Elastic Properties of Solids Topics Discussed in Kittel, Ch. 3, pages 73-85
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Elastic Properties of SolidsTopics Discussed in Kittel, Ch. 3, pages 73-85
Analysis of Elastic Strains
Continuum approximation: good for λ > 30A.Description of deformation (Cartesian coordinates):
Material point i i i ix x x u r r r u r
Ref: L.D.Landau, E.M.Lifshitz, “Theory of Elasticity”, Pergamon Press (59/86)
Displacement vector field u(r).
i id x dx d d d r r r r r r u r rNearby point d d r r u r r u r
ii i j
j
udx dx dxx
222dl d d d r r r u r
d d d r r r u r
2 2d d d d d r r r u r r u r r u r
2 2 i k ki j i j
j i j
u u udl dx dx dx dxx x x
2 2 ji k ki j
j i i j
uu u udl dl dx dx
x x x x
2 i j i ju dx dx
12
ji k ki j
j i i j
uu u uu
x x x x
= strain tensor
12
jii j
j i
uuux x
= linear strain tensor
Dilation
uik is symmetric → diagonalizable → principal axes such that
2 2i j i j i jdl u dx dx 1 2 32 2 21 2 31 2 1 2 1 2u dy u dy u dy
1 2 ii idy u dy → (no summation over i ) 1 i
iu dy
ii
dV dy 1 ii
i
u dy 1 i
i
u dV 1 iiu dV
iidV dV u
dV
Trace of uikFractional volume change
StressTotal force acting on a volume element inside solid
V
dVf f force density
Newton’s 3rd law → internal forces cancel each other → only forces on surface contribute
i ki
k
fx
This is guaranteed if so that i i k kV S
f dV dS σ stress tensor
σik ith component of force acting on the surface element normal to the xk axis.
Moment on volume element
ik i k k iM f x f x dV i j k jk i
j j
x x dVx x
k ii j k k j i i j k j
j j j
x xx x dV dVx x x
i j k k j i j i k k ix x dS dV
Only forces on surface contribute → i k k i (σ is symmetric)
Elastic Compliance & Stiffness Constants
σ and u are symmetric → they have at most 6 independent components
Compact index notations (i , j) → α :(1,1) → 1, (2,2) → 2, (3,3) → 3, (1,2) = (2,1) → 4, (2,3) = (3,2) → 5, (3,1) = (1,3) → 6
1, 2,3for
4,5,6ii
i j j i
uu
u u
u S
S α β elastic compliance constants
12 i j k l i j k lU C u uElastic energy density: 1
2C u u
where
i j k lC C elastic stiffness constants
i , j , k, l = 1,2,3α , β = 1,2,…,6
elastic modulus tensor
Stress: m nm n
Uu
12 i j k l mi n j k l i j m k nlC u u
12 mnk l k l i j mn i jC u C u m n k l k lC u
i j k l j i k l i j l k j il k
k l i j l k i j k l j i l k j i
C C C C
C C C C
i jU C uu
uik & uki treated as independent
21
Elastic Stiffness Constants for Cubic Crystals
2 2 2 2 2 21111 11 22 33 1122 11 22 22 33 33 11 1212 12 23 31
1 22
U C u u u C u u u u u u C u u u
Invariance under reflections xi → –xi C with odd numbers of like indices vanishes
Invariance under C3 , i.e.,
1111iiiiC C
x y z x x z y x
x z y x x y z x
All C i j k l = 0 except for (summation notation suspended):
1122ii k kC C 1212i k ikC C
2 2 2 2 2 211 1 2 3 12 1 2 2 3 3 1 44 4 5 6
1 12 2
C u u u C u u u u u u C u u u
1 111 12 12
2 212 11 12
3 312 12 11
4 444
5 544
6 644
0 0 00 0 00 0 0
0 0 0 0 00 0 0 0 00 0 0 0 0
uC C CuC C CuC C CuCuCuC
111 12 12 11 12 12
12 11 12 12 11 12
12 12 11 12 12 11
44 44
44 44
44 44
0 0 0 0 0 00 0 0 0 0 00 0 0 0 0 0
0 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0
C C C S S SC C C S S SC C C S S S
C SC S
C S
where 11 12
1111 12 11 122
C CSC C C C
12
1211 12 11 122
CSC C C C
44
44
1SC
111 12 11 12S S C C 1
11 12 11 122 2S S C C
Bulk Modulus & Compressibility
2 2 2 2 2 211 1 2 3 12 1 2 2 3 3 1 44 4 5 6
1 12 2
U C u u u C u u u u u u C u u u
Uniform dilation:
211 12
1 26
U C C
1 2 3 3u u u
4 5 6 0u u u
δ = Tr uik = fractional volume change
212
B B = Bulk modulus
1 VV p
11 121 23
B C C = 1/κ κ = compressibility
See table 3 for values of B & κ .
Elastic Waves in Cubic Crystals
Newton’s 2nd law:2
2i ki
k
ut x
don’t confuse ui with uα
i k ik j l j lC u →2
2jli
i k j lk
uu Ct x
2212
jli k j l
k j k l
uuC
x x x x
2l
ik j lk j
uC
x x
2 22 2 2 2 2 23 31 1 2 2 1 1
1111 1122 1133 1212 1221 1313 13312 2 2 21 1 2 1 3 2 1 2 3 1 3
u uu u u u u uC C C C C C Ct x x x x x x x x x x x
2 22 2 2 2 23 31 2 2 1 1
1111 1122 12122 2 21 1 2 1 3 2 1 2 3 1 3
u uu u u u uC C Cx x x x x x x x x x x
22 2 2 2 2
31 1 2 1 111 12 44 442 2 2 2
1 1 2 1 3 2 3
uu u u u uC C C Ct x x x x x x x
Similarly 22 2 2 2 2
32 2 1 2 211 12 44 442 2 2 2
2 2 3 2 1 1 3
uu u u u uC C C Ct x x x x x x x
2 2 2 22 2
3 3 3 32 111 12 44 442 2 2 2
3 3 2 3 1 2 1
u u u uu uC C C Ct x x x x x x x
Dispersion Equation2 2
2i l
i k j lk j
u uC
t x x
0
i ti iu u e k r
→2
0 0i i k j l k j lu C k k u
20 0il i k j l k j lC k k u
2 0i l i k j l k jC k k dispersion equation
2 0I kC i j imn j m nC k kkC
Waves in the [100] direction
2 0I kC i j i mn j m nC k kkC
1,0,0kk → 211i j i jC kkC
1111
22112
3113
0 00 00 0
Ck C
C
kC11
244
44
0 00 00 0
Ck C
C
11L
C k
0 1,0,0u Longitudinal
44T
C k
0 0,1,0u
Transverse, degenerate 0 0,0,1u
Waves in the [110] direction
2 0I kC i j i mn j m nC k kkC
1,1,02
kk →
2
11 12 21 22 2i j i j i j i j i jkC C C C kC
1111 1221 1122 12122
2121 2211 2112 2222
3113 3223
00
20 0
C C C Ck C C C C
C C
kC11 44 12 442
12 44 11 44
44
00
20 0 2
C C C Ck C C C C
C
11 12 441 2
2L C C C k
0 1,1,0u Lonitudinal
442T
C k
0 0,0,1u
Transverse 1 11 121
2T C C k
0 1, 1,0 u
Transverse