Colloid Transport and Colloid-Facilitated Transport in Groundwater Introduction DLVO Theory...

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Transcript of Colloid Transport and Colloid-Facilitated Transport in Groundwater Introduction DLVO Theory...

  • Slide 1
  • Colloid Transport and Colloid-Facilitated Transport in Groundwater Introduction DLVO Theory Stabilization/Transport/Aggregation/Filtration Applications Special Case: CFT the Vadose Zone B.C. Williams, 2002
  • Slide 2
  • Colloids Defined Particles with diameters < 10 micron, < 0.45 Mineral detrital(as deposited) or autigenic (from matrix) Layer silicates Silica Rich Particles Iron oxides Organic e.g. humic macromolecules Humic macromolecules Biocolloids bacteria and viruses
  • Slide 3
  • Slide 4
  • Groundwater Transport in General Usual conceptual model for groundwater transport as follows: Dissolved phase Adsorbed phase (onto soil/rock matrix) How a given chemical partitions into these two phases is represented by the partition coefficient, K d.
  • Slide 5
  • Groundwater Transport Including Colloid-Facilitated Transport Three phases Dissolved phase Adsorbed phase (onto soil/rock matrix) Adsorbed onto mobile particles
  • Slide 6
  • Colloid-Facilitated Groundwater Transport Adsorbed Solid matrix Dissolved mobile colloid
  • Slide 7
  • DLVO Theory Derjaguin, Landau, Verwey, Overbeek The stability of a homogeneous colloidal suspension depends upon (stability=dispersed) Van der Waals attractive forces (promote aggregation) Electrostatic repulsive forces that drive particles apart If electrostatic dominates, particles are electrostatically stabilized (dispersed)
  • Slide 8
  • DLVO - stabilized Colloids are stabilized (in suspension) when: Double layers expand (by decreasing electrolyte concentration, decreasing ionic strength Net particle charge 0 Colloids coagulate/aggregate when: Double layer shrinks because of increasing ionic strength
  • Slide 9
  • Challenges to DLVO Hot controversy in literature on whether spheres of like charge always repel. Experimental evidence that colloidal electrostatic interactions include a long- ranged attractive component. http://griergroup.uchicago.edu/~grier/lesho uches2/leshouches2.html http://griergroup.uchicago.edu/~grier/lesho uches2/leshouches2.html http://griergroup.uchicago.edu/~grier/comm ent3b/ http://griergroup.uchicago.edu/~grier/comm ent3b/
  • Slide 10
  • Stabilization and sorbable species Sorbed species can influence surface charge, and therefore stability (end of DLVO discussion) Sorbed species can also be mobilized if the colloid is mobilized through the soil/rock matrix (colloid-facilitated transport!)
  • Slide 11
  • Colloid Transport in General (Saturated and Unsaturated GW) Detachment / Mobilization / Suspension Stabilization Transport Aggregation / Filtration / Straining
  • Slide 12
  • Detachment/Mobilization/ Suspension Colloids can detach from matrix Biogeochemical weathering Precipitation from solution (thermodyn) Biocolloids or humics flushed from shallow zones If cementing agents dissolve If stable aggregates deflocculate
  • Slide 13
  • Transport More likely if colloid is neg. charged, because most soil/rock matrices are neg. Transport optimal if: Slow interpore transport rate few collisions with side surfaces High velocities in preferential pathways In preferential pathways, may have faster travel times than ambient gw flows
  • Slide 14
  • Stabilization/Aggregation Aggregation occurs when double layer shrinks due to increasing ionic strength (slide #6)
  • Slide 15
  • Filtering / Straining Physical filtering due to size, geometry Physicochemical straining surface chemical attraction to matrix Cementation agents (iron oxides, carbonates, silica)
  • Slide 16
  • Applications Many engineering ramifications of passage versus filtration Colloid-facilitated transport how a low-solubility (strongly-sorbed!) contaminant can travel miles from the source
  • Slide 17
  • Engineering Applications Wastewater sand filters removal is good, too-small particles clog Roads clogging of drain filters force buildup failure Dams matrix piping erosion 26% of earth dam failures ref: Reddi, 1997
  • Slide 18
  • Engineering Applications, cont. Petroleum Extraction permeability reduction termed formation damage Slurry Walls very fines filtered by fines is considered good Lining of Lakes/Reservoirs ditto ref: Reddi, 1997
  • Slide 19
  • Colloid-Facilitated Transport When a highly sorptive contaminant (constituent) is adsorbed onto colloids Contaminant of interest must have as high or higher affinity to sorb as other possible constituents Colloid may have patches of surface coatings (ferric, aluminum or manganese oxyhydroxides) that are best sites
  • Slide 20
  • Colloid Transport in the Unsaturated Zone Colloids may be strained, or retarded, if moisture content reduced so that water films have thickness less than colloid diameter Colloids may sorb to the air/water interface Called partitioning same K d. concept
  • Slide 21
  • Colloid Transport in the Unsaturated Zone Ongoing Research Film Straining of Colloids http://www.lbl.gov/~jwan/film_straining/film_str aining.html http://www.lbl.gov/~jwan/film_straining/film_str aining.html http://www.lbl.gov/~jwan/particles_film/particle s_film.html http://www.lbl.gov/~jwan/particles_film/particle s_film.html Colloids Sorbing to the Air-Water Interface http://www.lbl.gov/~jwan/colloid_partition/collo id_partitioning.html http://www.lbl.gov/~jwan/colloid_partition/collo id_partitioning.html
  • Slide 22
  • References Johnson, P.R., Sun, N., and Elimelech, M., 1996. Colloid Transport in Geochemically Heterogeneous Porous Media, Environmental Science and Technology, 30, 3284-3293. Reddi, L. N., 1997. Particle Transport in Soils: Review of Significant Processes in Infrastructure Systems. J. Infrastructure Systems. 3, 78-86. McCarthy, J.F., Zachara, J.M., 1989. Subsurface Transport of Contaminants. Environmental Science and Technology, 23, 496- 502. Wan, J. T.K. Tokunaga, 1998. "Measuring partition coefficients of colloids at air-water interfaces", Environ. Sci. Technol, 32, p3293- 3298, Wan, J., Wilson, J.L., 1994. Colloid transport in unsaturated porous media. Water Resources Research. 30, 857-864.
  • Slide 23
  • Acknowledgements Jason Shira, MS Student George Redden, INEEL