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Page 1: Definitions for Thermodynamics - chemistry.alanearhart.orgchemistry.alanearhart.org/resources/Handouts/defs-thermo-qr.pdf · Definitions for Thermodynamics Alan D. Earhart 5/16/2017

DefinitionsforThermodynamics

AlanD.Earhart 5/16/2017

Energy:Thecapacitytodoworkortransferheat.Enthalpy:Energychangeatconstantpressure.Entropy:Theamountofmoleculardisorderorrandomnessinasystem.FreeEnergy:G=H–TS ΔG=ΔH–TΔS ΔG0=ΔH0–TΔS0Heat:Theprocessofenergytransferfromonebodyorsystemtoanotherasaresultofadifferenceintemperature.LawsofThermodynamics FirstLaw:Energyisconserved.Itcanbeneithercreatednordestroyedinanisolatedsystem. SecondLaw:Inanisolatedsystem,naturalprocessesarespontaneouswhentheyleadtoan increaseinentropy. ThirdLaw:Theentropyofaperfectcrystalofanypuresubstanceapproacheszeroasthe temperatureofthecrystalapproaches0K. ZerothLaw:Whentwosystemsareinequilibriumwithathird,thosetwosystemsarein equilibriumwitheachother.SpontaneousProcess:Aprocessthatproceedsonitsownwithoutanycontinuousexternalinfluence.StateFunction:Apropertyofasystemthatisdeterminedonlybythestateorconditionofthesystem.StandardConditions:Solutions1mol/L;pressure1atm;ifthetemperatureisnotspecified,25°C.StandardState:Themoststableformofasubstanceunderstandardconditions.Surroundings:Everythingbutthesystem.System:Portionoftheuniversebeingstudied.Temperature:Thepropertyofabodyorregionofspacethatdetermineswhetherornottherewillbeanetflowofheatintooroutofitfromaneighboringbodyorregionandinwhichdirectiontheheatwillflow.

Prausnitz Thermodynamics Notes 26

Prausnitz Thermodynamics Notes 26

Heat and Thermodynamics - Razi University

Heat and Thermodynamics - Razi University

Week 5/Tu: Thermo, Lecture Unit ‘11’ · Week 5/Tu: Thermo, Lecture Unit ‘11’ © DJMorrissey, 2o12 ... Week 5/Tu: Chemical Thermodynamics © DJMorrissey, ... simply a form

Week 5/Tu: Thermo, Lecture Unit ‘11’ · Week 5/Tu: Thermo, Lecture Unit ‘11’ © DJMorrissey, 2o12 ... Week 5/Tu: Chemical Thermodynamics © DJMorrissey, ... simply a form

First Law of Thermodynamics

First Law of Thermodynamics

Entanglement and thermodynamics in non-equilibrium ...

Entanglement and thermodynamics in non-equilibrium ...

Chapter 19 Notes Chemical Thermodynamics- Entropy and The Laws of Thermodynamics.

Chapter 19 Notes Chemical Thermodynamics- Entropy and The Laws of Thermodynamics.

THERMODYNAMICS & THERMOCHEMISTRY - …kea.kar.nic.in/vikasana/chemistry_2013/che_c10.pdf · THERMODYNAMICS & THERMOCHEMISTRY ... and strong acid is -57.0 KJ. ... from solution having

THERMODYNAMICS & THERMOCHEMISTRY - …kea.kar.nic.in/vikasana/chemistry_2013/che_c10.pdf · THERMODYNAMICS & THERMOCHEMISTRY ... and strong acid is -57.0 KJ. ... from solution having

Thermo Chapter Eleven

Thermo Chapter Eleven

Mr Thermo-ch7 Partie 2

Mr Thermo-ch7 Partie 2

Reaction Thermodynamics - Harvard Universitypeople.fas.harvard.edu/~lsci1a/11-9notes.pdf · thermodynamics of various reactions, scientists have defined a “standard state” set

Reaction Thermodynamics - Harvard Universitypeople.fas.harvard.edu/~lsci1a/11-9notes.pdf · thermodynamics of various reactions, scientists have defined a “standard state” set

Thermo-Chemistry Curve Balls

Thermo-Chemistry Curve Balls

Thermodynamics - University of Edinburghgja/thermo/lectures/lecture17.pdf · Chemical equilibrium of a reacting system Closed system, xed (T;P) boundary Minimise G (set dG = 0) dG

Thermodynamics - University of Edinburghgja/thermo/lectures/lecture17.pdf · Chemical equilibrium of a reacting system Closed system, xed (T;P) boundary Minimise G (set dG = 0) dG

WJEC Definitions and Answers A2

WJEC Definitions and Answers A2

Gherman Group Meeting Thermodynamics and … · Gherman Group Meeting. Thermodynamics and Kinetics and Applications. June 25, 2009

Gherman Group Meeting Thermodynamics and … · Gherman Group Meeting. Thermodynamics and Kinetics and Applications. June 25, 2009

Physical Chemistry: Thermodynamics, Statistical Mechanics ... · Physical Chemistry: Thermodynamics, Statistical Mechanics, and Kinetics Objectives Review Questions Chapter 1 1.1

Physical Chemistry: Thermodynamics, Statistical Mechanics ... · Physical Chemistry: Thermodynamics, Statistical Mechanics, and Kinetics Objectives Review Questions Chapter 1 1.1

Physics 213: Lecture 3, Pg 1 Packet 3.4 Thermodynamics Thermodynamics l Internal Energy l W = PΔV l 1 st Law of Thermodynamics: ΔU = Q – W l Define: Adiabatic,

Physics 213: Lecture 3, Pg 1 Packet 3.4 Thermodynamics Thermodynamics l Internal Energy l W = PΔV l 1 st Law of Thermodynamics: ΔU = Q – W l Define: Adiabatic,

Chemical Thermodynamics

Chemical Thermodynamics

Thermodynamics quantities of calcium hydroxide

Thermodynamics quantities of calcium hydroxide

Chemical Thermodynamics with Applications in the Humanities— Edison Bittencourt (2007), “Thermodynamics of Irreversible Processes and the Teaching of Thermodynamics in Chemical

Chemical Thermodynamics with Applications in the Humanities— Edison Bittencourt (2007), “Thermodynamics of Irreversible Processes and the Teaching of Thermodynamics in Chemical

MIT Thermo Lect B 2015paocweb.mit.edu/files/MIT_Thermo_Lect_B_2015.pdf · Thermodynamics Lectures, MIT, 2015 40 40 Differential relationships between ηθ,,Θ and S A Taking"specific"enthalpy"to"beafunction"of"potential"temperature(rather"than"of"

MIT Thermo Lect B 2015paocweb.mit.edu/files/MIT_Thermo_Lect_B_2015.pdf · Thermodynamics Lectures, MIT, 2015 40 40 Differential relationships between ηθ,,Θ and S A Taking"specific"enthalpy"to"beafunction"of"potential"temperature(rather"than"of"