright 1957 by the AMERICAN CHEMICAL SOCIETY
Published w e e k l y by the American Chemical Society, from 20th and Northampton S t s . , Easton, Pa. Entered a s second-class mat ter at the Post Office at E a s t o n , Pa., U .S .A . , under the Act o f March 3 , 1 8 7 9 .
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A N I L I N E a growing intermediate
for your industry An old-timer, true—but even in these days of innumerable multipurpose intermediates, aniline finds growing use as an economical s tart ing point in the manufacture of:
• Rubber Chemicals • Dye Intermediates • Explosives • Pigments • Pharmaceuticals • Photochemicals • Selective Solvents
Now, complete physical properties of aniline are presented in Cyanamid's new eight-page data book. Particularly interesting to those using aniline is the detailed section on "Analytical Test Methods. "
err CYANAMID AMERICAN CYANAMID C O M P A N Y
Intermediates Department
Bound Brook, New Jersey
Please send me the following material on A N I L I N E
• Da ta Book • Prices
I 1 Sample (Because An i l i ne O i l is a tox ic
compound , samples a r e a v a i l a b l e on l y
t o qua l i f i ed personnel . )
NAME_
P O S I T I O N .
COMPANY-
STREET
CITY _ZONE STATE_
N O V . 18, 1 9 5 7 C & E N
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