continuity equation for probability densitycontinuity equation for probability density continuity...
Transcript of continuity equation for probability densitycontinuity equation for probability density continuity...
continuity equation for probability density
continuity equation for probability density
probability-density current
time-dependent Schrödinger equation
i~��(⇥r , t)�t
=
✓�~22m⇥r2 + V (⇥r , t)
◆�(⇥r , t)
Born interpretation: |Ψ(r,t)|2 is probability density for finding particle at time t at position r
�|�|2
�t= �⇥⇥ ·⇥j
�j = �i~2m
�� �r��� �r�
�
Crank-Nicolson algorithm
✓1 +1
2iH�t
◆⇥(tn+1) =
✓1�1
2iH�t
◆⇥(tn)
e�iH�t ⇡1� 12 iH�t1 + 12 iH�t
separation of variables
time-independent potential
A(t) = A0 e�iEt/~
general solution: linear combination of eigenstates
i~��(⇥r , t)�t
=
✓�~22m⇥r2 + V (⇥r)
◆�(⇥r , t)
time-independent Schrödinger equation (eigenvalue problem)
ansatz: (~r , t) = A(t)'(~r)
i~@A(t)@t
'(~r) = A(t)E '(~r) = A(t)
✓�~22m~r2 + V (~r)
◆'(~r)
✓�~22m~r2 + V (~r)
◆'(~r) = E '(~r)
(~r , t) =X
n
an e�iEnt/~ 'n(~r)
particle in a box
discrete energies zero-point energy
increasing number of nodes
symmetry of potential symmetry of solutions (density)
even/odd eigenfunctions
En =~22m
✓n⇡
Lz
◆2boundary conditions ⇒ quantization
⇥n(z) =
r2
Lzsin
✓n� z
Lz
◆
particle in a box
En =~22m
✓n⇡
Lz
◆2boundary conditions ⇒ quantization
⇥n(z) =
r2
Lzsin
✓n� z
Lz
◆
free wave packets
free time-independent Schrödinger equation: �~22m
d2
dx2�(x) = E�(x)
eigenfunctions and -values: �k(x) = C eikx ; Ek =
~2k22m
normalization:Zdx |�k(x)|2 = C2
Z 1
�1dx =??
improper wave functions:
with ‘normalization’ as in Fourier transform:Zdx ⇤k 0(x)⇤k(x) =
1
2⇥
Z 1
�1dx e i(k�k
0)x = �(k � k 0)
⇥k(x) =1p2�e ikx
wave packet: normalizable linear combination of plane waves
�(x, t) =1p2�
Zdk ⇥̃(k) e i(kx��(k) t)
Zdk |�̃(k)|2 = 1with
approximation to Dirac delta function
-20
-10
0
10
20
30
40
50
-2 -1 0 1 2
k-k’
L=10
L=20
L=50
sin(Lx)
x
Z 1
�1dz e i(k�k
0)z = limL!1
2sin((k � k 0)L/2)(k � k 0) = 2⇥ �(k � k 0)
Z L/2
�L/2dz e i(kn�km)z =
2sin((kn � km)L/2)kn � km
= L �n,m (kn = 2⇡n/L)<latexit sha1_base64="0CjoeavBCD/2nTUrFDGvHVauKiw=">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</latexit><latexit sha1_base64="0CjoeavBCD/2nTUrFDGvHVauKiw=">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</latexit><latexit sha1_base64="0CjoeavBCD/2nTUrFDGvHVauKiw=">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</latexit><latexit sha1_base64="0CjoeavBCD/2nTUrFDGvHVauKiw=">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</latexit>
Gaussian wave packet
⇤̃(k) =1pp2� ⇥k
e�(k�k0)2/4�2k
probability density for finding momentum ħk is Gaussian of width σk, centered at k0
|�̃(k)|2
probability density for finding particle at time t in position x is a Gaussianof width �x
p1 + ⇥2�t
2, where �x = 1/2�k and ⇥� = ~/2m�2x ,with its center moving with the group velocity vg = ~k0/m.
�(x, t) =1p
(2�)3/2⇥k
Zdk e�(k�k0)
2/4�2k e i(kx�⇥(k)t)
=1qp
2�⇥x(1 + i⇤�t)e i(k0x�⇥(k0)t) e
� (x�vg t)2
4�2x (1+i⇥� t)
spreading of wave packet
0
1
2
3
4
5
-4 -2 0 2 4
�x(
t)/�
x
�� t
Heisenberg limit: σx σk=½
spre
ading
of en
semble
of cl
assic
al pa
rticles
with G
auss
ian m
omen
tum di
stribu
tion
wave packet
0
0.5
1
1.5
2
2.5
3
-20 -15 -10 -5 0 5 10 15 20
t=0.00
0
0.5
1
1.5
2
2.5
3
-20 -15 -10 -5 0 5 10 15 20
t=1.00
0
0.5
1
1.5
2
2.5
3
-20 -15 -10 -5 0 5 10 15 20
t=2.00
0
0.5
1
1.5
2
2.5
3
-20 -15 -10 -5 0 5 10 15 20
t=3.00
superposition of two wave packets
0
0.5
1
1.5
2
2.5
3
-20 -15 -10 -5 0 5 10 15 20
t=1.00
0
0.5
1
1.5
2
2.5
3
-20 -15 -10 -5 0 5 10 15 20
t=2.00
0
0.5
1
1.5
2
2.5
3
-20 -15 -10 -5 0 5 10 15 20
t=3.00
0
0.5
1
1.5
2
2.5
3
-20 -15 -10 -5 0 5 10 15 20
t=4.10
wave packet hitting infinite wall
0
0.5
1
1.5
2
2.5
3
-20 -15 -10 -5 0 5 10 15 20
t=1.00
0
0.5
1
1.5
2
2.5
3
-20 -15 -10 -5 0 5 10 15 20
t=1.50
0
0.5
1
1.5
2
2.5
3
-20 -15 -10 -5 0 5 10 15 20
t=2.00
0
0.5
1
1.5
2
2.5
3
-20 -15 -10 -5 0 5 10 15 20
t=3.00