Lecture 6: More HSAB & Arrow-Pushing · 2017-12-22 · Lecture 6: More HSAB & Arrow-Pushing...

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Lecture 6: More HSAB & Arrow-Pushing Announcements: Problem Set 3 posted online. Due Thurs, 9/21/17 Today: Hard-Soft Acid-Base Theory (HSAB) - continued More arrow-pushing Basic conditions Substitution at electrophilic π-bonds Acidic Conditions Stability, formation, and reactions of carbocations

Transcript of Lecture 6: More HSAB & Arrow-Pushing · 2017-12-22 · Lecture 6: More HSAB & Arrow-Pushing...

Page 1: Lecture 6: More HSAB & Arrow-Pushing · 2017-12-22 · Lecture 6: More HSAB & Arrow-Pushing Announcements: • Problem Set 3 posted online. Due Thurs, 9/21/17 Today: • Hard-Soft

Lecture 6: More HSAB & Arrow-Pushing Announcements:

Problem Set 3 posted online. Due Thurs, 9/21/17•Today:

Hard-Soft Acid-Base Theory (HSAB) - continued•More arrow-pushing•

Basic conditions ◦Substitution at electrophilic π-bonds‣

Acidic Conditions◦Stability, formation, and reactions of carbocations‣

Page 2: Lecture 6: More HSAB & Arrow-Pushing · 2017-12-22 · Lecture 6: More HSAB & Arrow-Pushing Announcements: • Problem Set 3 posted online. Due Thurs, 9/21/17 Today: • Hard-Soft
Page 3: Lecture 6: More HSAB & Arrow-Pushing · 2017-12-22 · Lecture 6: More HSAB & Arrow-Pushing Announcements: • Problem Set 3 posted online. Due Thurs, 9/21/17 Today: • Hard-Soft
Page 4: Lecture 6: More HSAB & Arrow-Pushing · 2017-12-22 · Lecture 6: More HSAB & Arrow-Pushing Announcements: • Problem Set 3 posted online. Due Thurs, 9/21/17 Today: • Hard-Soft
Page 5: Lecture 6: More HSAB & Arrow-Pushing · 2017-12-22 · Lecture 6: More HSAB & Arrow-Pushing Announcements: • Problem Set 3 posted online. Due Thurs, 9/21/17 Today: • Hard-Soft
Page 6: Lecture 6: More HSAB & Arrow-Pushing · 2017-12-22 · Lecture 6: More HSAB & Arrow-Pushing Announcements: • Problem Set 3 posted online. Due Thurs, 9/21/17 Today: • Hard-Soft
Page 7: Lecture 6: More HSAB & Arrow-Pushing · 2017-12-22 · Lecture 6: More HSAB & Arrow-Pushing Announcements: • Problem Set 3 posted online. Due Thurs, 9/21/17 Today: • Hard-Soft