Table of Contents

3
The \ . : -&k. t s< > >* , >r& "«A « / This Week Science gets α voice in national policymaking as President Eisenhower appoints MIT president James R. Killian, Jr., to new post of Presidential science adviser. Scientists approve the move but wonder whether this is the answer to long range problems of U. S. science. Page 25. FEATURE Magnesium's chemical and nonstructural uses are growing faster than the industry as a whole. At present over a third of primary production is going into chemical uses—tita- nium tetrachloride reduction and Grignard reagents. Page 72. INDUSTRY & BUSINESS Petroleum products sales lag this year. Some declines are blamed on industrial production drop, but lack of gasoline consumption growth confounds the oil industry. Page 28. More of the same—process firms indict high costs for erod- ing earnings so far this year. Some third-quarter reports take earnings for first nine months ahead of last year, but many others show drops. Page 30. MARKETS Influenza, the Asian type and ordinary kinds, has people running to the corner drugstore for aspirin. Result: record aspirin production. Trend to aspirin for rheumatism and arthritis also ups output. Page 36. MANAGEMENT Four factors will influence industrial relations of the future, says Labor Secretary Mitchell. Principal one: public insistence that labor and management conduct their busi- ness for public good. Page 39. GOVERNMENT Slowdown in U. S. atomic power development may lie ahead unless we have a reactor system that can be ex- ploited on a large scale in 1963. AEC's solution: push develop- ment of water cooled and moderated reactors to meet the atomic power timetable. Page 42. RESEARCH U. S. drug companies will spend 7.5% of sales this year for research—$127 million in all. This is $17 million more than last year. Main objects of this research are new drugs, better drugs, and cheaper drugs. Page 48. Organic materials capable of withstanding 1000° F. for prolonged periods of time are goal of chemists working in the lubrication field. The high-temperature goal of 500° F. set two years ago for 1965 already has been met. Page 49. PROPUCTION "Packaged" reprocessing plants seem a likely answer to the question, "Where will spent power reactor fuels be processed?" Such a plant could get additional revenue from the recovery of radioactive isotopes. Page 50. C H EM ICALS Two new silicone fluids—lubricants for the jet age—are stable to oxygen, perform at 700° F. General Electric designs new testing equipment to check silicones at higher tem- peratures than standard testers can take. Page 53. EQUIPMENT Speedy turbine mixer emigrates from Europe, is licensed by Swedish inventor for U. S. manufacture. Al- though still under test, the unit shows good results in mixing concrete, looks promising for chemicals. Page 56. AND Nalco has antifoams to stop foaming in virtually any aqueous solution • Antifoams to perform at any pH • Both oil base and water base anti- foams • Antifoams that are self-emulsifying with water • Autifoams with exceptional temperature stability We will gladly send you technical data • Just describe your foam- ing problem so we will be better able to help yon • NATIONAL ALUMINATE 6199 WeSt 66th:Place, Chicago 38, Illinois' NORTHVVESTÉRN U.S HAWAll ALASKÀ :^ t Flox Company, )nt., Minneapolis; Minrtl •; : - Alchènï. Liniifeê l Burlington, Ontpno r :. NOV. 18, 1957 C&EN 3 HIGH-GRADE3 HIGH-GRADE3 HIGH-GRADE3

Transcript of Table of Contents

Page 1: Table of Contents

The \

.

:

-&k.

t s<

>

>*, >r&

"«A «

/ This Week

Science g e t s α voice in nat ional policymaking as President Eisenhower appoints MIT president James R. Killian, Jr., to new post of Presidential science adviser. Scientists approve the move but wonder whether this is the answer to long range problems of U. S. science. Page 25.

F E A T U R E Magnesium's chemical and nonstructural uses are growing faster than the industry as a whole. At present over a third of primary production is going into chemical uses—tita­nium tetrachloride reduction and Grignard reagents. Page 72.

I N D U S T R Y & B U S I N E S S Pe t ro leum produc ts sales lag this yea r . Some declines are blamed on industrial production drop, but lack of gasoline consumption growth confounds the oil industry. Page 28. More of t he same—process firms indict high cos t s for erod­ing earnings so far this year. Some third-quarter reports take earnings for first nine months ahead of last year, but many others show drops. Page 30.

M A R K E T S Influenza, the Asian type and ordinary kinds, has people running to the corner drugstore for aspirin. Result: record aspirin production. Trend to aspirin for rheumatism and arthritis also ups output. Page 36.

M A N A G E M E N T Four factors wil l influence industrial relations of the future, says Labor Secretary Mitchell. Principal one: public insistence that labor and management conduct their busi­ness for public good. Page 39.

G O V E R N M E N T Slowdown in U. S. atomic power development may lie ahead unless we have a reactor system that can be ex­ploited on a large scale in 1963. AEC's solution: push develop­ment of water cooled and moderated reactors to meet the atomic power timetable. Page 42.

RESEARCH U. S. drug companies will spend 7 .5% of sales this year for research—$127 million in all. This is $17 million more than last year. Main objects of this research are new drugs, better drugs, and cheaper drugs. Page 48. Organic materials capable of withstanding 1000° F. for prolonged periods of time are goal of chemists working in the lubrication field. The high-temperature goal of 500° F. set two years ago for 1965 already has been met. Page 49.

P R O P U C T I O N "Packaged" reprocessing plants seem a likely a n s w e r to the question, "Where will spent power reactor fuels be processed?" Such a plant could get additional revenue from the recovery of radioactive isotopes. Page 50.

C H EM ICALS Two new silicone fluids—lubricants for the jet age—are stable to oxygen, perform at 700° F . General Electric designs new testing equipment to check silicones at higher tem­peratures than standard testers can take. Page 53.

EQUIPMENT Speedy turbine mixer emigrates from Europe, is licensed by Swedish inventor for U. S. manufacture. Al­though still under test, the unit shows good results in mixing concrete, looks promising for chemicals. Page 56.

AND Nalco has antifoams to stop foaming in virtually any a q u e o u s solution • Antifoams to perform at any pH • Both oil base and wa te r base anti-foams • Antifoams t h a t a r e s e l f - emu l s i fy ing wi th wa te r • Autifoams with exceptional

t e m p e r a t u r e s tabi l i ty • We will gladly send you technical d a t a • Just descr ibe your foam­ing p rob l em so we will b e bet ter a b l e to help yon •

NATIONAL AL UMINATE

6199 WeSt 66th:Place, Chicago 38, Illinois' NORTHVVESTÉRN U.S HAWAll ALASKÀ :^

t Flox Company, )nt., Minneapolis; Minrtl

•;: - Alchènï. Liniifeêl Burlington, Ontpnor:.

N O V . 18, 1957 C & E N 3

HIGH-GRADE3

HIGH-GRADE3

HIGH-GRADE3

Page 2: Table of Contents

CYANOETHYLATION

OH = CHCAJ t H*HS03 * ? 7 * g < > - ^03SCH2CHxCN

0 OdUtfûûpoJCU fàHSQz <*"**- lOOpoAtà. ΗχΟ ta-a. t^-fuck^

peùetL <r£ / faun.; tj^p&w£ùMl> mjcd*JbÀ*£d' at #0 -¥6 °C. bu- erf&AAiajL α«ΰ€οκα.·

φ H<&i, at ¥5*C. ^L 1 iaML; Ont tir RX OAKL £ôe<L{fru

WMMËM<0I

^^^^^^^gÈ^^B

^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^

fc *·'}*·*-<;>!&J&J ~KÙ^^WÊÊ&Ê£!gŒs£&

mm ^^^^Wtw^^m

^j i^^Bfe / ^ i S S f i B ^ ^ ^ X ^ ^ ^ ^ H i E

^ S K ^ ^ ^ ^ ^ ^ S H I

Sïl^Sli^^^P^SSI Ϊ Η Η Η ^ Η Β Ή Η Η

^jh-Zs

'ΛΑ » * i ' f

§Φ^ΙΕΚ**5*

!§§W-3?J

κ&* illif>* •»

BK*. HISSÉE** IHk i

mm

„,*. ^fetaag

Keeping Tabs on ACRYLONITRILE There are a great number of compounds, both organic and inorganic, possessing labile hydrogen atoms wh ich add readily to the carbon-carbon double bond of Acrylonitr i le. This reaction i s commonly known as "cyanoethy la t ion" .

The compounds that have been added to Acrylonitr i le to produce cyanoethyl derivatives may be classified according to the atom attached t o the reactive hy­drogen. Thus, examples of cyanoethyla­t ion of compounds conta in ing As-H, B-H, Br-H,C-H,CI-H, N-Η,Ο-Η, P-H,S-H, Si-H, and Sn-H have been reported. Among the specif ic classes of compounds that

undergo cyanoethylation are a var iety of amines, amides, alcohols, mercaptans, aldehydes, ketones, esters, inorganic acids and their salts.

The cyanoethylation reaction usually requires an alkaline medium (about pH 11-13). However, some aromatic and heterocyclic amines require an acidic catalyst such as acetic acid.

Synthesis problems? Cyanoethylat ion may offer an economical route to profit­able new products. Your nearest Cyan-amid Petrochemicals representative wil l be glad to show you the way.

Write for the 78-page "Poly­m e r s a n d Copo l ymers of A c r y l o n i t r i l e , " d e t a i l i n g many experimental proce­dures, l is t ing hundreds of polymer systems and sug­gesting many applications. American Cyanamid Com­pany, P e t r o c h e m i c a l s De­p a r t m e n t , 30 Rocke fe l l e r Plaza, New York 20, Ν. Υ.

ACRYLO TECHNICAL CENTER

Note: The foregoing· shal l not be construed to imply the non-existence of any re levant patents nor t o constitute a permission. Inducement or recOUU mendatlon to practice any Invention covered by any patent owned by American Cyanamid or b y otfaers, without authority from tho owner of the patent .

HIGH-GRADE3

Page 3: Table of Contents

Hie Chemical World Ms Week C O N Τ Ι Ν U E D

I N T E R N A T I O N A L No slowdown is seen in radioisotopes pro­duction a t Britain's Radiochemical Center a t Amersham. Sales now run over $1.25 million a year, with 70% of the output ex­ported. Page 80.

EDU CAT ι ON High schools short on science teachers will wel­come a new series of films made at the University of Florida. These sound-and-color films, to be available next year, make up an entire course in high school chemistry. Page 88. Business can still place college graduates with no trouble. Annual survey shows that only 66% of the technical openings and 80% of the nontechnical were filled this year. Page 90. Only α fifth of U. S. graduate students have enrolled in the physical sciences, NSF survey shows. Chemistry brightens the picture, however, by making the best showing. Page 90.

ACS N E W S Ten years of chemical progress are assembled in Chemical Abstracts Fifth Decennial Index, coming out over the next four years. Formula and numerical patent indexes sup­plement author and subject entries in this 19-volume decen­nial. Page 10O.

ASS OC I ATI Ο Ν s Molecular Physics in Chemical Engineering will be the topic of the "Christmas" Symposium being lined up by the ACS Division of Industrial and Engineering Chem­istry. Page 108.

CHEUICAUND ENGINEERING

NEWS the newsmagazine of the chemical world VOLUME 35, NUMBER 46 NOVEMBER 18, 1957

Mg Chemical/Metallurgical Uses Grow . . C. K. Bjork and P. F. George CA's Perennial Decennial E. J. Crane ACS News . . Associations . . Books Chemical World Chemicals . . . Concentrates Editorial . . Education . . Equipment . . . Government Industrial Lîtera

This Week

ture . . . .

100 108 96

3 53 23

7 88 56 42 62

72 100 28 80 9

39 36

Industry & Business International Letters Management . . . . . Markets News Focus 134 News-Scripts 136 People I 14 Production 50 Research 48 Secretary's Office 106

© Copyright 1957 by the AMERICAN CHEMICAL SOCIETY

Published w e e k l y by the American Chemical Society, from 20th and Northampton S t s . , Easton, Pa. Entered a s second-class mat ter at the Post Office at E a s t o n , Pa., U .S .A . , under the Act o f March 3 , 1 8 7 9 .

Subscription rates 1957: domest ic and Canada, 1 yr. $ 6 . 0 0 ; 2 y r . $ 1 0 . 0 0 ; 3 yr . $14.00; foreign, $15.00, $27 .50 , $40 .00 . Postage to countries not i n the Pan-American Union , $ 3 . 0 0 yearly. Canadian postage $1 .00 yearly. Single copies : current i ssues , $0.40, except for issue containing special section, Facts and Figures for the Chemical Process Industries, w h i c h is $ 2 . 0 0 . Claims for missing numbers w i l l not be a l lowed if received more than 60 days from date of mai l ing plus t i m e normally required for postal delivery of journal and claim. N o claims al lowed from subscribers in Centra! Europe, Asia, o r the Pacific Islands o ther than H a w a i i , or because o f failure to notify t h e Circulation Department o f a change of address, or because copy i s "missing from files."

C H A N G E O F A D D R E S S : Not i fy Circulat ion Department, American Chemical Society , 1155 Sixteenth S t . , N . W . , V/ashington 6, D . C. Such notif ication should include both old a n d new addresses and postal zone number, i f any. The American Chemical Soc iety also publishes: Industrial and Engineering Chemistry, Analytical Chemistry, Chemical Abstracts Service, Journal of tbt American Chemical Society, The Journal of Physical Chemistry, JrourtialofAgriculturalandFoodChemistry, a n d TheJournalofOrganic Chemistry. Rateson request.

A N I L I N E a growing intermediate

for your industry An old-timer, true—but even in these days of innumerable multipurpose intermediates, aniline finds growing use as an economical s tart ing point in the manufacture of:

• Rubber Chemicals • Dye Intermediates • Explosives • Pigments • Pharmaceuticals • Photochemicals • Selective Solvents

Now, complete physical properties of aniline are presented in Cyanamid's new eight-page data book. Particu­larly interesting to those using aniline is the detailed section on "Analytical Test Methods. "

err CYANAMID AMERICAN CYANAMID C O M P A N Y

Intermediates Department

Bound Brook, New Jersey

Please send me the following material on A N I L I N E

• Da ta Book • Prices

I 1 Sample (Because An i l i ne O i l is a tox ic

compound , samples a r e a v a i l a b l e on l y

t o qua l i f i ed personnel . )

NAME_

P O S I T I O N .

COMPANY-

STREET

CITY _ZONE STATE_

N O V . 18, 1 9 5 7 C & E N

HIGH-GRADE3

HIGH-GRADE3