Individual-particle studies of cloud droplet residues and ambient aerosols in RICO: the effect of...

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Individual-particle studies of cloud droplet residues and ambient aerosols in RICO: the effect of particle size, composition, surface properties, and mixing state on trade wind cumuli. Jim Anderson Environmental Fluid Dynamics Program Peter Crozier Center for Solid State Science Arizona State University n collaboration with Cindy Twohy, Oregon State Univ

Transcript of Individual-particle studies of cloud droplet residues and ambient aerosols in RICO: the effect of...

  • Individual-particle studies of cloud droplet residues and ambient aerosols in RICO: the effect of particle size, composition, surface properties, and mixing state on trade wind cumuli.

    Jim AndersonEnvironmental Fluid Dynamics Program Peter CrozierCenter for Solid State ScienceArizona State UniversityIn collaboration with Cindy Twohy, Oregon State Univ.

  • Are giant (dry radius > 1 m) and ultragiant nuclei (dry radius > 10 m) present in the aerosol, are they responsible for the onset of precipitation, and what are their compositions and mixing states?

    For smaller hygroscopic inorganic nuclei (sea salt, reacted sea salt, sulfate), what are the relationships with regard to preferential activation, and what are their compositions and mixing states?

    Objectives

  • During North African dust episodes, what effect does mineral dust have on cloud properties and precipitation? How important is aggregation or coating of dust with sulfate, nitrate, or other species?

    What evidence is there of aerosol aging and cloud processing (e.g., reacted sea salt)?

    Do other aerosol types such as elemental carbon and low-volatility organic species play a role in trade-wind cumulus cloud properties?

  • Analytical methods

    Automated scanning electron microscopy

    High-resolution SEM imaging with standard Field Emission SEM

    Transmission electron microscopy of submicronParticles

  • Imaging under elevated RH with environmental Field Emission SEM

    Environmental TEM analysis of submicron particles under elevated RH (3 different SEMs, 3 or 4 TEMs)

  • Inlets and sampling systems (all on C-130):

    Counterflow Virtual Impactor (Cindy Twohy), cloud droplet residues single stagepolycarbonate membrane filter for SEM, 3-stage micro-impactor with 3 mm grids for TEM.

    Total Aerosol Sampler (TAS) 90 mmpolycarbonate membrane filter

    Solid diffuser inlet (SDI) 3-stage micro-impactor, interested in submicron ambientaerosol for TEM.

  • Barbados, April 1992

  • (% by N; Dp>0.2 mm)DYCOMS IIautomated SEMresults

  • PELTI (July 2001, flying out of St. Croix)

  • A fairly high percentage of particles > 10 microns can be biogenicin origin. (Barbados, July 1992)

  • Conventional TEM

  • P. Crozier & J. AndersonArizona State Univ.

  • Anderson, Crozier ASUTwohy - OSUOrganic clouddroplet residues(TEM bright field)

  • Relative concentrations of carbon (blue), nitrogen (magenta) and sulphur (yellow) as functions of position (in nanometers) from 400 nm carbon rich particle.

    Chart2

    2933224.7475-18.99126

    977.83632.9615150.7721

    289.8167.6569190.156

    107.11803.8021166.7709

    482.25-11.07014128.1983

    104.561082.319185.1768

    -705.73255.844649.52895

    -116.14487.9468235.7801

    -36.55210.2363200.181

    306.18-215.254150.28325

    702.58126.757282.0514

    1549.93-166.0029177.5753

    3201.68458.22387.33363

    12576.5582352927706.1695527.2024

    15011.1105211623815.8001628.2828

    16434.02161737124212.38890.2621

    16802.98123687663856.8181201.191

    17152.91902017284874.0771424.008

    17024.59684295355037.2131694.911

    16853.33681889135034.2731925.902

    17552.684964875911.0781872.734

    16953.37795109275058.5212056.793

    15915.20263582834495.1951782.685

    14900.81091283275093.7991654.026

    13712.31246752284503.1151557.534

    11561.06952189234220.9941075.562

    9397.17866116652797.0271093.842

    4480.06402913742393.202821.9918

    1283.11966.127313.1376

    326.48974.1765276.2111

    -311.997.53945176.6154

    -903.81481.6145128.8561

    -295.08224.3339297.6981

    -140.56-196.8133193.3611

    70.72261.45159.59853

    571.82-582.077477.88694

    51.1729.21347125.8859

    -100.878.9465564.22807

    -262.82162.4026224.7318

    CorrectedC

    S

    N

    02

    CPositionCorrectied CSPositionS/C

    0.00E+003.08E+040.00E+002.81E+030.00E+00-8.00E+020.00E+00-2.84E-01

    2.33E-082.96E+042.33E+011.64E+032.33E+01-9.36E+012.33E+10-5.70E-02

    4.65E-082.97E+044.65E+011.72E+034.65E+01-3.56E+024.65E+10-2.07E-01

    6.98E-082.90E+046.98E+019.53E+026.98E+01-8.14E+016.98E+10-8.55E-02

    9.31E-082.83E+049.31E+012.85E+029.31E+01-6.97E+019.31E+10-2.44E-01

    1.16E-072.84E+041.16E+024.40E+021.16E+02-5.19E+021.16E+11-1.18E+00

    1.40E-072.80E+041.40E+02-4.22E+011.40E+027.28E+011.40E+11-1.72E+00

    1.63E-072.80E+041.63E+022.53E+001.63E+02-5.90E+021.63E+11-2.33E+02

    1.86E-072.81E+041.86E+021.17E+021.86E+02-1.17E+021.86E+11-1.01E+00

    2.09E-072.82E+042.09E+021.65E+022.09E+02-5.95E+002.09E+11-3.62E-02

    2.33E-072.86E+042.33E+026.10E+022.33E+02-4.30E+022.33E+11-7.04E-01

    2.56E-072.91E+042.56E+021.07E+032.56E+02-3.99E+012.56E+11-3.73E-02

    2.79E-073.06E+042.79E+022.61E+032.79E+02-1.29E+002.79E+11-4.94E-04

    3.02E-073.17E+043.02E+023.68E+033.02E+02-9.26E+013.02E+11-2.52E-02

    3.26E-073.20E+043.26E+024.01E+033.26E+021.85E+023.26E+114.62E-02

    3.49E-073.18E+043.49E+023.82E+033.49E+021.52E+033.49E+113.98E-01

    3.72E-073.19E+043.72E+023.88E+033.72E+021.03E+033.72E+112.65E-01

    3.96E-073.23E+043.96E+024.30E+033.96E+022.17E+033.96E+115.04E-01

    4.19E-073.25E+044.19E+024.50E+034.19E+022.18E+034.19E+114.85E-01

    4.42E-073.26E+044.42E+024.58E+034.42E+023.14E+034.42E+116.86E-01

    4.65E-073.28E+044.65E+024.78E+034.65E+022.79E+034.65E+115.83E-01

    4.89E-073.26E+044.89E+024.65E+034.89E+022.67E+034.89E+115.74E-01

    5.12E-073.25E+045.12E+024.46E+035.12E+021.65E+035.12E+113.70E-01

    5.35E-073.21E+045.35E+024.13E+035.35E+022.52E+035.35E+116.09E-01

    5.58E-073.18E+045.58E+023.81E+035.58E+021.93E+035.58E+115.06E-01

    5.82E-073.14E+045.82E+023.44E+035.82E+022.44E+035.82E+117.09E-01

    6.05E-073.11E+046.05E+023.09E+036.05E+022.14E+036.05E+116.93E-01

    6.28E-073.07E+046.28E+022.74E+036.28E+021.53E+036.28E+115.59E-01

    6.52E-073.01E+046.52E+022.14E+036.52E+022.15E+036.52E+111.01E+00

    6.75E-072.96E+046.75E+021.58E+036.75E+021.29E+036.75E+118.14E-01

    6.98E-072.98E+046.98E+021.76E+036.98E+029.68E+006.98E+115.51E-03

    7.21E-072.90E+047.21E+021.00E+037.21E+026.55E+017.21E+116.53E-02

    7.45E-072.89E+047.45E+028.93E+027.45E+02-2.91E+027.45E+11-3.26E-01

    7.68E-072.82E+047.68E+022.18E+027.68E+02-9.85E+027.68E+11-4.53E+00

    7.91E-072.77E+047.91E+02-2.95E+027.91E+022.61E+027.91E+11-8.86E-01

    8.14E-072.80E+048.14E+026.85E+008.14E+02-4.88E+028.14E+11-7.12E+01

    8.38E-072.78E+048.38E+02-2.08E+028.38E+02-5.48E+018.38E+112.64E-01

    8.61E-072.79E+048.61E+02-8.74E+018.61E+02-1.38E+028.61E+111.58E+00

    8.84E-072.80E+048.84E+02-3.20E+018.84E+02-3.17E+028.84E+119.88E+00

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    Correctied C

    S

    03

    CPositionCorrectedCPositonS

    0.00E+002.91E+040.00E+001.10E+030.00E+001.15E+03

    3.05E-082.84E+043.05E+013.91E+023.05E+01-3.03E+02

    6.09E-082.76E+046.09E+01-3.69E+026.09E+01-3.67E+01

    9.14E-082.78E+049.14E+01-1.77E+029.14E+01-7.31E+01

    1.22E-072.81E+041.22E+021.31E+021.22E+02-5.51E+02

    1.52E-072.82E+041.52E+021.54E+021.52E+024.73E+01

    1.83E-072.76E+041.83E+02-3.93E+021.83E+02-3.51E+01

    2.13E-072.70E+042.13E+02-1.03E+032.13E+028.13E+02

    2.44E-072.73E+042.44E+02-7.23E+022.44E+021.53E+01

    2.74E-072.87E+042.74E+027.32E+022.74E+02-1.31E+03

    3.05E-072.97E+043.05E+021.71E+033.05E+02-1.10E+03

    3.35E-073.11E+043.35E+023.10E+033.35E+024.86E+02

    3.66E-073.20E+043.66E+024.02E+033.66E+021.36E+03

    3.96E-073.24E+043.96E+024.38E+033.96E+021.84E+03

    4.26E-073.29E+044.26E+024.95E+034.26E+022.15E+03

    4.57E-073.32E+044.57E+025.22E+034.57E+022.11E+03

    4.87E-073.36E+044.87E+025.60E+034.87E+024.36E+03

    5.18E-073.37E+045.18E+025.66E+035.18E+024.33E+03

    5.48E-073.40E+045.48E+025.98E+035.48E+023.74E+03

    5.79E-073.40E+045.79E+025.95E+035.79E+025.46E+03

    6.09E-073.40E+046.09E+026.01E+036.09E+023.47E+03

    6.40E-073.38E+046.40E+025.77E+036.40E+023.88E+03

    6.70E-073.34E+046.70E+025.37E+036.70E+024.64E+03

    7.01E-073.31E+047.01E+025.07E+037.01E+023.51E+03

    7.31E-073.27E+047.31E+024.71E+037.31E+023.31E+03

    7.61E-073.22E+047.61E+024.25E+037.61E+022.67E+03

    7.92E-073.14E+047.92E+023.43E+037.92E+022.15E+03

    8.22E-073.07E+048.22E+022.66E+038.22E+021.56E+03

    8.53E-072.98E+048.53E+021.80E+038.53E+021.05E+03

    8.83E-072.97E+048.83E+021.66E+038.83E+029.86E+02

    9.14E-072.89E+049.14E+028.53E+029.14E+02-1.44E+02

    9.44E-072.85E+049.44E+025.45E+029.44E+02-8.01E+02

    9.75E-072.87E+049.75E+026.62E+029.75E+02-4.98E+02

    1.01E-062.80E+041.01E+034.77E+011.01E+03-3.11E+02

    1.04E-062.81E+041.04E+035.89E+011.04E+03-1.11E+03

    1.07E-062.79E+041.07E+03-1.42E+021.07E+03-3.61E+02

    1.10E-062.73E+041.10E+03-6.82E+021.10E+032.19E+02

    1.13E-062.82E+041.13E+032.00E+021.13E+031.51E+02

    1.16E-062.88E+041.16E+038.44E+021.16E+03-4.13E+02

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    CorrectedC

    S

    04

    shift580lambda510r300S20918C3006N1353O694

    BlobC/S0.143703987c/n2.22172949c/o4.3314121037

    CPositionThicknessCorrectionCorrected CPositionSPositionNPositionOPositionS/CPositionN/CO/CPositionCarbonSulphurOxygenNitrogenSum

    0.00E+003.48E+040.00E+000.00E+001.00E+001.79E+030.00E+007.26E+020.00E+002.25E+020.00E+00-2.04E+010.00E+005.84E-020.00E+000.2799627406-0.049568352907.76E-014.53E-02-3.85E-022.17E-011.00E+00

    3.00E-083.39E+043.00E+010.00E+001.00E+008.65E+023.00E+012.87E+023.00E+011.21E+023.00E+011.08E+023.00E+014.77E-023.00E+010.30992184680.538582469329.965615.27E-012.52E-022.84E-011.63E-011.00E+00

    5.99E-083.20E+045.99E+010.00E+001.00E+00-9.90E+025.99E+016.71E+025.99E+013.18E+025.99E+01-7.71E+005.99E+01-9.74E-025.99E+01-0.7123237890.03370332759.931214.47E+00-4.35E-011.50E-01-3.18E+001.00E+00

    8.99E-083.24E+048.99E+010.00E+001.00E+00-6.31E+028.99E+012.53E+038.99E+012.74E+028.99E+01-6.13E+018.99E+01-5.77E-018.99E+01-0.96399230480.420453439389.89682-8.31E+004.79E+00-3.49E+008.01E+001.00E+00

    1.20E-073.24E+041.20E+020.00E+001.00E+00-5.51E+021.20E+023.84E+031.20E+024.82E+021.20E+021.29E+021.20E+02-1.00E+001.20E+02-1.9436637521-1.0135178913119.8624-3.38E-013.38E-013.43E-016.57E-011.00E+00

    1.50E-073.10E+041.50E+020.00E+001.00E+00-1.96E+031.50E+021.69E+031.50E+021.74E+021.50E+02-1.33E+021.50E+02-1.24E-011.50E+02-0.19710391810.2931640564149.8281.03E+00-1.28E-013.02E-01-2.03E-011.00E+00

    1.80E-073.11E+041.80E+020.00E+001.00E+00-1.92E+031.80E+021.81E+031.80E+021.24E+021.80E+02-4.35E+011.80E+02-1.36E-011.80E+02-0.14369439120.0984217215179.79361.22E+00-1.66E-011.20E-01-1.75E-011.00E+00

    2.10E-073.11E+042.10E+020.00E+001.00E+00-1.93E+032.10E+028.49E+022.10E+022.61E+022.10E+027.95E+012.10E+02-6.32E-022.10E+02-0.3006425756-0.1783426598209.75922.18E+00-1.38E-01-3.90E-01-6.57E-011.00E+00

    2.40E-073.05E+042.40E+020.00E+001.00E+00-2.52E+032.40E+022.55E+022.40E+022.31E+022.40E+02-2.32E+012.40E+02-1.46E-022.40E+02-0.20392893730.0398630127239.72481.22E+00-1.77E-024.85E-02-2.48E-011.00E+00

    2.70E-073.15E+042.70E+020.00E+001.00E+00-1.52E+032.70E+028.67E+022.70E+024.31E+022.70E+023.74E+012.70E+02-8.18E-022.70E+02-0.6288289233-0.1063640389269.69055.46E+00-4.47E-01-5.81E-01-3.44E+001.00E+00

    3.00E-073.36E+043.00E+021.07E+028.11E-016.84E+033.00E+02-2.54E+023.00E+027.86E+023.00E+02-4.68E+013.00E+02-5.35E-033.00E+020.2553004467-0.0296221749299.65618.19E-01-4.38E-03-2.43E-022.09E-011.00E+00

    3.30E-073.49E+043.30E+021.65E+027.23E-011.11E+043.30E+026.79E+023.30E+021.07E+033.30E+02-1.30E+023.30E+028.81E-033.30E+020.2157311645-0.0507948522329.62178.52E-017.51E-03-4.33E-021.84E-011.00E+00

    3.60E-073.56E+043.60E+022.04E+026.71E-011.34E+043.60E+029.48E+023.60E+021.45E+033.60E+028.12E+013.60E+021.02E-023.60E+020.23931938260.0262174297359.58737.84E-017.96E-032.06E-021.88E-011.00E+00

    3.90E-073.65E+043.90E+022.32E+026.35E-011.55E+043.90E+023.87E+033.90E+021.95E+033.90E+02-7.23E+013.90E+023.58E-023.90E+020.2799853239-0.0201867155389.55297.72E-012.77E-02-1.56E-022.16E-011.00E+00

    4.20E-073.76E+044.20E+022.53E+026.08E-011.75E+044.20E+023.48E+034.20E+021.96E+034.20E+02-2.61E+014.20E+022.86E-024.20E+020.2484200173-0.0064608757419.51857.87E-012.25E-02-5.09E-031.96E-011.00E+00

    4.49E-073.82E+044.49E+022.70E+025.89E-011.88E+044.49E+026.02E+034.49E+022.37E+034.49E+025.96E+014.49E+024.62E-024.49E+020.28127469930.0137666094449.48417.46E-013.44E-021.03E-022.10E-011.00E+00

    4.79E-073.90E+044.79E+022.83E+025.75E-012.01E+044.79E+025.79E+034.79E+022.88E+034.79E+02-3.93E+014.79E+024.14E-024.79E+020.3184154622-0.0084653233479.44977.40E-013.07E-02-6.26E-032.36E-011.00E+00

    5.09E-073.95E+045.09E+022.92E+025.65E-012.08E+045.09E+025.77E+035.09E+022.93E+035.09E+024.01E+015.09E+023.97E-025.09E+020.31255057720.0083320762509.41537.35E-012.92E-026.12E-032.30E-011.00E+00

    5.39E-073.97E+045.39E+022.97E+025.58E-012.13E+045.39E+026.62E+035.39E+023.24E+035.39E+024.50E+015.39E+024.48E-025.39E+020.33863930810.0091756047539.38097.18E-013.22E-026.59E-032.43E-011.00E+00

    5.69E-073.97E+045.69E+023.00E+025.56E-012.14E+045.69E+026.76E+035.69E+023.34E+035.69E+026.28E+015.69E+024.55E-025.69E+020.3469227240.0127188288569.34657.12E-013.24E-029.05E-032.47E-011.00E+00

    5.99E-073.96E+045.99E+022.99E+025.56E-012.13E+045.99E+025.13E+035.99E+023.23E+035.99E+029.70E+015.99E+023.47E-025.99E+020.33755223330.0197416158599.31217.18E-012.49E-021.42E-022.43E-011.00E+00

    6.29E-073.99E+046.29E+022.96E+025.60E-012.14E+046.29E+025.99E+036.29E+023.25E+036.29E+021.92E+016.29E+024.02E-026.29E+020.3373603590.0038777229629.27777.24E-012.91E-022.81E-032.44E-011.00E+00

    6.59E-073.95E+046.59E+022.89E+025.67E-012.08E+046.59E+025.39E+036.59E+023.01E+036.59E+025.07E+016.59E+023.72E-026.59E+020.32096627990.0105588467659.24337.31E-012.72E-027.71E-032.34E-011.00E+00

    6.89E-073.93E+046.89E+022.79E+025.78E-012.02E+046.89E+026.16E+036.89E+022.77E+036.89E+021.09E+026.89E+024.38E-026.89E+020.30484030970.0233613515689.20897.29E-013.19E-021.70E-022.22E-011.00E+00

    7.19E-073.95E+047.19E+022.66E+025.94E-011.99E+047.19E+025.45E+037.19E+022.74E+037.19E+022.55E+017.19E+023.93E-027.19E+020.30491340960.005548937719.17457.41E-012.91E-024.11E-032.26E-011.00E+00

    7.49E-073.92E+047.49E+022.48E+026.15E-011.89E+047.49E+024.01E+037.49E+022.32E+037.49E+022.60E+007.49E+023.05E-027.49E+020.2728301160.0005959875749.14017.67E-012.34E-024.57E-042.09E-011.00E+00

    7.79E-073.87E+047.79E+022.24E+026.44E-011.74E+047.79E+024.23E+037.79E+022.10E+037.79E+022.27E+027.79E+023.49E-027.79E+020.26832108930.0564058404779.10587.35E-012.57E-024.15E-021.97E-011.00E+00

    8.09E-073.79E+048.09E+021.94E+026.84E-011.53E+048.09E+023.49E+038.09E+021.48E+038.09E+02-4.87E+018.09E+023.27E-028.09E+020.2144862914-0.013759686809.07148.11E-012.65E-02-1.12E-021.74E-011.00E+00

    8.39E-073.69E+048.39E+021.51E+027.43E-011.24E+048.39E+021.95E+038.39E+028.75E+028.39E+02-9.16E+018.39E+022.25E-028.39E+020.1566090852-0.0319765064839.0378.72E-011.96E-02-2.79E-021.37E-011.00E+00

    8.69E-073.61E+048.69E+028.05E+018.54E-017.91E+038.69E+021.68E+038.69E+026.95E+028.69E+022.16E+018.69E+023.05E-028.69E+020.19510503390.0118269526869.00268.08E-012.46E-029.56E-031.58E-011.00E+00

    8.99E-073.46E+048.99E+020.00E+001.00E+001.61E+038.99E+021.02E+038.99E+023.87E+028.99E+02-1.26E+028.99E+029.07E-028.99E+020.5341496818-0.3395529513898.96827.78E-017.06E-02-2.64E-014.16E-011.00E+00

    9.29E-073.33E+049.29E+020.00E+001.00E+003.31E+029.29E+021.34E+039.29E+023.29E+019.29E+02-2.59E+019.29E+025.83E-019.29E+020.2209319557-0.33908638928.93386.83E-013.98E-01-2.31E-011.51E-011.00E+00

    9.59E-073.39E+049.59E+020.00E+001.00E+009.46E+029.59E+025.55E+029.59E+022.04E+029.59E+02-1.81E+009.59E+028.43E-029.59E+020.4798113557-0.008282999958.89946.43E-015.42E-02-5.32E-033.08E-011.00E+00

    9.89E-073.48E+049.89E+020.00E+001.00E+001.78E+039.89E+021.21E+039.89E+022.12E+029.89E+02-1.18E+029.89E+029.77E-029.89E+020.264686909-0.2872405914988.8659.30E-019.09E-02-2.67E-012.46E-011.00E+00

    1.02E-063.50E+041.02E+030.00E+001.00E+002.05E+031.02E+031.13E+031.02E+038.40E+011.02E+037.30E+011.02E+037.92E-021.02E+030.09107655150.15424773311018.8317.55E-015.98E-021.16E-016.88E-021.00E+00

    1.05E-063.52E+041.05E+030.00E+001.00E+002.18E+031.05E+038.35E+021.05E+032.31E+021.05E+03-1.15E+021.05E+035.51E-021.05E+030.2356185441-0.22993503571048.7969.43E-015.20E-02-2.17E-012.22E-011.00E+00

    1.08E-063.51E+041.08E+030.00E+001.00E+002.07E+031.08E+032.13E+031.08E+032.47E+011.08E+03-8.02E+011.08E+031.48E-011.08E+030.0264921935-0.16742528321078.7629.93E-011.47E-01-1.66E-012.63E-021.00E+00

    1.11E-063.54E+041.11E+030.00E+001.00E+002.44E+031.11E+031.23E+031.11E+031.92E+021.11E+035.25E+011.11E+037.22E-021.11E+030.17451478250.09305573851108.7277.46E-015.39E-026.95E-021.30E-011.00E+00

    1.14E-063.63E+041.14E+030.00E+001.00E+003.34E+031.14E+031.15E+031.14E+031.77E+021.14E+03-8.34E+011.14E+034.93E-021.14E+030.1177730287-0.10799095341138.6939.44E-014.65E-02-1.02E-011.11E-011.00E+00

    .

    04

    000

    000

    000

    000

    000

    000

    000

    000

    000

    000

    000

    000

    000

    000

    000

    000

    000

    000

    000

    000

    000

    000

    000

    000

    000

    000

    000

    000

    000

    000

    000

    000

    000

    000

    000

    000

    000

    000

    000

    Corrected C

    S

    N

    05

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    06

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0000

    0000

    0000

    0000

    0000

    0000

    0000

    0000

    0000

    0000

    0000

    0000

    0000

    0000

    0000

    0000

    0000

    0000

    0000

    0000

    0000

    0000

    0000

    0000

    0000

    0000

    0000

    0000

    0000

    0000

    0000

    0000

    0000

    0000

    0000

    0000

    0000

    0000

    0000

    Carbon

    Sulphur

    Oxygen

    Nitrogen

    shift585lambda510r240S20918C3006N1353O694

    BlobC/S0.143703987c/n2.22172949c/o4.3314121037

    CPositionThicknessCorrectionCorrectedCPositionPostionSPositionNPositionOPositionS/CPositionN/CO/CPositionCarbonSulphurOxygenNitrogenSum

    0.00E+003.29E+040.00E+000.00E+001.00E+002.93E+030.00E+002.25E+020.00E+00-1.90E+010.00E+00-3.72E+010.00E+001.10E-020.00E+00-0.0143857628-0.054949212501.06E+001.17E-02-5.84E-02-1.53E-021.00E+00

    3.05E-083.10E+043.05E+010.00E+001.00E+009.78E+023.05E+016.33E+023.05E+011.51E+023.05E+01-3.43E+013.05E+019.30E-023.05E+010.3425695886-0.151824536829.965617.79E-017.25E-02-1.18E-012.67E-011.00E+00

    6.09E-083.03E+046.09E+010.00E+001.00E+002.90E+026.09E+011.68E+026.09E+011.90E+026.09E+01-7.14E+016.09E+018.31E-026.09E+011.4578164006-1.067613270859.931216.79E-015.64E-02-7.25E-019.89E-011.00E+00

    9.14E-083.01E+049.14E+010.00E+001.00E+001.07E+029.14E+018.04E+029.14E+011.67E+029.14E+01-2.03E+019.14E+011.08E+009.14E+013.4592458837-0.821299790189.896822.12E-012.29E-01-1.74E-017.33E-011.00E+00

    1.22E-073.05E+041.22E+020.00E+001.00E+004.82E+021.22E+02-1.11E+011.22E+021.28E+021.22E+025.41E+011.22E+02-3.30E-031.22E+020.59061056230.485771752119.86244.82E-01-1.59E-032.34E-012.85E-011.00E+00

    1.52E-073.01E+041.52E+020.00E+001.00E+001.05E+021.52E+021.08E+031.52E+021.85E+021.52E+02-9.38E+011.52E+021.49E+001.52E+023.9347050251-3.8876726869149.8283.95E-015.87E-01-1.53E+001.55E+001.00E+00

    1.83E-072.93E+041.83E+020.00E+001.00E+00-7.06E+021.83E+022.56E+021.83E+024.95E+011.83E+02-4.26E+011.83E+02-5.21E-021.83E+02-0.15592355270.2614529781179.79369.49E-01-4.95E-022.48E-01-1.48E-011.00E+00

    2.13E-072.99E+042.13E+020.00E+001.00E+00-1.16E+022.13E+024.88E+022.13E+022.36E+022.13E+029.57E+012.13E+02-6.04E-012.13E+02-4.5104150278-3.5672512825209.7592-1.30E-017.86E-024.64E-015.87E-011.00E+00

    2.44E-073.00E+042.44E+020.00E+001.00E+00-3.65E+012.44E+022.10E+022.44E+022.00E+022.44E+02-3.00E+012.44E+02-8.27E-012.44E+02-12.16820878363.5570942722239.7248-1.19E-019.80E-02-4.22E-011.44E+001.00E+00

    2.74E-073.03E+042.74E+020.00E+001.00E+003.06E+022.74E+02-2.15E+022.74E+025.03E+012.74E+02-8.28E+012.74E+02-1.01E-012.74E+020.3648696172-1.171843895269.69051.09E+01-1.10E+00-1.27E+013.97E+001.00E+00

    3.05E-073.07E+043.05E+020.00E+001.00E+007.03E+023.05E+021.27E+023.05E+022.82E+023.05E+024.63E+013.05E+022.59E-023.05E+020.89191538770.2852340107299.65614.54E-011.18E-021.29E-014.05E-011.00E+00

    3.35E-073.15E+043.35E+020.00E+001.00E+001.55E+033.35E+02-1.66E+023.35E+021.78E+023.35E+02-1.00E+023.35E+02-1.54E-023.35E+020.2545432895-0.2803693183329.62171.04E+00-1.61E-02-2.92E-012.65E-011.00E+00

    3.66E-073.32E+043.66E+029.71E+011.00E+003.20E+033.66E+024.58E+023.66E+028.73E+013.66E+022.47E+013.66E+022.06E-023.66E+020.060603090.0334325224359.58738.97E-011.85E-023.00E-025.44E-021.00E+00

    3.96E-073.50E+043.96E+021.48E+027.48E-011.26E+043.96E+027.06E+023.96E+025.27E+023.96E+02-2.34E+003.96E+028.07E-033.96E+020.0931336775-0.0008069669389.55299.09E-017.33E-03-7.33E-048.46E-021.00E+00

    4.26E-073.61E+044.26E+021.80E+027.02E-011.50E+044.26E+028.16E+024.26E+026.28E+024.26E+021.06E+014.26E+027.81E-034.26E+020.09298941760.0030477554419.51859.06E-017.08E-032.76E-038.42E-021.00E+00

    4.57E-073.66E+044.57E+022.03E+026.72E-011.64E+044.57E+024.21E+034.57E+028.90E+024.57E+021.92E+024.57E+023.68E-024.57E+020.12035529750.0506634597449.48418.28E-013.05E-024.19E-029.96E-021.00E+00

    4.87E-073.63E+044.87E+022.19E+026.51E-011.68E+044.87E+023.86E+034.87E+021.20E+034.87E+021.49E+024.87E+023.30E-024.87E+020.15882428420.0385048608479.44978.13E-012.68E-023.13E-021.29E-011.00E+00

    5.18E-073.62E+045.18E+022.30E+026.37E-011.72E+045.18E+024.87E+035.18E+021.42E+035.18E+021.85E+025.18E+024.08E-025.18E+020.18444444140.0466254864509.41537.86E-013.21E-023.67E-021.45E-011.00E+00

    5.48E-073.59E+045.48E+022.37E+026.28E-011.70E+045.48E+025.04E+035.48E+021.69E+035.48E+023.30E+025.48E+024.25E-025.48E+020.2211878370.0840753486539.38097.42E-013.15E-026.24E-021.64E-011.00E+00

    5.79E-073.56E+045.79E+022.40E+026.25E-011.69E+045.79E+025.03E+035.79E+021.93E+035.79E+021.56E+025.79E+024.29E-025.79E+020.25388641520.0400993671569.34657.48E-013.21E-023.00E-021.90E-011.00E+00

    6.09E-073.63E+046.09E+022.39E+026.26E-011.76E+046.09E+025.91E+036.09E+021.87E+036.09E+021.66E+026.09E+024.84E-026.09E+020.23704113430.0409280755599.31217.54E-013.65E-023.09E-021.79E-011.00E+00

    6.40E-073.59E+046.40E+022.34E+026.32E-011.70E+046.40E+025.06E+036.40E+022.06E+036.40E+023.26E+026.40E+024.29E-026.40E+020.26954142570.0832762798629.27777.16E-013.07E-025.97E-021.93E-011.00E+00

    6.70E-073.52E+046.70E+022.24E+026.44E-011.59E+046.70E+024.50E+036.70E+021.78E+036.70E+021.92E+026.70E+024.06E-026.70E+020.24885915230.0521953415659.24337.45E-013.03E-023.89E-021.85E-011.00E+00

    7.01E-073.48E+047.01E+022.10E+026.62E-011.49E+047.01E+025.09E+037.01E+021.65E+037.01E+021.09E+027.01E+024.91E-027.01E+020.24661733930.0316629923689.20897.53E-013.70E-022.39E-021.86E-011.00E+00

    7.31E-073.44E+047.31E+021.90E+026.88E-011.37E+047.31E+024.50E+037.31E+021.56E+037.31E+029.67E+017.31E+024.72E-027.31E+020.25235854480.0305317447719.17457.52E-013.55E-022.30E-021.90E-011.00E+00

    7.61E-073.34E+047.61E+021.63E+027.27E-011.16E+047.61E+024.22E+037.61E+021.08E+037.61E+025.96E+017.61E+025.25E-027.61E+020.20669435550.0223379593749.14017.80E-014.09E-021.74E-021.61E-011.00E+00

    7.92E-073.30E+047.92E+021.22E+027.88E-019.40E+037.92E+022.80E+037.92E+021.09E+037.92E+022.15E+027.92E+024.28E-027.92E+020.25861177240.0992440071779.10587.14E-013.05E-027.09E-021.85E-011.00E+00

    8.22E-073.25E+048.22E+023.53E+019.33E-014.48E+038.22E+022.39E+038.22E+028.22E+028.22E+02-5.18E+018.22E+027.68E-028.22E+020.4076377951-0.0501171153809.07146.97E-015.35E-02-3.49E-022.84E-011.00E+00

    8.53E-073.13E+048.53E+020.00E+001.00E+001.28E+038.53E+021.97E+038.53E+023.13E+028.53E+02-8.75E+018.53E+022.20E-018.53E+020.5422079654-0.2953024173839.0376.82E-011.50E-01-2.01E-013.70E-011.00E+00

    8.83E-073.03E+048.83E+020.00E+001.00E+003.26E+028.83E+029.74E+028.83E+022.76E+028.83E+023.22E+018.83E+024.29E-018.83E+021.87964453060.4269525501869.00262.68E-011.15E-011.14E-015.03E-011.00E+00

    9.14E-072.97E+049.14E+020.00E+001.00E+00-3.12E+029.14E+029.75E+019.14E+021.77E+029.14E+02-7.05E+019.14E+02-4.49E-029.14E+02-1.25806874820.9792356219898.96821.48E+00-6.65E-021.45E+00-1.86E+001.00E+00

    9.44E-072.91E+049.44E+020.00E+001.00E+00-9.04E+029.44E+024.82E+029.44E+021.29E+029.44E+02-4.94E+019.44E+02-7.66E-029.44E+02-0.3167517480.2366670231928.93381.19E+00-9.08E-022.81E-01-3.76E-011.00E+00

    9.75E-072.97E+049.75E+020.00E+001.00E+00-2.95E+029.75E+022.24E+029.75E+022.98E+029.75E+021.06E+029.75E+02-1.09E-019.75E+02-2.2414418053-1.556419575958.8994-3.44E-013.76E-025.35E-017.71E-011.00E+00

    1.01E-062.99E+041.01E+030.00E+001.00E+00-1.41E+021.01E+03-1.97E+021.01E+031.93E+021.01E+034.38E+011.01E+032.01E-011.01E+03-3.0563180001-1.3500240526988.865-3.12E-01-6.28E-024.21E-019.54E-011.00E+00

    1.04E-063.01E+041.04E+030.00E+001.00E+007.07E+011.04E+032.61E+021.04E+035.96E+011.04E+031.08E+011.04E+035.31E-011.04E+031.87233896580.66064446631018.8312.46E-011.31E-011.63E-014.61E-011.00E+00

    1.07E-063.06E+041.07E+030.00E+001.00E+005.72E+021.07E+03-5.82E+021.07E+037.79E+011.07E+03-5.63E+011.07E+03-1.46E-011.07E+030.3026192009-0.42656167861048.7961.37E+00-2.00E-01-5.85E-014.15E-011.00E+00

    1.10E-063.01E+041.10E+030.00E+001.00E+005.12E+011.10E+032.92E+011.10E+031.26E+021.10E+03-4.25E+011.10E+038.20E-021.10E+035.4657888686-3.59756152881078.7623.39E-012.78E-02-1.22E+001.85E+001.00E+00

    1.13E-062.99E+041.13E+030.00E+001.00E+00-1.01E+021.13E+037.89E+011.13E+036.42E+011.13E+037.04E+011.13E+03-1.13E-011.13E+03-1.4156487818-3.02519185111108.727-2.81E-013.17E-028.51E-013.98E-011.00E+00

    1.16E-062.97E+041.16E+030.00E+001.00E+00-2.63E+021.16E+031.62E+021.16E+032.25E+021.16E+03-2.46E+011.16E+03-8.88E-021.16E+03-1.89975369990.40569223351138.693-1.72E+001.52E-01-6.96E-013.26E+001.00E+00

    .

    CorrectedC

    S

    N

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    1.06193563860.0116936427-0.0583525271-0.0152767542

    0.77895790.072459735-0.11826492230.2668472874

    0.67873011950.0564272636-0.72462128280.9894638997

    0.21202764580.2286548544-0.1741382610.7334557608

    0.4823732233-0.00159122970.23432328580.2848947207

    0.39454927790.586894147-1.53387845131.5524350264

    0.9492771129-0.04945378120.2481913282-0.1480146599

    -0.13018427050.07859917440.4644000060.5871850902

    -0.11851567280.0979636431-0.42157142081.4421234505

    10.8698804035-1.0981665144-12.73780299043.9660891013

    0.45391081220.01176834830.12947080150.404850038

    1.0429891185-0.0160528514-0.29242214820.2654858811

    0.89718086390.01845218420.02999501930.0543719327

    0.90876405060.0073327538-0.00073334250.0846365381

    0.9059226750.00707507230.00276103080.0842412219

    0.82791527330.03049568550.04194505210.0996439891

    0.81280078310.02680993330.0312967810.1290925026

    0.7862228320.03210471490.0366580220.1450144311

    0.74195969110.031547330.06238051970.1641124592

    0.74799255120.03210827350.02999402790.1899051474

    0.75394127070.03648626990.03085736530.178715094

    0.71648847390.03072170670.05966649460.1931233247

    0.74535465310.03025297920.03890404070.1854883271

    0.75334951080.03700813740.02385329980.185789052

    0.75183301180.03548072990.02295477360.1897314848

    0.78033601250.04094182420.01743111410.1612910492

    0.71396513880.030538310.07085676130.1846397899

    0.69721111210.0535214972-0.03494220970.2842096004

    0.68161361320.1500922041-0.20128214760.3695763303

    0.26770950220.11479254150.11429925470.5031987016

    1.4787937933-0.06645709671.4480875598-1.8604242564

    1.1857620376-0.09080061110.2806307716-0.3755921981

    -0.34398399390.0375804680.53538342160.7710201043

    -0.3120001645-0.06277928070.42120772650.9535717187

    0.24604753150.13071814770.16254994010.4606843807

    1.3702839538-0.2004475655-0.58451062350.4146742352

    0.33895209730.0278083277-1.21940102531.8526406004

    -0.28142143640.03167368670.85135383610.3983939136

    -1.71567931440.152348962-0.69603777293.2593681253

    Carbon

    Sulphur

    Oxygen

    Nitrogen

    shift610lambda510r220S20918C3006N1353O694

    BlobC/S0.143703987c/n2.22172949c/o4.3314121037

    CPositionThicknessCorrectionCorrectedCPositionSPositionNPositionOPositionS/CPositionN/CO/CPositionCarbonSulphurOxygenNitrogenSumPositionCarbonSulphurNitrogenOxygen

    0.00E+003.36E+040.00E+000.00E+001.00E+003.61E+030.00E+00-1.77E+010.00E+001.03E+020.00E+00-1.01E+020.00E+00-7.05E-040.00E+000.0636378151-0.120875712301.06E+00-7.49E-04-1.28E-016.76E-021.00E+0003.61E+030.00E+000.00E+000.00E+00

    3.05E-083.21E+043.05E+010.00E+001.00E+002.07E+033.05E+016.44E+023.05E+011.64E+023.05E+01-5.22E+013.05E+014.47E-023.05E+010.1755236928-0.109221949729.965619.00E-014.02E-02-9.83E-021.58E-011.00E+0029.965612.07E+030.00E+000.00E+000.00E+00

    6.10E-083.13E+046.10E+010.00E+001.00E+001.34E+036.10E+016.33E+026.10E+012.62E+026.10E+015.21E+016.10E+016.77E-026.10E+010.43311443590.168098060359.931215.99E-014.06E-021.01E-012.60E-011.00E+0059.931211.34E+030.00E+000.00E+000.00E+00

    9.15E-083.12E+049.15E+010.00E+001.00E+001.23E+039.15E+013.46E+029.15E+011.62E+029.15E+012.21E+019.15E+014.05E-029.15E+010.29290884210.077921491789.896827.09E-012.87E-025.52E-022.08E-011.00E+0089.896821.23E+030.00E+000.00E+000.00E+00

    1.22E-073.13E+041.22E+020.00E+001.00E+001.30E+031.22E+024.62E+021.22E+027.05E+011.22E+02-8.78E+011.22E+025.11E-021.22E+020.1207056937-0.2927548452119.86241.14E+005.82E-02-3.33E-011.37E-011.00E+00119.86241.30E+030.00E+000.00E+000.00E+00

    1.53E-073.12E+041.53E+020.00E+001.00E+001.16E+031.53E+02-3.04E+021.53E+021.55E+021.53E+021.60E+011.53E+02-3.76E-021.53E+020.29603813430.0597494897149.8287.59E-01-2.85E-024.53E-022.25E-011.00E+00149.8281.16E+030.00E+000.00E+000.00E+00

    1.83E-073.13E+041.83E+020.00E+001.00E+001.31E+031.83E+023.62E+021.83E+021.60E+021.83E+02-1.31E+021.83E+023.98E-021.83E+020.2720185625-0.4362640847179.79361.14E+004.55E-02-4.98E-013.11E-011.00E+00179.79361.31E+030.00E+000.00E+000.00E+00

    2.14E-073.21E+042.14E+020.00E+001.00E+002.09E+032.14E+025.95E+022.14E+021.44E+022.14E+022.06E+012.14E+024.10E-022.14E+020.15352621410.0427700174209.75928.08E-013.31E-023.46E-021.24E-011.00E+00209.75922.09E+030.00E+000.00E+000.00E+00

    2.44E-073.24E+042.44E+020.00E+001.00E+002.38E+032.44E+021.08E+032.44E+023.09E+022.44E+02-9.74E+012.44E+026.54E-022.44E+020.2883794745-0.1771333569239.72488.50E-015.56E-02-1.51E-012.45E-011.00E+00239.72482.38E+030.00E+000.00E+000.00E+00

    2.75E-073.24E+042.75E+020.00E+001.00E+002.40E+032.75E+025.01E+022.75E+021.64E+022.75E+02-1.54E+022.75E+023.00E-022.75E+020.1511929262-0.2784085329269.69051.11E+003.32E-02-3.08E-011.67E-011.00E+00269.69052.40E+030.00E+000.00E+000.00E+00

    3.05E-073.31E+043.05E+020.00E+001.00E+003.11E+033.05E+026.02E+023.05E+022.07E+023.05E+021.49E+023.05E+022.78E-023.05E+020.14788888750.2072780955299.65617.23E-012.01E-021.50E-011.07E-011.00E+00299.65613.11E+030.00E+000.00E+000.00E+00

    3.36E-073.40E+043.36E+020.00E+001.00E+004.04E+033.36E+025.79E+023.36E+021.38E+023.36E+02-1.09E+023.36E+022.06E-023.36E+020.0758353966-0.1169198708329.62171.02E+002.10E-02-1.19E-017.74E-021.00E+00329.62174.04E+030.00E+000.00E+000.00E+00

    3.66E-073.52E+043.66E+020.00E+001.00E+005.22E+033.66E+027.15E+023.66E+023.55E+023.66E+02-1.04E+023.66E+021.97E-023.66E+020.151332444-0.0867734242359.58739.22E-011.82E-02-8.00E-021.40E-011.00E+00359.58735.22E+030.00E+000.00E+000.00E+00

    3.97E-073.58E+043.97E+025.31E+019.01E-018.78E+033.97E+022.28E+033.97E+026.69E+023.97E+029.66E+013.97E+023.73E-023.97E+020.16921113740.0476626879389.55297.97E-012.97E-023.80E-021.35E-011.00E+00389.55298.78E+030.00E+000.00E+000.00E+00

    4.27E-073.61E+044.27E+021.22E+027.87E-011.25E+044.27E+022.31E+034.27E+028.30E+024.27E+021.93E+014.27E+022.67E-024.27E+020.14806077660.0067247732419.51858.46E-012.26E-025.69E-031.25E-011.00E+00419.51851.25E+040.00E+000.00E+000.00E+00

    4.58E-073.72E+044.58E+021.59E+027.33E-011.52E+044.58E+022.37E+034.58E+029.53E+024.58E+021.48E+024.58E+022.24E-024.58E+020.1389287410.0420458287449.48418.31E-011.86E-023.49E-021.15E-011.00E+00449.48411.52E+040.00E+000.00E+000.00E+00

    4.88E-073.80E+044.88E+021.83E+026.98E-011.70E+044.88E+023.69E+034.88E+021.20E+034.88E+021.90E+024.88E+023.11E-024.88E+020.15659686450.0481914489479.44978.09E-012.52E-023.90E-021.27E-011.00E+00479.44971.70E+040.00E+000.00E+000.00E+00

    5.19E-073.79E+045.19E+022.00E+026.76E-011.77E+045.19E+023.55E+035.19E+021.39E+035.19E+021.73E+025.19E+022.89E-025.19E+020.17518242190.042536102509.41538.02E-012.32E-023.41E-021.41E-011.00E+00509.41531.77E+040.00E+000.00E+000.00E+00

    5.49E-073.77E+045.49E+022.11E+026.61E-011.78E+045.49E+023.93E+035.49E+021.58E+035.49E+022.76E+025.49E+023.17E-025.49E+020.1963104650.0668896375539.38097.72E-012.45E-025.17E-021.52E-011.00E+00539.38091.78E+040.00E+000.00E+000.00E+00

    5.80E-073.75E+045.80E+022.18E+026.52E-011.79E+045.80E+023.30E+035.80E+021.52E+035.80E+021.24E+025.80E+022.64E-025.80E+020.18815083850.0299800984569.34658.04E-012.12E-022.41E-021.51E-011.00E+00569.34651.79E+040.00E+000.00E+000.00E+00

    6.10E-073.69E+046.10E+022.20E+026.50E-011.74E+046.10E+023.49E+036.10E+021.65E+036.10E+021.59E+026.10E+022.88E-026.10E+020.21018517790.0396567868599.31217.82E-012.25E-023.10E-021.64E-011.00E+00599.31211.74E+040.00E+000.00E+000.00E+00

    6.41E-073.65E+046.41E+022.18E+026.52E-011.69E+046.41E+024.99E+036.41E+021.63E+036.41E+022.99E+026.41E+024.25E-026.41E+020.21450305960.0766483167629.27777.50E-013.19E-025.75E-021.61E-011.00E+00629.27771.69E+040.00E+000.00E+000.00E+00

    6.71E-073.65E+046.71E+022.11E+026.61E-011.67E+046.71E+024.79E+036.71E+021.49E+036.71E+021.89E+026.71E+024.12E-026.71E+020.19846006670.0489764728659.24337.76E-013.20E-023.80E-021.54E-011.00E+00659.24331.67E+040.00E+000.00E+000.00E+00

    7.02E-073.61E+047.02E+022.00E+026.76E-011.59E+047.02E+025.53E+037.02E+021.30E+037.02E+021.62E+027.02E+025.01E-027.02E+020.18273041590.0441438147689.20897.83E-013.92E-023.46E-021.43E-011.00E+00689.20891.59E+040.00E+000.00E+000.00E+00

    7.32E-073.56E+047.32E+021.83E+026.98E-011.46E+047.32E+024.46E+037.32E+021.30E+037.32E+022.61E+027.32E+024.38E-027.32E+020.1976514170.0774268933719.17457.58E-013.32E-025.87E-021.50E-011.00E+00719.17451.46E+040.00E+000.00E+000.00E+00

    7.63E-073.48E+047.63E+021.59E+027.33E-011.28E+047.63E+023.85E+037.63E+028.56E+027.63E+029.64E+017.63E+024.30E-027.63E+020.14800668820.0324851714749.14018.17E-013.52E-022.66E-021.21E-011.00E+00749.14011.28E+040.00E+000.00E+000.00E+00

    7.93E-073.36E+047.93E+021.22E+027.87E-019.94E+037.93E+022.19E+037.93E+027.23E+027.93E+025.69E+017.93E+023.17E-027.93E+020.1615262370.024796144779.10588.21E-012.60E-022.04E-021.33E-011.00E+00779.10589.94E+030.00E+000.00E+000.00E+00

    8.24E-073.30E+048.24E+025.31E+019.01E-015.99E+038.24E+029.34E+028.24E+027.21E+028.24E+02-3.58E+018.24E+022.24E-028.24E+020.2674253517-0.0259010804809.07147.91E-011.77E-02-2.05E-022.12E-011.00E+00809.07145.99E+030.00E+000.00E+000.00E+00

    8.54E-073.20E+048.54E+020.00E+001.00E+002.01E+038.54E+023.51E+028.54E+023.94E+028.54E+02-6.13E+018.54E+022.51E-028.54E+020.4358320288-0.1321118928839.0377.53E-011.89E-02-9.94E-023.28E-011.00E+00839.0372.01E+030.00E+000.00E+000.00E+00

    8.85E-073.12E+048.85E+020.00E+001.00E+001.23E+038.85E+021.08E+038.85E+022.95E+028.85E+028.38E+018.85E+021.26E-018.85E+020.53159647640.2940226328869.00265.12E-016.45E-021.51E-012.72E-011.00E+00869.00261.23E+030.00E+000.00E+000.00E+00

    9.15E-073.12E+049.15E+020.00E+001.00E+001.18E+039.15E+021.03E+029.15E+021.89E+029.15E+02-9.64E+019.15E+021.26E-029.15E+020.3547132433-0.3533676288898.96829.86E-011.24E-02-3.49E-013.50E-011.00E+00898.96821.18E+030.00E+000.00E+000.00E+00

    9.46E-073.13E+049.46E+020.00E+001.00E+001.28E+039.46E+02-7.98E+019.46E+021.61E+029.46E+02-1.90E+029.46E+02-8.94E-039.46E+020.2783275999-0.6429352493928.93381.60E+00-1.43E-02-1.03E+004.44E-011.00E+00928.93381.28E+030.00E+000.00E+000.00E+00

    9.76E-073.12E+049.76E+020.00E+001.00E+001.20E+039.76E+02-5.98E+009.76E+022.42E+029.76E+028.76E+019.76E+02-7.14E-049.76E+020.44697415280.3150507489958.89945.68E-01-4.05E-041.79E-012.54E-011.00E+00958.89941.20E+030.00E+000.00E+000.00E+00

    1.01E-063.10E+041.01E+030.00E+001.00E+001.00E+031.01E+034.92E+021.01E+032.52E+021.01E+03-2.20E+011.01E+037.05E-021.01E+030.5592627418-0.0952354195988.8656.52E-014.60E-02-6.21E-023.64E-011.00E+00988.8651.00E+030.00E+000.00E+000.00E+00

    1.04E-063.11E+041.04E+030.00E+001.00E+001.09E+031.04E+03-2.36E+021.04E+034.89E+011.04E+03-3.77E+011.04E+03-3.12E-021.04E+030.0996446737-0.15000373441018.8311.09E+00-3.39E-02-1.63E-011.08E-011.00E+001018.8311.09E+030.00E+000.00E+000.00E+00

    1.07E-063.12E+041.07E+030.00E+001.00E+001.20E+031.07E+034.08E+021.07E+033.26E+021.07E+03-8.00E+011.07E+034.91E-021.07E+030.6053941555-0.28999579311048.7967.33E-013.60E-02-2.13E-014.44E-011.00E+001048.7961.20E+030.00E+000.00E+000.00E+00

    1.10E-063.10E+041.10E+030.00E+001.00E+009.84E+021.10E+03-1.58E+021.10E+032.44E+021.10E+03-1.31E+011.10E+03-2.30E-021.10E+030.5509372569-0.05769656951078.7626.80E-01-1.57E-02-3.92E-023.75E-011.00E+001078.7629.84E+020.00E+000.00E+000.00E+00

    1.13E-063.12E+041.13E+030.00E+001.00E+001.21E+031.13E+031.67E+021.13E+032.22E+021.13E+03-7.87E+011.13E+031.98E-021.13E+030.4071598228-0.28182267621108.7278.73E-011.73E-02-2.46E-013.56E-011.00E+001108.7271.21E+030.00E+000.00E+000.00E+00

    1.16E-063.14E+041.16E+030.00E+001.00E+001.39E+031.16E+031.22E+031.16E+032.28E+021.16E+038.70E+001.16E+031.26E-011.16E+030.36493628470.02716174621138.6936.59E-018.29E-021.79E-022.40E-011.00E+001138.6931.39E+030.00E+000.00E+000.00E+00

    .

    0000

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    CorrectedC

    S

    N

    O

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

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    0

    0

    0

    0000

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    0000

    0000

    0000

    0000

    0000

    0000

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    0000

    0000

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    0000

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    0000

    0000

    0000

    Carbon

    Sulphur

    Oxygen

    Nitrogen

    0000

    0000

    0000

    0000

    0000

    0000

    0000

    0000

    0000

    0000

    0000

    0000

    0000

    0000

    0000

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    0000

    0000

    0000

    0000

    0000

    0000

    0000

    0000

    0000

    0000

    0000

    0000

    0000

    0000

    0000

    0000

    0000

    0000

    Carbon

    Sulphur

    Nitrogen

    Oxygen

  • Sampling strategy:

    Short level legs below, above, and in cloud:5-10 minutes out of cloudshorter in cloud (because of concentrating effectof CVI)