Energy Efficiency Legislation Overview - RO

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Report Summary

Hy9 Corporation ID:

KB092ASmart Chemistry #: 10HY9001-01

Sampled on 02/22/2010

ConstituentSAE Limits (μmol/mol)

Smart Chemistry Detection Limits

(μmol/mol) Method Concentration (μmol/mol)

Water 5 1 ASTM WK4548 <1

Total Hydrocarbons (C1 Basis) 2

Methane 0.001 ASTM D5466 0.0012Ethane, Ethene, Ethyne 0.6 ASTM D1946 < 0.6

Other Hydrocarbons (Smart Chemistry Detection Limit is for individual compound of hydrocarbon listed in "Other

Hydrocarbons" under Analytical Data.) 0.001 ASTM D5466 < 0.001

Oxygen 5 3 ASTM WK4548 < 3

Helium 300 10 ASTM D1946 <10

Nitrogen, Argon 100 Nitrogen 5 ASTM WK4548 < 5

Argon 1 ASTM WK4548 <1

Carbon Dioxide 1 0.5 ASTM WK4548 < 0.5

Carbon Monoxide 0.1 0.001 ASTM D5466 <0.001

Total Sulfur 0.001 0.0001 ASTM WK 24073 < 0.0001

Hydrogen Sulfide 0.00002 ASTM WK 24073 0.000067Carbonyl Sulfide 0.00002 ASTM WK 24073 < 0.00002

Methyl Mercaptan 0.00002 ASTM WK 24073 < 0.00002Carbon Disulfide 0.00002 ASTM WK 24073 < 0.00002

Formaldehyde 0.01 0.001 ASTM D5466 < 0.001

Formic Acid 0.2 0.001 ASTM D5466 < 0.001

Ammonia 0.1 0.02 ASTM D5466 < 0.02

Total halogenates 0.05

Chlorine 0.001 ASTM D5466 < 0.001

Hydrogen Chloride 0.001 ASTM D5466 < 0.001Hydrogen Bromide 0.001 ASTM D5466 < 0.001

Organic Halides (32 compounds in bold listed in "Other Hydrocarbons") (Smart

Chemistry Detection Limit is for individual organic halide compound) 0.001 ASTM D5466

Organic Halides Found

Butane, 1,1,3,4-tetrachloro-1,2,2,3,4,4-hexafluoro- 0.02Particulate Concentration 1 µg/Liter 0.002 µg/Liter ASTM Wk 21611 Not Required

Particulates Found & Size < 10µm ASTM WK 21597 Not Required

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Analytical Data for Non-Hydrogen Gaseous Constituents

Smart Chemistry, 3401 La Grande Blvd, Sacramento, CA 95823, (916)391-3300, [email protected]

The analytical data for each non-hydrogen gaseous constituent in SAE TIR J2719 is tabulated in the sequence below. The analytical data includes calibration standards, detection limit study, sample analysis, spike, or duplicate.

Non-Hydrogen Gaseous Constituents 1. Water 2. Total Hydrocarbons

2.1 Methane 2.2 Ethane, Ethene & Ethyne 2.3 Other Hydrocarbons

3. Oxygen 4. Helium 5. Nitrogen 6. Argon 7. Carbon Dioxide 8. Carbon Monoxide 9. Sulfur

9.1 H2S, COS, CH3SH & CS2 9.2 Total Sulfur

10. Formaldehyde 11. Formic Acid 12. Ammonia 13. Total Organic Halogenates

13.1 Chlorine 13.2 Hydrogen Chloride 13.3 Hydrogen Bromide 13.4 Organic Halides (32 compounds in red and bold listed in "Other Hydrocarbons")

Particulate Particulate Concentration Calculation Table II Sizes and Images of Particulates Found on Filter

of 21 03/18/2010


Analytical Data

File Name, Sample, Sample Loop Pressure (psi)

003081B.D - PRAXAIR UHP H2 3 10UL G0620;ES1:50;CF=1.5ML/MN

362.3

10030801.D - G754,3.5PPM CO2,3.3PPM AR,3.3PPM N2,3.4PPM O2 3 10UL G0620;ES1:50;CF=1.5ML/MN

349.6

10030802.D - G754,3.5PPM CO2,3.3PPM AR,3.3PPM N2,3.4PPM O2 3 10UL P0136;ES 1:50;CF=1.5ML/MIN

330.1

10030803.D - G754,3.5PPM CO2,3.3PPM AR,3.3PPM N2,3.4PPM O2 3 10UL AM AIR;ES 1:50;CF=1.5ML/MIN

312.7

10030804.D - PRAXAIR UHP H2,WHOLE SYSTEM 3 10UL G0620;ES1:50;CF=1.5ML/MN

367.1

10030805.D - 10HY90016-01#1,KB092A,S100222,R100303 3 10UL G0620;ES1:50;CF=1.5ML/MN

131.1


266.8

H2O

H2O Sample RTH2O Sample

Area

Co-Injected Peak RT or

BAD RFCo-Injected Peak AREA

Co-Injected Vol (uL) RF

H2O CONC. (ppmv)

0.00 0 2.79 201948 10 03.13 311839 103.55 200233 10

0.00 0 2.74 86815 10 03.14 72566 10

3.55 82981 10

0.00 0 2.75 437562 10 03.15 216229 10

3.54 230052 10

0.00 0 2.71 1710813 10 8.3E-10 0.03.09 1687953 10 8.4E-10

3.50 1825923 10 7.7E-10

0.00 0 2.74 106696 10 03.15 67518 103.55 68146 10

0.00 0 2.75 111933 10 03.15 83294 103.52 83048 10

0.00 0 3.15 1527989 10 9.3E-10 0.000

3.38 1654029 10 8.5E-10

3.59 1819457 10 7.8E-10

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of 21 03/18/2010


Analytical Data

Injection File Name

Standard Conc.

(PPMV)

G0552,0.235 PPMV CO & 0.235 CH4 (16ML LOOP INJECTION) (OT=80C) PRE-COL IS @LIQ. N2 AND LOOP OPEN 5 MIN BEFORE AND 10 MIN AFTER VALVE TURNS. WITH PUMP. 10PSI CHECK VALVE. 001F0101.D 0.235

G0726,0.045 PPMV CO & 0.046 CH4 (16ML LOOP INJECTION) (OT=80C) PRE-COL IS @LIQ. N2 AND LOOP OPEN 5 MIN BEFORE AND 10 MIN AFTER VALVE TURNS. WITH PUMP. 10PSI CHECK VALVE. 001F0201.D 0.045

G0694, 0.00104 PPMV EACH CO & CH4 (16ML LOOP INJECTION) (OT=80C) PRE-COL IS @LIQ. N2 AND LOOP OPEN 5 MIN BEFORE AND 10 MIN AFTER VALVE TURNS. WITH PUMP.10PSI CHECK VALVE. 001F0301.D 0.00104

METHOD BLANK, JUST CARRIER GAS (16ML LOOP INJECTION) (OT=80C) PRE-COL IS @LIQ. N2 AND LOOP OPEN 5 MIN BEFORE AND 10MIN AFTER VALVE TURNS. WITH PUMP. 10PSI CHECK VALVE. 001F0401.D

10HY9001-01,KB092A,S100222,R100303 (16ML LOOP INJECTION) (OT=80C) PRE-COL IS @ LIQ. N2 AND LOOP OPEN 5 MIN BEFORE AND 10MIN AFTER VALVE TURNS. WITH PUMP. 10PSI CHECK VALVE. 001F0501.D

G0694, 0.00104 PPMV EACH CO & CH4 (16ML LOOP INJECTION) (OT=80C) PRE-COL IS @LIQ. N2 AND LOOP OPEN 5 MIN BEFORE AND 10 MIN AFTER VALVE TURNS. WITH PUMP.10PSI CHECK VALVE. 001F0601.D 0.00104

CH4 Date 3/11/2010

Ret. Time (MIN) of CH4 Area of CH4

CH4 Response Factor

Sample CH4

Conc. (ppmv)

4.851 66950 3.5E-06

4.895 13078 3.4E-06

4.91 459 2.3E-06

4.91 0 0.0E+00

4.899 521 1.2E-03

4.903 771 1.3E-06

Smart Chemistry, 3401 La Grande Blvd, Sacramento, CA 95823, (916)391-3300, [email protected] 4 of 21 03/18/2010


Analytical Data

C2 (Ethane, Ethene & Ethyne

InjectionInjection

Volume (uL)

1000UL G0345 (0.2PPMV CH4, HCCH,CH2CH2 & CH3CH3 IN H2) 1000

1000UL 10HY9001-01, KB092A, S100222, R100303. 1000

1000UL G0345 (0.2PPMV CH4, HCCH,CH2CH2 & CH3CH3 IN H2) 1000

Date of Analysis 3/15/2010

Ethene & Ethyne

Retention Time (min)

Ethene & Ethyne Standard Conc.

(PPMV)Ethene & Ethyne

Area

Response Factor (RF)

or Ethene & Ethyne Sample Conc

(PPMV)

Ethane Retention Time (min)

Ethane Standard

Conc. (PPMV) Ethane Area


or Ethane Sample Conc

(PPMV) File Name

0.579 0.4 53 7.52E-06 0.631 0.2 48 4.14E-06 001F0101.D

0.578 0.4 0 0.00E+00 0.636 0.2 4 1.66E-05 001F0201.D

0.578 0.4 38 1.06E-05 0.632 0.2 39 5.14E-06 001F0301.D

Smart Chemistry, 3401 La Grande Blvd, Sacramento, CA 95823, [email protected], (916)391-3300 of 21 03/18/2010


Analytical Laboratory Report for "Other Hydrocarbons"

EPA Method TO-15Client: HY9 Field ID #: 10HY9001-01

Hydrogen Station at: HY9 Lab Sample ID: 10HY90010

Sample Type: Hydrogen Fuel Concentration Units: PPBV

Date Sampled: 02222010,12:00 Date File 10HY9001TPH.pdf

Date Received: 0303/2010 Data Filename: 10031203.D

Date Analyzed: 3/12/2010 Dilution Factor: 1.0

Time Analyzed: 5:48 pm

Analytes MW CASNUM MQL (PPBV) Results (PPBV) Qualifier MQL (ug/L) Results (ug/L)

1,1,1-Trichloroethane 132 71-55-6 1 0 U 0.005 0

1,1,2,2-Tetrachloroethane 166 79-34-5 1 0 U 0.007 0

1,1,2-Trichloroethane 132 79-00-5 1 0 U 0.005 0

1,2-Dibromoethane 186 106-93-4 1 0 U 0.008 0

1,1-Dichloroethane 98 75-34-3 1 0 U 0.004 0

1,1-Dichloroethene 96 75-35-4 1 0 U 0.004 0

1,2,4-Trichlorobenzene 180 120-82-1 1 0 U 0.007 0

1,2,4-Trimethylbenzene 120 95-63-6 1 0 U 0.005 0

1,2-Dichloroethane 98 107-06-2 1 0 U 0.004 0

1,2-Dichloropropane 112 78-87-5 1 0 U 0.005 01,3,5-Trimethylbenzene 120 108-67-8 1 0 U 0.005 01,3-Butadiene 54 106-99-0 1 0 U 0.002 0

1,2-Dichlorobenzene 146 95-50-1 1 0 U 0.006 0

1,3-Dichlorobenzene 146 541-73-1 1 0 U 0.006 0

1,4-Dichlorobenzene 146 106-46-7 1 0 U 0.006 01,4-Dioxane 88 123-91-1 1 0 U 0.004 02-Butanone 72 78-93-3 1 0 U 0.003 02-Hexanone 100 591-78-6 1 0 U 0.004 04-Ethyltoluene 120 622-96-8 1 0 U 0.005 0

4-Methyl-2-Pentanone 100 108-10-1 1 0 U 0.004 0Acetone 58 67-64-1 1 0 U 0.002 0Benzene 78 71-43-2 1 0 U 0.003 0

Benzyl Chloride 126 100-44-7 1 0 U 0.005 0

Bromodichloromethane 162 75-27-4 1 0 U 0.007 0

Bromoform 250 75-25-2 1 0 U 0.01 0

Bromomethane 94 74-83-9 1 0 U 0.004 0Carbon Disulfide 76 75-15-0 1 0 U 0.003 0

Carbon tetrachloride 152 56-23-5 1 0 U 0.006 0

Chlorobenzene 112 108-90-7 1 0 U 0.005 0

Chloroethane 64 75-00-3 1 0 U 0.003 0

Chloroform 118 67-66-3 1 0 U 0.005 0

Chloromethane 50 74-87-3 1 0 U 0.002 0

cis-1,2-dichloroethene 96 156-59-2 1 0 U 0.004 0

cis-1,3-Dichloropropene 110 10061-01-5 1 0 U 0.005 0Cyclohexane 84 110-82-7 1 0 U 0.003 0

Dibromochloromethane 206 124-48-1 1 0 U 0.008 0

Dichlorodifluoromethane 120 75-71-8 1 0 U 0.005 0Ethanol 46 64-17-5 1 0 U 0.002 0Ethyl Acetate 88 141-78-6 1 0 U 0.004 0Ethylbenzene 106 100-41-4 1 0 U 0.004 0

Freon113 186 76-13-1 1 0 U 0.008 0

Freon114 170 76-14-2 1 0 U 0.007 0Heptane 100 142-82-5 1 0 U 0.004 0Hexane 86 110-54-3 1 0 U 0.004 0

Hexachlorobutadiene 258 87-68-3 1 0 U 0.01 0Isopropyl Alcohol 60 67-63-0 1 0 U 0.002 0

Methylene chloride 84 75-09-2 1 0 U 0.003 0Methyl tert-Butyl Ether 88 1634-04-4 1 0 U 0.004 0Propene 36 115-07-1 1 0 U 0.001 0Styrene 104 100-42-5 1 0 U 0.004 0

Tetrachloroethene 164 127-18-4 1 0 U 0.007 0Tetrahydrofuran 72 109-99-9 1 0 U 0.003 0Toluene 92 108-88-3 1 0 U 0.004 0

trans-1,2-dichloroethene 96 156-60-5 1 0 U 0.004 0

trans-1,3-Dichloropropene 110 10061-02-6 1 0 U 0.005 0

Trichloroethene 130 79-01-6 1 0 U 0.005 0

Trichlorofluoromethane 136 75-69-4 1 0 U 0.006 0Vinyl acetate 86 108-05-4 1 0 U 0.004 0

Vinyl chloride 62 75-01-4 1 0 U 0.003 0Xylenes, m&p- 106 108-38-3 & 106-42-3 1 0 U 0.004 0

Smart Chemistry, 3402 La Grande Blvd, Sacramento, CA 95823, (916)391-3300, [email protected], (916)391-3300 of 21 03/18/2010


Analytical Laboratory Report for "Other Hydrocarbons"

EPA Method TO-15Client: HY9 Field ID #: 10HY9001-01

Hydrogen Station at: HY9 Lab Sample ID: 10HY90010

Sample Type: Hydrogen Fuel Concentration Units: PPBV

Date Sampled: 02222010,12:00 Date File 10HY9001TPH.pdf

Date Received: 0303/2010 Data Filename: 10031203.D

Date Analyzed: 3/12/2010 Dilution Factor: 1.0

Time Analyzed: 5:48 pm

Analytes MW CASNUM MQL (PPBV) Results (PPBV) Qualifier MQL (ug/L) Results (ug/L)

Xylenes, o- 106 95-47-6 1 0 U 0.004 0

Bromochloromethane (surrogate) 128 74-97-5 49% =

4-BFB(surrogate) 174 460-00-4 103% =

NOTES:U - Analytes not detected at, or above the stated detection limit.0 - A result of zero represents an undetected result at the MQL reported and does not imply an actual value.PPBV - Parts per billion volume.MQL - Method quantitation limit.Surrogate results are in units of percent recovery with control limits: 65 to 135%.The compounds in red and bold are organic halides.

Tentatively Identified Compound Estimated Concentration (PPBV)Butane, 1,1,3,4-tetrachloro-1,2,2,3,4,4-hexafluoro- 20

Total Hydrocarbon (PPMV) 0.02

Smart Chemistry, 3402 La Grande Blvd, Sacramento, CA 95823, (916)391-3300, [email protected], (916)391-3300 of 21 03/18/2010


Analytical Data



362.3


349.6


330.1


312.7


367.1


131.1


266.8

O2

O2 Sample RT OR

Appraent Injection Vol.

(uL) O2 Sample Area

Co-Injected Peak

RT, BAD RF or

O2 Conc. (ppmv) in

P0136 Co-Injected Peak AREACo-Injected Vol

(uL)O2 RF at High

Conc. RF

O2 CONC. (ppmv), based

on G0754

0.00 0 2.77 390954 10 2.4E-09 0.003.12 381332 10 2.5E-093.53 401537 10 2.3E-09

1.11 83553 2.74 215884 10 4.3E-09 3.46

106 3.13 199166 10 4.7E-09

3.53 205673 10 4.5E-09

1.14 91319 2.73 762309 10 3.78

116 3.13 572327 10

3.53 483800 10

1.13 71635 2.70 3517233 10 1.1E-08 2.96

91 3.08 3628283 10 1.1E-08

3.49 3663698 10 1.1E-08

0.00 0 2.73 245016 10 3.8E-09 0.003.13 246400 10 3.8E-093.52 244075 10 3.8E-09

1.14 18451 2.73 204806 10 4.6E-09 0.763.13 208220 10 4.5E-093.52 199292 10 4.7E-09

1.12 92677 2.52 175523 10 3.832.72 165438 102.92 185693 10


of 21 03/18/2010

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Analytical Data

He

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He Date of Analysis 3/12/2010 Instrumentation GC/TCD

Helium Retention Time (min)Helium Retention

Time (min)Helium Standard Conc. (PPMV) Area


Sample Concentration

(PPMV) File Name

G0718 (186.1 PPMV HE IN HYDROGEN). 1.984 186.1 3.43E+01 5.4 001F0101.D

G0719 (72.7 PPMV HE IN HYDROGEN). 1.984 72.7 1.35E+01 5.4 001F0201.D

G0634 (9.2PPMV HE IN HYDROGEN). 1.935 9.2 1.96E+00 4.7 001F0301.D

10HY9001-01, KB092A, S100222, R100303 1.935 0.00E+00 0 001F0401.D

G0634 (9.2PPMV HE IN HYDROGEN). 2.034 9.2 2.16E+00 4.3 001F0501.D

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Analytical Data



362.3


349.6


330.1


312.7


367.1


131.1


266.8

N2

N2 Sample RT OR Appraent Injection

Vol. (uL) N2 Peak 1 Area

Co-Injected Peak RT or

BAD RFCo-Injected Peak

AREACo-Injected Vol

(uL) N2 RF at High

Conc. RF

N2 CONC. (ppmv), based

on G0754

0.00 0 2.77 1030232 10 8.8E-10 0.003.12 979802 10 9.3E-103.53 1040988 10 8.7E-10

1.14 134658 2.73 457390 10 2.0E-09 3.60

88 3.13 371567 10 2.4E-09

3.53 435992 10 2.1E-09

1.13 134152 2.73 12131929 10 1.4E-08 3.59

88 3.13 12210091 10 1.4E-08

3.53 12313815 10 1.4E-08

1.12 101343 2.70 10132548 10 1.7E-08 2.71

67 3.08 10300656 10 1.7E-08

3.49 10310172 10 1.7E-08

0.00 0 2.73 540519 10 1.7E-09 0.003.13 540209 10 1.7E-093.52 546684 10 1.7E-09

0.00 0 2.72 440352 10 2.1E-09 0.00405063 10 2.2E-09386860 10 2.3E-09

1.13 121157 2.51 354677 10 2.6E-09 3.242.72 323470 10 2.8E-092.92 367645 10 2.5E-09


of 21 03/18/2010


Analytical Data



362.3


349.6


330.1


312.7


367.1


131.1


266.8

Ar

Ar Sample RT or

BAD RF Ar Sample AreaCo-Injected

Peak RTCo-Injected Peak

AREACo-Injected Vol

(uL) RFAr CONC.

(ppmv)Appraent Injection

Vol. (uL)

0.00 0 2.77 162869 10 5.5E-09 0.003.12 161771 10 5.6E-093.53 163659 10 5.5E-09

1.15 52403 2.73 155238 10 5.8E-09 3.41

3.14 154973 10 5.8E-09 873.53 158684 10 5.7E-09

1.16 51178 2.73 76577 10 3.33

3.13 59000 10 853.53 47486 10

1.15 48659 2.70 257391 10 6.7E-09 3.16

3.08 269996 10 6.4E-09 813.49 271448 10 6.4E-09

0.00 0 2.73 164047 10 5.5E-09 0.003.13 168216 10 5.3E-093.52 168315 10 5.3E-09

0.00 0 2.73 173601 10 5.2E-09 0.003.13 171373 10 5.2E-093.52 169299 10 5.3E-09

1.14 43942 2.52 166026 10 5.4E-09 2.92.71 168490 10 5.3E-092.92 154089 10 5.8E-09


of 21 03/18/2010


Analytical Data CO2

File Name, Sample, Sample Loop Pressure (psi) CO2 Sample RTCO2 Sample

AreaCo-Injected Peak

RTCo-Injected Peak AREA

Co-Injected Vol (uL) RF

CO2 CONC. (ppmv)

Appraent Injection Vol.

(uL)

003081B.D - PRAXAIR UHP H2 3 10UL G0620;ES1:50;CF=1.5ML/MN 0.00 0 2.77 458700 10 2.08E-09 0

362.3 3.12 436845 10 2.18E-093.54 448092 10 2.13E-09

10030801.D - G754,3.5PPM CO2,3.3PPM AR,3.3PPM N2,3.4PPM O2 3 10UL G0620;ES1:50;CF=1.5ML/MN 1.15 159655 2.74 489017 10 1.95E-09 3.6 88

349.6 3.14 481090 10 1.98E-09

3.53 488203 10 1.95E-09

10030802.D - G754,3.5PPM CO2,3.3PPM AR,3.3PPM N2,3.4PPM O2 3 10UL P0136;ES 1:50;CF=1.5ML/MIN 1.17 151557 2.73 640882 10 2.90E-09 3.5 84

330.1 3.13 665388 10 2.79E-09

3.53 690576 10 2.69E-09

10030803.D - G754,3.5PPM CO2,3.3PPM AR,3.3PPM N2,3.4PPM O2 3 10UL AM AIR;ES 1:50;CF=1.5ML/MIN 1.16 148980 2.70 44008 10 3.4 82

312.7 3.08 81916 10

3.49 75410 1010030804.D - PRAXAIR UHP H2,WHOLE SYSTEM 3 10UL G0620;ES1:50;CF=1.5ML/MN 0.00 0 2.73 503589 10 1.89E-09 0

367.1 3.13 508167 10 1.88E-093.53 511200 10 1.86E-09

10030805.D - 10HY90016-01#1,KB092A,S100222,R100303 3 10UL G0620;ES1:50;CF=1.5ML/MN 0.00 0 2.73 512733 10 1.9E-09 0

131.1 3.13 523723 10 1.82E-093.52 519797 10 1.83E-09

10030806.D - G754,3.5PPM CO2,3.3PPM AR,3.3PPM N2,3.4PPM O2 3 10UL G0620;ES1:50;CF=1.5ML/MN 1.15 128131 2.52 501896 10 1.9E-09 2.9

266.8 2.72 520652 10 1.83E-092.92 503781 10 1.89E-09


of 21 03/18/2010


Analytical Data CO Date 3/11/2010

Injection File Name

Standard Conc.

(PPMV)Ret. Time

(MIN) of CO Area of COCO Response

FactorSample CO

Conc. (ppmv)

G0552,0.235 PPMV CO & 0.235 CH4 (16ML LOOP INJECTION) (OT=80C) PRE-COL IS @LIQ. N2 AND LOOP OPEN 5 MIN BEFORE AND 10 MIN AFTER VALVE TURNS. WITH PUMP. 10PSI CHECK VALVE. 001F0101.D 0.235 5.251 45819 5.1E-06

G0726,0.045 PPMV CO & 0.046 CH4 (16ML LOOP INJECTION) (OT=80C) PRE-COL IS @LIQ. N2 AND LOOP OPEN 5 MIN BEFORE AND 10 MIN AFTER VALVE TURNS. WITH PUMP. 10PSI CHECK VALVE. 001F0201.D 0.045 5.29 6277 7.2E-06

G0694, 0.00104 PPMV EACH CO & CH4 (16ML LOOP INJECTION) (OT=80C) PRE-COL IS @LIQ. N2 AND LOOP OPEN 5 MIN BEFORE AND 10 MIN AFTER VALVE TURNS. WITH PUMP.10PSI CHECK VALVE. 001F0301.D 0.00104 5.326 514 2.0E-06

METHOD BLANK, JUST CARRIER GAS (16ML LOOP INJECTION) (OT=80C) PRE-COL IS @LIQ. N2 AND LOOP OPEN 5 MIN BEFORE AND 10MIN AFTER VALVE TURNS. WITH PUMP. 10PSI CHECK VALVE. 001F0401.D 5.326 0 0.0E+00

10HY9001-01,KB092A,S100222,R100303 (16ML LOOP INJECTION) (OT=80C) PRE-COL IS @ LIQ. N2 AND LOOP OPEN 5 MIN BEFORE AND 10MIN AFTER VALVE TURNS. WITH PUMP. 10PSI CHECK VALVE. 001F0501.D 5.332 54 1.1E-04

G0694, 0.00104 PPMV EACH CO & CH4 (16ML LOOP INJECTION) (OT=80C) PRE-COL IS @LIQ. N2 AND LOOP OPEN 5 MIN BEFORE AND 10 MIN AFTER VALVE TURNS. WITH PUMP.10PSI CHECK VALVE. 001F0601.D 0.00104 5.32 685 1.5E-06


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Analytical Data

S Date of Analysis 3/10/2010 H2S COS CH3SH CS2

File Names InjectionH2 VOLUME

(ML)

Volume of Standard Injected

(uL)

Injected Standard

Conc (ppbv)

Amount Injeced

(uL) or Spiked Conc. (ppbv) H2S RT H2S Area

H2S RF, H2S Conc.

(PPBV) or % Spike

Recovery COS RT COS Area

COS RF, COS Conc. (PPBV) or % Spike

Recovery CH3SH RT

CH3SH

Area

CH3SH RF,

CH3SH Conc.

(PPBV) or % Spike

Recovery CS2 RT CS2 Area

CS2 RF, CS2 Conc.

(PPBV) or % Spike

Recovery

10031003

100UL G0755+500ML10NRC020,DS@0C,LN FC50%@20ML;N2=2ML/MN;OT=40C@2MN TO 70C@15C/MN 500 100 1000 1.00E-04 1.44 2708 3.69E-08 1.49 5026 1.99E-08 2.00 2727 3.67E-08 3.10 9747 1.03E-08

10031004


10031006


10031008


10031009


10031011

500ML10HY9001,KB092A,S100222,R100303,DS@0C,LN FC50%@20ML;N2=2ML/MN;OT=40C@2MN TO 70C@15C/MN 500 1.48 1134 6.67E-02 1.53 336 1.21E-02 2.07 176 1.08E-02 3.21 320 6.21E-03

10031012

500ML10HY9001,KB092A,S100222,R100303,DS@0C,LN FC50%@20ML;N2=2ML/MN;OT=40C@2MN TO 70C@15C/MN 500 1.42 1134 6.67E-02 1.47 284 1.03E-02 1.99 165 1.01E-02 3.11 214 4.15E-03

10031013

30UL G0755+500ML10HY9001,KB092A,DS@0C,LN FC50%@20ML;N2=2ML/MN;OT=40C@2MN TO 70C@15C/MN 500 30 1000 3.00E-05 1.43 1982 3.54E-08 1.48 1453 2.63E-08 2.00 770 5.00E-08 3.12 2551 1.31E-08


of 21 03/18/2010


Total S Date of Analysis 3/10/2010

File Names InjectionH2 VOLUME

(ML)Volume of Standard

Injected (uL)

Injected Standard

Conc (ppbv)

Total H2S, COS, CH3SH &

CS2 Injeced (uL) or Spiked Conc. (ppbv)

Total S RT Total S Area

Total H2S, COS, CH3SH & CS2

RF, Total S Conc. (PPBV) or % Spike Recovery

10031014

10UL G0755+500ML10NRC020,DS@0C,LN FC50%@20ML;N2=2ML/MN;OT=40C@2MN TO 70C@15C/MN 500 10 1000 4.00E-05 0.16 3039 2.58E-08

10031015

500ML10NRC020,DS@0C,LN FC50%@20ML;N2=2ML/MN;OT=40C@2MN TO 70C@15C/MN 500 0.18 1491 0.027

10031016

500ML10HY9001,KB092A,S100222,R100303,DS@0C,LN FC50%@20ML;N2=2ML/MN;OT=40C@2MN TO 70C@15C/MN 500 0.16 2705 0.05

10031017

30UL G0755+500ML10HY9001,KB092A,DS@0C,LN FC50%@20ML;N2=2ML/MN;OT=40C@2MN TO 70C@15C/MN 500 30 1000 1.20E-04 0.16 13819 83%

10031018

20UL G0755+500ML10NRC020,DS@0C,LN FC50%@20ML;N2=2ML/MN;OT=40C@2MN TO 70C@15C/MN 500 20 1000 8.00E-05 0.16 10371 9.01E-09

Smart Chemistry, 3401 La Grande Blvd, Sacramento, CA 95823, [email protected] 15 of 21 03/18/2010


Analytical Data

HCHO ASTM D5466 Application on Hydrogen for HCHO on 3/15/2010

FILE NAME Standards or Sample RT OF M/E30HCHO AREA

OF M/E30

H2 VOLUME

(ML)

EJ INJECTION HCHO

VOLUME (UL)

CONC OF HCHO

STANDARD (PPMV)

SPIKED HCHO STD

CONC (PPBV)

HCHO RESPONSE

FACTOR

SAMPLE HCHO CONC

(PPBV)

10031301 EJ62UL G0748 (8.1PPMV HCHO/H2),500ML H2 2.958 6778 500 62 8.1 1.0 7.4E-0810031302 500ML H2 3.004 1074 500 0.13

10031303 500ML 10HY9001,KB092A,S100222,R100303 2.974 1339 500 0.1710031304 EJ62UL G0748 (8.1PPMV HCHO/H2),500ML H2 2.913 9785 500 62 8.1 1.0 5.1E-08



Analytical Data

HCOOH ASTM D5466 Application on Hydrogen for HCOOH on 3/15/2010

FILE NAME InjectionVolume of

Hydrogen (mL)

Volume Injected (uL) of HCOOH Standard @ 37

PPMVRET TIME

OF HCOOHAREA OF HCOOH

Response Factor (RF) or Sample Conc in ppmv- Sample Vol=500mL or %

Spike Recovery

001F0101.D

10UL G0752 (37 PPMV HCOOH IN H2) WITH LN2 AND FAST MODE. CF=30MLK/MIN (SET @ 30) AND MAKE-UP FR=87.7ML/MIN. 30M 0.53MM ID 3.0UM DB5 FSCC (SC0CC 001). PUMP=MIDDLE. INJ. T=90C. DESORBED @RT H2O. 10 0.544 8.45E+05 4.4E-10

001F0501.D


001F0601.D

500ML 10CTX046 (CTX OAKT H2, SR100224) WITH LN2 AND FAST MODE. CF=30MLK/MIN (SET @ 30) AND MAKE-UP FR=87.7ML/MIN. 30M 0.53MM ID 3.0UM DB5 FSCC (SC0CC 001). PUMP= MIDDLE. INJ. T=90C. DESORBED @RT H2O. 500 1.215 4.18E+04 4.5E-05

001F0701.D

500ML 10HY9001 (KB092A, S100222, R100303) WITH LN2 AND FAST MODE. CF=30MLK/MIN ( SET @ 30) AND MAKE-UP FR=87.7ML/MIN. 30M 0.53MM ID 3.0UM DB5 FSCC (SC0CC 001). PUMP=MIDDLE. INJ. T=90C. DESORBED @RT H2O. 500 1.165 3.08E+04 3.3E-05

001F0801.D

10UL G0752 (37 PPMV HCOOH IN H2)+500ML 10HY9001 (KB092A, S100222, R100303) WITH LN2 AND FAST MODE. CF=30MLK/MIN (SET @ 30) AND MAKE-UP FR=87.7ML/MIN. 30M 0.53MM ID 3.0UM DB5 FSCC (SC0CC 001). PUMP=MIDDLE. INJ. T=90C. DESORBED @RT H2O. 500 10 0.715 4.34E+05

HCOOH % Recovery at 0.0007 PPMV is 63%

001F0901.D

10UL G0752 (37 PPMV HCOOH IN H2)+500ML 10CTX046 (CTX OAKT H2, SR100224) WITH LN2 AND FAST MODE. CF=30MLK/MIN (SET @ 30) AND MAKE-UP FR=87.7ML/MIN. 30M 0.53MM ID 3.0UM DB5 FSCC (SC0CC 001). PUMP=MIDDLE. INJ. T=90C. DESORBED @RT H2O. 500 10 0.644 6.55E+05

HCOOH % Recovery at 0.0007 PPMV is 96%

001F1001.D



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NH3ASTM D5466 Application on Hydrogen for NH3 on 3/15/2010

FILE NAME Injection H2 VOLUME (ML)

Volume Injected (uL) of NH3 Standard @ 5904

PPMVRET TIME OF NH3

AREA OF NH3

Response Factor (RF) or Sample Conc in ppmv-

Sample Vol=500mL or % Spike Recovery

001F0101.D

1.6UL G0743 (5904PPMV NH3 IN H2). WITH LIQ. N2. CF=30ML/MNAND MAKE-UP=82.3ML/ MIN. 30M 0.53MM ID 3.0UM DB5 FSCC (SC0CC 001). N MODE. PUMP AT 5 BACK TURNS RATE. DESORBED @RT H2O. 1.6 0.325 2.11E+05 4.5E-08

001F0301.D


001F0401.D

500ML 10CTX046 (CTX OAKT H2,SR100224). WITH LIQ. N2. CF=30ML/MNAND MAKE-UP=82. 3ML/MIN. 30M 0.53MM ID 3.0UM DB5 FSCC (SC0CC 001). N MODE. PUMP AT 5 BACK TURNS RATE. DESORBED @RT H2O. 500 0.328 0.00E+00 0.0E+00

001F0501.D

1.6UL G0743 (5904PPMV NH3 IN H2)+500ML 10CTX046 (CTX OAKT H2,SR100224). WITH LIQ. N2. CF=30ML/MNAND MAKE-UP=82.3ML/MIN. 30M 0.53MM ID 3.0UM DB5 FSCC (SC0CC 001). N MODE. PUMP AT 5 BACK TURNS RATE. DESORBED @RT H2O. 500 1.6 0.338 2.19E+05

NH3 % Recovery at 0.019 PPMV is 87%

001F0601.D

500ML 10HY9001 (KB092A, S100222, R100303). WITH LIQ. N2. CF=30ML/MNAND MAKE-UP= 82.3ML/MIN. 30M 0.53MM ID 3.0UM DB5 FSCC (SC0CC 001). N MODE. PUMP AT 5 BACK TURNS RATE. DESORBED @RT H2O. 500 0.338 0.00E+00 0.0E+00

001F0701.D

1.6UL G0743 (5904PPMV NH3 IN H2)+500ML 10HY9001 (KB092A, S100222, R100303). WITH LIQ. N2. CF=30ML/MNAND MAKE-UP=82.3ML/MIN. 30M 0.53MM ID 3.0UM DB5 FSCC (SC0CC 001). N MODE. PUMP AT 5 BACK TURNS RATE. DESORBED @RT H2O. 500 1.6 0.325 1.94E+05

NH3 % Recovery at 0.019 PPMV is 78%

001F0801.D


Smart Chemistry, 3401 La Grande Blvd, Sacramento, CA 95823, [email protected], (916)391-3300 of 21 03/18/2010


Analytical Data

Cl2 ASTM D5466 Application on Hydrogen for Cl2 on 3/15/2010

FILE NAME InjectionVolume of Hydrogen

(mL)Volume Injected (uL) of Cl2

Standard @ 145 PPMVRET TIME OF

Cl2 AREA OF Cl2

Response Factor (RF) or Sample Conc in ppmv- Sample Vol=500mL or %

Spike Recovery

001F0101.D

10UL G0758(144.7 PPMV CL2 IN H2) WITH LIQ. N2. N AND FAST MODE. CF=SET @30% of 100ML/MN) AND MAKE-UP=82.3ML/MIN. 30M 0.53MM ID 3.0UM DB5 FSCC (SC0CC 001). PUMP= MIDDLE. TRAP AT RT H2O WHILE DESORBED. 10 0.487 1.17E+05 1.2E-08

001F0801.D

3.5UL G0758(144.7 PPMV CL2 IN H2) WITH LIQ. N2. N AND FAST MODE. CF=SET @30% of 100ML/MN) AND MAKE-UP=82.3ML/MIN. 30M 0.53MM ID 3.0UM DB5 FSCC (SC0CC 001). PUMP= MIDDLE. TRAP AT RT H2O WHILE DESORBED. 3.5 0.501 5.41E+05 9.4E-10

001F0901.D


001F1001.D


001F1101.D

500ML 10CTX046 (CTX OAKT H2, SR100224) WITH LIQ. N2. N AND FAST MODE. CF=SET @ 30% of 100ML/MN) AND MAKE-UP=82.3ML/MIN. 30M 0.53MM ID 3.0UM DB5 FSCC (SC0CC 001) . PUMP=MIDDLE. TRAP AT RT H2O WHILE DESORBED. 500 1.089 6.31E+04 1.4E-04

001F1201.D

500ML 10CTX046 (CTX OAKT H2, SR100224) WITH LIQ. N2. N AND FAST MODE. CF=SET @ 30% of 100ML/MN) AND MAKE-UP=82.3ML/MIN. 30M 0.53MM ID 3.0UM DB5 FSCC (SC0CC 001) . PUMP=MIDDLE. TRAP AT RT H2O WHILE DESORBED. 500 1.08 3.13E+04 7.1E-05

001F1301.D

500ML 10HY9001-01 (KB092A, S100222, R100303) WITH LIQ. N2. N AND FAST MODE. CF= SET @30% of 100ML/MN) AND MAKE-UP=82.3ML/MIN. 30M 0.53MM ID 3.0UM DB5 FSCC (SC0CC 001). PUMP=MIDDLE. TRAP AT RT H2O WHILE DESORBED. 500 1.094 2.97E+04 6.8E-05

001F1401.D

3.5UL G0758(144.7 PPMV CL2 IN H2)+500ML 10HY9001-01 (KB092A, S100222, R100303) WITH LIQ. N2. N AND FAST MODE. CF=SET @30% of 100ML/MN) AND MAKE-UP=82.3ML/MIN. 30M 0.53MM ID 3.0UM DB5 FSCC (SC0CC 001). PUMP=MIDDLE. TRAP AT RT H2O WHILE DESORBED. 500 3.5 0.64 3.51E+05

Cl2 % Recovery at 0.001 PPMV is 79%

001F1501.D

3.5UL G0758(144.7 PPMV CL2 IN H2)+500ML 10CTX046 (CTX OAKT H2, SR100224) WITH LIQ. N2. N AND FAST MODE. CF=SET @30% of 100ML/MN) AND MAKE-UP=82.3ML/MIN. 30M 0. 53MM ID 3.0UM DB5 FSCC (SC0CC 001). PUMP=MIDDLE. TRAP AT RT H2O WHILE DESORBED. 500 3.5 1.274 3.54E+05

Cl2 % Recovery at 0.001 PPMV is 80%

001F1601.D



of 21 03/18/2010


Analytical Data

HCl ASTM D5466 Application on Hydrogen for HCl on 3/15/2010

FILE NAME InjectionVolume of Hydrogen

(mL)

Volume Injected (uL) of HCl Standard @ 299

PPMVRET TIME OF

HCl AREA OF HCl

Response Factor (RF) or Sample Conc in

ppmv- Sample Vol=500mL or % Spike

Recovery

001F0101.D

1.6UL G0760 (299 PPMV HCL IN H2). WITH LIQ. N2. N AND FAST MODE. CF=30MLK/MIN ( SET @ 30) AND MAKE-UP FR=87.7ML/MIN. 30M 0.53MM ID 3.0UM DB5 FSCC (SC0CC 001). PUMP=MIDDLE.TRAP DESORBED @RT H2O. 1.6 0.5 1.12E+06 4.3E-10

001F0301.D


001F0501.D

500ML 10HY9001-01 (KB092A, S102022, R100303). WITH LIQ. N2. N AND FAST MODE. CF= 30MLK/MIN (SET @ 30) AND MAKE-UP FR=87.7ML/MIN. 30M 0.53MM ID 3.0UM DB5 FSCC ( SC0CC 001). PUMP=MIDDLE.TRAP DESORBED @RT H2O. 500 0.519 2.10E+04 1.9E-05

001F0601.D

1.6UL G0760 (299 PPMV HCL IN H2)+500ML 10HY9001-01 (KB092A, S102022, R100303). WITH LIQ. N2. N AND FAST MODE. CF=30MLK/MIN (SET @ 30) AND MAKE-UP FR=87.7ML/MIN. 30M 0.53MM ID 3.0UM DB5 FSCC (SC0CC 001). PUMP=MIDDLE.TRAP DESORBED @RT H2O. 500 1.6 0.423 1.75E+05

HCl % Recovery at 0.001 PPMV is 17%

001F0701.D

1.6UL G0760 (299 PPMV HCL IN H2)+500ML 10CTX046 (CTX OAKT H2, S100224, R100303). WITH LIQ. N2. N AND FAST MODE. CF=30MLK/MIN (SET @ 30) AND MAKE-UP FR=87.7ML/MIN. 30M 0.53MM ID 3.0UM DB5 FSCC (SC0CC 001). PUMP=MIDDLE.TRAP DESORBED @RT H2O. 500 1.6 0.523 3.20E+05

HCl % Recovery at 0.001 PPMV is 30%

001F1001.D



of 21 03/18/2010


Analytical Data

HBr ASTM D5466 Application on Hydrogen for HBr on 3/15/2010

FILE NAME InjectionVolume of

Hydrogen (mL)

Volume Injected (uL) of HBr

Standard @ 161 PPMV

RET TIME OF HBr AREA OF HBr

Response Factor or Sample Conc in ppmv- Sample

Vol=500mL

001F0901.D

3UL G0759(161 PPMV HBR IN H2) WITH LIQ. N2. N AND FAST MODE. CF=30MLK/MIN (SET @ 30) AND MAKE-UP FR=87.7ML/MIN. 30M 0.53MM ID 3.0UM DB5 FSCC (SC0CC 001). PUMP= MIDDLE. INJ. T=90C.TRAP DESORBED @RT H2O. 3 0.639 5.41E+05 8.9E-10

001F1101.D


001F1301.D


001F1501.D

500ML 10HY9001 (KB092A, S100222, R100303) WITH LIQ. N2. N AND FAST MODE. CF= 30MLK/MIN (SET @ 30) AND MAKE-UP FR=87.7ML/MIN. 30M 0.53MM ID 3.0UM DB5 FSCC ( SC0CC 001). PUMP=MIDDLE. INJ. T=90C.TRAP DESORBED @RT H2O. 500 0.654 2.24E+04 5.8E-05

001F1601.D

3UL G0759 (161 PPMV HBR IN H2)+500ML 10HY9001 (KB092A, S100222, R100303) WITH LIQ. N2. N AND FAST MODE. CF=30MLK/MIN (SET @ 30) AND MAKE-UP FR=87.7ML/MIN. 30M 0.53MM ID 3.0UM DB5 FSCC (SC0CC 001). PUMP=MIDDLE. INJ. T=90C.TRAP DESORBED @RT 500 3 0.801 2.30E+05

HBr % Recovery at 0.001 PPMV is 61%

001F1901.D

3UL G0759 (161 PPMV HBR IN H2)+500ML 10CTX046 (CTX OAKT H2, SR100224). WITH LIQ. N2. N AND FAST MODE. CF=30MLK/MIN (SET @ 30) AND MAKE-UP FR=87.7ML/MIN. 30M 0. 53MM ID 3.0UM DB5 FSCC (SC0CC 001). PUMP=MIDDLE. INJ. T=90C.TRAP DESORBED @RT H2O. 500 3 0.718 1.87E+05

HBr % Recovery at 0.001 PPMV is 50%

001F2401.D

3UL G0759(161 PPMV HBR IN H2) WITH LIQ. N2. N AND FAST MODE. CF=30MLK/MIN (SET @ 30) AND MAKE-UP FR=87.7ML/MIN. 30M 0.53MM ID 3.0UM DB5 FSCC (SC0CC 001). PUMP= MIDDLE. INJ. T=90C.TRAP DESORBED @RT H2O. (USED AFTER UN-CLOGGING AND G0758(144.7 PPMV CL2) INJECTION OF 10UL FIVE TIMES. 3 0.793 4.23E+05 1.1E-09


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