Large Area Sputter Deposition for Metal Oxide TFT...

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External Use Large Area Sputter Deposition for Metal Oxide TFT Applications using Rotary Cathode Technology Marcus Bender R&D PVD Display Applied Materials FPD International China, Beijing September 11 th , 2013

Transcript of Large Area Sputter Deposition for Metal Oxide TFT...

External Use

Large Area Sputter Deposition for Metal Oxide TFT Applications using Rotary Cathode Technology

Marcus BenderR&D PVD DisplayApplied MaterialsFPD International China, BeijingSeptember 11th, 2013

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Trends in Display Technology

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New Requirements for Backplane Performance

Ultra High Resolution

Ultra Large Displays

High Refresh Rate (3D)

Low Power Consumption

Slim BezelDesign

Uniform and Stable, High Mobility TFT with simple

Structure and lowManufacturing Costs!

OLED TV

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Excellent Cooling, Low SurfaceTemperature, Enabling high DR

No Nodule FormationNo Redeposition Zones

Rotary Target Technology

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High Material Utilization

New 80%

Racetracks

Rotary Target

TU ~ 80%

Tmax ~ 80°C

AKT PiVotTM

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Uniform IGZO: Ion Bombardment ControlµPCDMura free IGZO

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Excursion: Oxygen Ion Bombardment

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Reactive Sputtering• Oxygen creates energetic

and highly directional ionbombardment locallychanging layer propertiesduring growth

Bombardment Directions• O- Ions always leaving the target

surface perpendicular• Planar: No control of directions,

changing with target lifetime• Rotary: Geometry constant, no

change over lifetime

Tominaga, Thin Solid Films 1999

TOF: Dominant Species O- Ions

De Gryse, Thin Solid Films 2012

O- Ion Trajectories: Planar vs. Rotary

1m betweenDetector andSource

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PiVot: Ion Bombardment Control

Split sputter mode (SSM)– Superposition of two sinusoidal

profiles

Minimize Bombardment Impact (large angle, reduced energy)

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Perfect wobbling (PW)– Magnet movement sweeps

plasma across substrate

Widely spread Bombardmentexposure across substrate

Two Concepts for unique Magnet Motion in PiVot:

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µPCD: Correlations with IGZO TFT

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Reported direct correlation between µPCD measurement and TFT performance (by Kobelco)

μ-PCR (peak reflectivity signal) proportional to the carrier densityand carrier mobility

μ-PCD lifetime is characteristic to the recombination process of carriers, depending on quality of the IGZO

correlation with TFT stability expected Kobelco, APL 2011

µPCR

TFT

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Uniform IGZO: Tuning µPCR profilesTwo routes towards more uniform reflectivity profiles

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Ion Bombardment Control• Energetic oxygen ion

bombardment locally increasingmicrowave reflectivity

• Magnet movement improving asdepo non-uniformities

• PiVot can eliminate targetimprints

IGZO Post Annealing• As depo non uniformities in µPCR

can be reduced by annealing

µPCR 4.8% after annealing

4.7% THK uniformity

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Uniform IGZO: Gen8.5 horizontal µPCD scans

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Both, lifetime and amplitude homogeneity significantly improving byapplying and optimizing magnet movement

Unif. ≈ 40% Unif. ≈ 20%

Unif. < 5% Unif. ≈ 10%

Local Unif. ≈ 16% Local Unif. ≈ 12%

Local Unif. << 5%Local Unif. << 5%

OptimizedMagnet

Movement

No Magnet Movement

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Mura Free IGZO from PiVot

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Two kinds of mura known from PVD IGZO deposition

Target Pitch Mura• Reported Vth differences with

correlation to target positions forcompetitor system

Bond Gap / Target Tile Mura• No increase in peak reflectivity in

front of bond gap area• Data shows no target tile mura for

IGZO rotary targets

2x IGZO rotary target at 60% Utilization

Arai, Sony Corporation, SID 2012

Minimized Vth differencebetween and in front of target

Mura free IGZO Backplane

4 TFTs foreach position Bond gapBond gap

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Stable IGZO TFT: PVD Al2O3 performance

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Significant Stability Improvement of IGZO TFT reported

Challenges: Low deposition rate, slow etch

PVD Al2O3: Advanced Barrier Layer

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Arai, Sony Corporation, SID 2010

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StatusThickness 150 -1000 ÅThicknessuniformity

± 9.0%(Gen 8.5, wobbling)

Breakdownvoltage

~ 2-3 MV/cm

Density 3.1-3.2 g/cm³Deposition rate 100-150 Å/minRefractiveIndex @ 550 nm

1.59 – 1.7

Uniformityrefractive index

~ ± 1 %(Gen 8.5, wobbling)

WER (DHF) 40~140 Å/min(depends on pO2)

PVD Al2O3 Performance Gen8.5

tunif = +/- 9.0%

n550nm = +/- 1.1%

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ConclusionIGZO TFT emerging as a-Si replacement for high resolution mobile applications and large scale high definition LCD and OLED TVs

Rotary target technology combined with unique magnet movement enable uniform PVD IGZO deposition

TFT performance uniformity, especially Von, suitable for LCD andOLED applications

Fully reactive Al2O3 process with metal-like uniformity achieved withrotary target array

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AcknowledgementsSpecial Thanks to:

Evelyn ScheerAndreas Klöppel

Jian LiuHyun Chan Park

Rodney LimDong Kil YimHarvey You

Hao-Chien Hsu

and everybody contributing to AMAT Metal Oxide progress around theglobe

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