NEW AIRCO ACETYLENK ALCOHOLS, GLYCOLS, AND DERIVATIVES VERSATILE STARTING POINTS FOR ORGANIC...

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NEW BOOKS Abstracts of Scientific Papers presented at the XVIIIth International Congress of Pure and Applied Chemistry, ν + 290 pages. University of Toronto Press, Toronto 5, Ont. 1961. $6.00. Chemical Thermodynamics. JOHN G. KIRKWOOD, IRWIN OPPENHEIM. ix -j- 261 pages. McGraw-Hill Book Co., Inc., 330 West 42nd St., New York 36, N.Y. 1961. $8.75. Textbook designed to serve as the basis of a senior or graduate course. Intended primarily for chemists, but useful to physicists and chemical engineers. The Chemistry of Natural Products. 286 pages. Butterworth Inc., 7235 Wisconsin Ave., Washington 14, D.C. 1961. $10.50. Lectures presented at the IUPAC Sym- posium on the Chemistry of Natural Products held in Melbourne, Canberra, and Sydney, Australia, August 1960. Demineralization by Electrodialysis. J. R. WILSON, editor, xv + 378 pages. Butterworth Inc., 7235 Wisconsin Ave., Washington 14, D.C. 1960. $14. Summarizes work of researchers and in- ventors in rapidly expanding field. The Determination of Stability Con- stants. FRANCIS J. C. ROSSOTTI, HAZEL ROSSOTTI. xiv -f- 425 pages. McGraw-Hill Book Co., Inc., 330 West 42nd St., New York 36, N.Y. 1961. $12.50. Book is designed as comprehensive guide to the study of complex formation in solution. For the graduate student in inorganic, physical, analytical, and bio- chemistry, and as a reference for teachers and research workers in these fields. Diagramm-Mappe. 2 Auflagc. Band 12. F. Bosnjakovic. 15 Diagramme. Ver- lagsbuchhandlung Theodor Steinkopff, Loschwitzer Strasse 32, Germany. 1961. DM 19. Encyclopedia of Explosives and Related Items. Vol. I. BASIL T. FEDOROFF et al xxvi + 768 pages. ( PB 171603 ) Office of Technical Services, U.S. De- partment of Commerce, Washington 25, D.C. 1960. $10. Fearon's Introduction to Biochemistry. 4th ed. J. E. JESSOP. vi + 473 pages. Academic Press Inc., I l l Fifth Ave., New York 3, N.Y. 1961. $8.00. An entire rewrite of the third edition, this book was finished by Dr. Jessop after the death of Dr. Fearon in 1959. The Pfizer Handbook of Microbial Metabolites. MAX W. MILLER, Χ -f- 772 pages. McGraw-Hill Book Co., Inc., 330 West 42nd St., New York 36, N.Y. 1961. $15. Book is said to represent the first effort to provide data on the source and the physical and chemical properties of all known metabolic products isolated from bacteria, molds, fungi, and lichens. pH Measurement and Titration. G. MATTOCK, G. ROSS TAYLOR, xiv -j- 406 pages. Macmillan Co., Fifth Ave., New York 11, N.Y. 1961. $14.50. Written primarily for executives in de- velopment, pilot production, and main production lines. Said to fill need for textbook which can be used by both prac- tically and theoretically trained engineers. PRODUCT STRUCTURAL FORMULA SUGGESTED APPLICATIONS METHYL BUTYN0L CH3 I CH3-C-C = C -H I 0H METHYL PENTYN0L CH3 I CH3-CH2-C-C = C-H I 0H Stabilizers in chlorinated solvents. Viscosity reducers and stabilizers. Electroplating brighteners. Inter- mediate in synthesis of hypnotics and isoprenoid chemicals such as Vitamin A, ionone and perfume alcohols. Solvents for alcohol- soluble nylon and polyamide resins. ETHYNYL CYCL0HEXAN0L <!>< C = C-.H *0H Corrosion inhibitor for mineral acids. Stabilizer in chlorinated organics. Synthesis of hypnotics, other pharma- ceuticals and perfumery materials. HEXYN0L CH3-CH2-CH2-CH-C =C-H I OH ETHYL 0CTYN0L CH3-CH2-CH2- CH2-CH3 I CH2-CH-CH- I OH C = C-H Corrosion inhibitors for mineral acids; high temperature oil well acidizing inhibitors. Inhibitors for acid pickling and cleaning baths, electrolytic cleaning baths and in electrolytic refining of metals. DIMETHYL HEXYNEDI0L CH3 CH3 I I CH3-C-C = C-C-CH3 I I OH OH Synthesis of peroxide catalysts and cross-linkers. Component in wire drawing lubricant formulations. Cou- pling agent in resin coatings. DIMETHYL HEXANEDI0L CH3 CH3 I I CH3-C-CH2-CH2-C-CH3 I I OH OH Synthesis of peroxide catalysts and cross-linkers, cyclic musk compounds and allethrin. ALSO AVAILABLE: AIRCO ALKYL ACETYLENES-METHYL ACETYLENE AND ETHYL ACETYLENE. Produced in commercial quantities only by Airco. Warehouse stocks are immediately available through Airco's nationwide distribution network. Ask your Airco man or write for detailed technical bulletins. AIR REDUCTION CHEMICAL & CARBIDE CO. A DIVISION OF AIR REDUCTION COMPANY, INCORPORATED · 150 EAST 42ND STREET, NEW YORK 17, NEW YORK · MURRAY HILL 2 - 6 7 0 0 AREA CODE 212 f/S|f5>\ Vinyl Monomers / /MmwS$\ Calcium Carbide / /'COLTSÏ^ Vinyl Monomers Acetylenic Chemicals /τΛΐ»ποΗΑνΛ Calcium Carbide \$AMIDV) Pipeline Acetylene Vinyl Resins Copolymers OCT. 3 0, 1961 C&EN 97 NEW AIRCO ACETYLENK ALCOHOLS, GLYCOLS, AND DERIVATIVES VERSATILE STARTINC? POINTC FOR O R G i i l i CHEMICAL SYNTHESES

Transcript of NEW AIRCO ACETYLENK ALCOHOLS, GLYCOLS, AND DERIVATIVES VERSATILE STARTING POINTS FOR ORGANIC...

NEW BOOKS

Abstracts of Scientific Papers presented at the XVIIIth International Congress of Pure and Applied Chemistry, ν + 290 pages. University of Toronto Press, Toronto 5, Ont. 1961. $6.00.

Chemical Thermodynamics. JOHN G. KIRKWOOD, IRWIN O P P E N H E I M . ix -j-261 pages. McGraw-Hill Book Co., Inc., 330 West 42nd St., New York 36, N.Y. 1961. $8.75.

Textbook designed to serve as the basis of a senior or graduate course. Intended primarily for chemists, but useful to physicists and chemical engineers.

The Chemistry of Natural Products. 286 pages. Butterworth Inc., 7235 Wisconsin Ave., Washington 14, D.C. 1961. $10.50.

Lectures presented at the IUPAC Sym­posium on the Chemistry of Natural Products held in Melbourne, Canberra, and Sydney, Australia, August 1960.

Demineralization by Electrodialysis. J. R. WILSON, editor, xv + 378 pages. Butterworth Inc., 7235 Wisconsin Ave., Washington 14, D.C. 1960. $14.

Summarizes work of researchers and in­ventors in rapidly expanding field.

The Determination of Stability Con­stants. FRANCIS J. C. ROSSOTTI, H A Z E L ROSSOTTI. xiv -f- 425 pages. McGraw-Hill Book Co., Inc., 330 West 42nd St., New York 36, N.Y. 1961. $12.50.

Book is designed as comprehensive guide to the study of complex formation in solution. For the graduate student in inorganic, physical, analytical, and bio­chemistry, and as a reference for teachers and research workers in these fields.

Diagramm-Mappe. 2 Auflagc. Band 12. F. Bosnjakovic. 15 Diagramme. Ver-lagsbuchhandlung Theodor Steinkopff, Loschwitzer Strasse 32, Germany. 1961. DM 19.

Encyclopedia of Explosives and Related Items. Vol. I. BASIL T. FEDOROFF et al xxvi + 768 pages. ( PB 171603 ) Office of Technical Services, U.S. De­partment of Commerce, Washington 25, D.C. 1960. $10.

Fearon's Introduction to Biochemistry. 4th ed. J. E. JESSOP. vi + 473 pages. Academic Press Inc., I l l Fifth Ave., New York 3, N.Y. 1961. $8.00.

An entire rewrite of the third edition, this book was finished by Dr. Jessop after the death of Dr. Fearon in 1959.

The Pfizer Handbook of Microbial Metabolites. MAX W. MILLER, Χ -f-772 pages. McGraw-Hill Book Co., Inc., 330 West 42nd St., New York 36, N.Y. 1961. $15.

Book is said to represent the first effort to provide data on the source and the physical and chemical properties of all known metabolic products isolated from bacteria, molds, fungi, and lichens.

pH Measurement and Titration. G. MATTOCK, G. ROSS TAYLOR, xiv -j-406 pages. Macmillan Co., Fifth Ave., New York 11, N.Y. 1961. $14.50.

Written primarily for executives in de­velopment, pilot production, and main production lines. Said to fill need for textbook which can be used by both prac­tically and theoretically trained engineers.

PRODUCT STRUCTURAL FORMULA SUGGESTED APPLICATIONS

METHYL BUTYN0L

CH3 I

C H 3 - C - C = C - H I 0H

METHYL PENTYN0L

CH3 I

C H 3 - C H 2 - C - C = C - H I 0H

Stabilizers in chlorinated solvents. Viscosity reducers and stabilizers. Electroplating brighteners. Inter­mediate in synthesis of hypnotics and isoprenoid chemicals such as Vitamin A, ionone and perfume alcohols. Solvents for alcohol-soluble nylon and polyamide resins.

ETHYNYL CYCL0HEXAN0L < ! > <

C = C-.H

*0H

Corrosion inhibitor for mineral acids. Stabilizer in chlorinated organics. Synthesis of hypnotics, other pharma­ceuticals and perfumery materials.

HEXYN0L C H 3 - C H 2 - C H 2 - C H - C = C - H

I OH

ETHYL 0CTYN0L CH3-CH2-CH2-

CH2-CH3 I

CH2-CH-CH-I OH

C = C-H

Corrosion inhibitors for mineral acids; high temperature oil well acidizing inhibitors. Inhibitors for acid pickling and cleaning baths, electrolytic cleaning baths and in electrolytic refining of metals.

DIMETHYL HEXYNEDI0L

CH3 CH3 I I

CH3-C-C = C-C-CH3 I I OH OH

Synthesis of peroxide catalysts and cross-linkers. Component in wire drawing lubricant formulations. Cou­pling agent in resin coatings.

DIMETHYL HEXANEDI0L

CH3 CH3 I I

C H 3 - C - C H 2 - C H 2 - C - C H 3 I I OH OH

Synthesis of peroxide catalysts and cross-linkers, cyclic musk compounds and allethrin.

ALSO AVAILABLE: AIRCO ALKYL ACETYLENES-METHYL ACETYLENE AND ETHYL ACETYLENE.

Produced in commercial quantities only by Airco. Warehouse stocks are immediately available through Airco's nationwide distribution network. Ask your Airco man or write for detailed technical bulletins.

AIR REDUCTION CHEMICAL & CARBIDE CO. A DIVISION OF AIR REDUCTION COMPANY, INCORPORATED · 150 EAST 42ND STREET, NEW YORK 17, NEW YORK · MURRAY HILL 2-6700 AREA CODE 212

f / S | f 5 > \ Vinyl Monomers / /MmwS$\ Calcium Carbide / /'COLTSÏ^ Vinyl Monomers Acetylenic Chemicals

/τΛΐ»ποΗΑνΛ Calcium Carbide \$AMIDV) Pipeline Acetylene

Vinyl Resins Copolymers

O C T . 3 0, 1 9 6 1 C & E N 97

NEW AIRCO ACETYLENK ALCOHOLS, GLYCOLS, AND DERIVATIVES

VERSATILE STARTINC? POINTC FOR O R G i i l i

CHEMICAL SYNTHESES