Research Seminar for New Graduate Students...

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1 Richard P. Van Duyne Research Seminar for New Graduate Students Nano4003, 9:00 - 9:15 AM Thursday September 12, 2013 Molecular Plasmonics: Nanoscale Spectroscopy & Sensing Departments of Chemistry and Biomedical Engineering & The Applied Physics Program TECH K124, (847)-491-3561, [email protected]
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  • 1

    Richard P. Van Duyne

    Research Seminar for New Graduate StudentsNano4003, 9:00 - 9:15 AM Thursday September 12, 2013

    Molecular Plasmonics: Nanoscale Spectroscopy & Sensing

    Departments of Chemistry and Biomedical Engineering & The Applied Physics ProgramTECH K124, (847)-491-3561, [email protected]

  • 2

    What is the Mechanism?

    = E

    EFCHEM ~ 101 EFEM ~ 108

    EFSERS = 1 x 108

    Ek

    Benzenethiolhhoo h(h(oo--vib)

    Haes, Haynes, McFarland, Zou, Schatz, and Van Duyne, MRS Bulletin, 30, 368-375 (2005)P. Stiles, J. Dieringer, N. C. Shah, and R. P. Van Duyne, Ann. Rev. Anal. Chem., 1, 601-626 (2008)

    Surface Enhanced Raman Spectroscopy (SERS)

  • 3

    Van Duyne Group Research Portfolio #1Grand Challenge: Control light on the 1-100 nm Length Scale

    Plasmonic Materials

    MRS Bulletin, 30, 368 (2005)

    Plasmonic Biosensors

    Nature Materials, 7, 442 - 453 (2008)

    Single Molecule Spectroscopy

    JACS, 129, 16249-16256 (2007)

    Single Particle Spectroscopy

    JPCC, 116, 393-403 (2012)

  • 4

    Van Duyne Group Research Portfolio #2Ultrafast Plasmonics

    JPCL, 2, 1193-1203 (2011)

    Single Molecule TERS

    JPCC 116, 487-483 (2012)

    Ultrafast Photoionization Microscopy

    Nano. Lett. 12, 4823-4829 (2012)

    UHV-TERS

    Nano Lett. 12, 5061-5067 (2012)

  • 5

    Ultrahigh Vacuum Tip-Enhanced Raman Spectroscopy

    Ag tip is plasmonic amplifier

    All external optics

    < 2 x 10-11 torr

    Cryostat: 7K; 19K

    E. Foley, N. Jiang, A. McFarland, J. Klingsporn, M. Sonntag, J. Dieringer, M. Hersam, and R. P. Van Duyne, in preparation (2013)

  • 6

    15

    3

    2nm

    2nm

    9.1

    11.2 11.2

    Cross Section

    10pA

    , 2.0

    V

    Single molecules and/or clusters observed on the Ag(111) surface

    LT-UHV-STM R6G/Ag(111): 1 mW @ 532 nm Ag Tip

    J. Klingsporn, N. Jiang, E. Pozzi, M. Sonntag, D. Chulhai, T. Seideman, L. Jensen, M. Hersam, and R. Van Duyne, submitted (2013)

  • 7J. Klingsporn, N. Jiang, E. Pozzi, M. Sonntag, D. Chulhai, T. Seideman, L. Jensen, M. Hersam, and R. Van Duyne, submitted (2013)

    Line Narrowing in LT-UHV-TERS: R6G/Ag(111)

    14001450150015501600165017001750

    1700 1600 1500 1400

    Nor

    mal

    ized

    Inte

    nsity

    Raman Shift (cm-1)

    a

    b

    c

    d

    e

    RT-SERSAverage peakwidth: 20 cm-1

    RT-TERSAverage peakwidth: 17 cm-1

    LT-SERSAverage peakwidth: 18 cm-1

    LT-TERSAverage peakwidth: 9 cm-1

    LT-TERS fitresiduals

    15

    1310

    19

    16

    14

    21

    13

    26

    16

    9

    22

    16 24

    22

    22

    231314

    1921

    17 12

    (9)(18)

    11

    1700 1400 cm-1 Region

  • 8

    High Repetition Rate is Needed for SE-FSRS

  • 9

    High Resolution Plasmonic Sensors

    HR-LSPR Sensor: Calmodulin JACS, 130, 5836-5837 (2008)

    Nano Lett,11,1098-1105 (2011)

    Single Molecule LSPRNano Lett., 11, 1826-1830 (2011)

    Van Duyne Group Research Portfolio #3

    Super-Resolution LSPR MicroscopyJACS, 134, 1583215839 (2012)

  • 10

    SERS for Art Conservation ScienceVan Duyne Group Research Portfolio #4

    TLC-SERS for Fiber AnalysisAnal. Chem. 81, 3056-3062 (2009)

    SERS for Fiber AnalysisPCCP, 11, 7350-7359 (2009)

    SERS to Identify of Color in Mary CassattsPastels, Anal. Chem. 81, 7443-7447 (2009)

    SERS to Identify Color in Winslow HomersWatercolors, JRS 42, 1305-1310 (2011)

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    Van Duyne Group & Collaborators Summer 2013

    InternationalMikael Kll (Chalmers)

    Bill Barnes (Exeter)Besenbacher (Aarhus)

    Pileni (Paris VI)Vallee (Lyon)

    Liz-Marzan (Spain)

    NU, ChemistryHupp, Mirkin, Mrksich,

    Ratner, Schatz, Seideman, Stair, Weitz

    NU, Neuro.Bill Klein

    UIUC, ChemistrySligar

    AIC, Art Conserv.Casadio

    NU, MS&EHersam, Marks

    NU, BMEGlucksberg, Walsh, Zhang

    UCI, CaSTLApkarian, Ho

    3rd Row: Jon Dieringer, Matt Sonntag, Bogdan Nehru, Jordan Klingsporn, Eric Pozzi, Cassie George, Mike McAnally, James Brooks, Sicelo Manango, Dmitri Kurouski

    2nd Row: Nan Jiang, Naihao Chaing, Alex Peroff, Natalie Gruenke, Natalie Ray, Sanaiya Khatwani, Laura Ruvuna, Alyssa Zrimsek, Huayi Wang,David Pawletki

    1st Row: Nilam Shah,, Stephanie Zaleski, Bhavya Sharma, Fernanda Cardinal, Emily Sprague, Nathan Greeneltch, Anne-Isabelle Henry, Nolan Wong

  • 12

    Dongkuk University (Faculty)

    University of Connecticut (Faculty)

    Senior Scientist, EWG

    Teacher, Chicago Public Schools

    Scientist III, US Pharmocpieal

    University of Portland (Faculty)

    Vaxess Technologies

    Postdoc, NU (Van Duyne Group)

    Ph.D.(2007)

    Ph.D.(2008)

    Ph.D.(2008)

    M.S.(2008)

    Ph.D.(2009)

    Ph.D. (2010)

    Ph.D. (2010)

    Ph.D. (2010)

    2002-2007

    2003-2008

    2003-2008

    2006-2008

    2004-2009

    2005-2010

    2005-2010

    2005-2010

    Jiha Sung

    Jing Zhao

    David Q. Andrews

    Jenny Roden

    Kevin Biggs

    Paige Hall

    Kathryn Kosuda

    Julia Bingham

    IBM, Albany, NY (Scientist)Ph.D.(2007)2002-2007Erin C. McLellan

    Hillsdale College (Faculty)Ph.D.(2007)2002-2007Matthew A. Young

    Chemistry Instructor, Bossier Parish Community College (Faculty)

    Ph.D.(2007)2002-2007Leif J. Sherry

    Chemist, British PetroleumPh.D.(2007)2002-2007Alyson V. Whitney

    Res. Scientist, Schering PloughPh.D.(2006)2001-2006Chanda Ranjit Yonzon

    Res. Scientist, Eli LilyPh.D.(2006)2001-2006Xiaoyu Zhang

    Res. Scientist, Eli LilyPh.D.(2004)1999-2004Adam D. McFarland

    University of Iowa (Faculty)Ph.D.(2003)1999-2004Amanda J. Haes

    University of Minnesota (Faculty)Ph.D.(2003)1998-2003Christy L. Haynes

    Van Duyne Group: PlacementGraduate Students

  • 13

    Postdoc, NU (Van Duyne Group)

    Postdoc, NU (Van Duyne Group)

    ExxonMobil (Research Scientist)

    Enhanced Plasmonics, LLC (Founder)

    British Petroleum (Chemist)

    MedSphere Corp. (Biomed. Engineer)

    Ph.D.(2012)

    Ph.D.(2013)

    Ph.D.(2013)

    Ph.D.(2013)

    Ph.D.(2013)

    Ph.D.(2013)

    2007-2012

    2009-2013

    2009-2013

    2009-2013

    2009-2013

    2009-2013

    Samuel Kleinman

    Matt Sonntag

    Lauren Kreno

    Nathan Greeneltch

    Natalie Ray

    Ke Ma

    Rice University (Faculty, Mat. Sci.)Ph.D.(2012)2008-2012Emilie Ringe

    Van Duyne Group: PlacementGraduate Students #2

  • 14

    Van Duyne Group: Placement

    University of West Georgia (Faculty)

    University of Texas, Austin (Faculty)

    ZEV Capital Research (Analysis & Design)

    Avon (Program Manager)

    Clemson University (Faculty)

    University of Tennessee (Faculty)

    Saint Marys University (Faculty)

    Northwestern University (Res. Faculty)

    College of William & Mary (Faculty)

    Stepan Company (Research Scientist)

    Illinois Toolworks (Research Scientist)

    St. Xavier College (Faculty)

    Intel (Research Scientist)

    Washington University, St. Louis (Postdoc)

    Northwestern University (Res. Faculty)

    2003-2006

    2005-2007

    2005-2007

    2007-2008

    2006-2008

    2006-2008

    2007-2009

    2008-2010

    2007-2010

    2009-2011

    2009-2011

    2010-2011

    2010-2011

    2010-2012

    2008-2011

    Douglas A. Stuart

    Katherine A. Willets

    Paul L. Stiles

    Rebecca L. Stiles

    Jeffrey N. Anker

    Jon P. Camden

    Christa Brosseau

    Nilam Shah

    Kristin Wustholz

    Faith Boman

    Julia Ruemelle

    Julia Bingham

    Dragos Seghete

    Jon Yuen

    Jon Dieringer

    Postdoctoral Fellows

  • 15

    Van Duyne Group: Placement

    University of Cincinnati (Faculty)

    University of Minnesota (Faculty)

    Research Scientist, (OndaVia, Inc.)

    2009-2012

    2010-2013

    2012-2013

    Laura Sagle

    Renee Frontiera

    Samuel Kleinman

    Postdoctoral Fellows #2

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    Group Meetings:

    Open House:Date: 10/16/13Time: 4:00 6:00 pmPlace: Pancoe 2nd Floor near Einsteins

    Meet the group, see our work, enjoyfree FOOD and DRINKS

    Time: Thursdays 4-5 pmPlace: TECH K140

    Van Duyne Group

  • 17

    Van Duyne Travel ScheduleSeptember - November

    09/30/13 10/03/13: SciX

    10/28/13 10/29/13: Osaka, Japan

    10/21/13 10/23/13: ARO Workshop

    11/05/13 11/07/13: Singapore

    11/18/13 11/22/13: Nanjing, China

    10/30/13 10/31/13: DARPA

    09/14/13 09/27/13: Vacation

  • 18

    Van Duyne Group Project Summary (2013-2014)New Students = (2 full or 1 full & 2 joint)

    NSF (MRSEC): Plasmonics, Ultrafast Plasmon Switching, HRTEM

    NSF (CHE): Single Nanoparticle & Ultrafast Spectroscopy

    SERS/TERS in Art Conservation (Renewal Pending)Mellon Foundation:

    DOE (SISGR): Ultrafast TERS, Photocatalysis, Solar

    DARPA (IVN:Dx): in vivo Nanosensors

    NSF (CCI): Ultrafast TERS, Ultrafast Raman, electron transfer

    NSF (SCIART): NIR-SERS in Art Conservation (Renewal Pending)

    SERS Sensors Critical Care AnalytesBaxter:

    ARO SBIR (Phase II): SERS Gas Sensing

    AFOSR: Mechanism of CO2 Electrocatalysis (Pending)

    AFOSR MURI: Nanoscale Electrochemistry SECM/TERS (New)