ChemInform Abstract: A Novel Synthesis of Alkyl, Aryl, Alkenyl, and Alkynyl 1,6-Diketones.
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1999 alkylation, arylation, dealkylation, dearylation, C-acylation, olefination alkylation, arylation, dealkylation, dearylation, C-acylation, olefination O 0280 32 - 063 A Novel Synthesis of Alkyl, Aryl, Alkenyl, and Alkynyl 1,6-Diketones. — α-Benzotriazole ether moieties are used as acyl anion synthons to synthesize both symmetrical and unsymmetrical alkyl, aryl, alkenyl, and alkynyl 1,6- diketones by a lithiation, alkylation, and hydrolysis sequence. The hydrolysis of the dibenzotriazole intermediates is performed depending on the substituents at the two ends either by dilute HCl or using a mixture of oxalic acid, water, and silica gel. — (KATRITZKY, ALAN R.; HUANG, ZHIZHEN; FANG, YUNFENG; PRAKASH, INDRA; J. Org. Chem. 64 (1999) 6, 2124-2126; Cent. Heterocycl. Comp., Dep. Chem., Univ. Fla., Gainesville, FL 32611, USA; EN) 1
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Transcript of ChemInform Abstract: A Novel Synthesis of Alkyl, Aryl, Alkenyl, and Alkynyl 1,6-Diketones.
1999 alkylation, arylation, dealkylation, dearylation, C-acylation, olefination
alkylation, arylation, dealkylation, dearylation, C-acylation, olefinationO 0280
32 - 063A Novel Synthesis of Alkyl, Aryl, Alkenyl, and Alkynyl 1,6-Diketones.— α-Benzotriazole ether moieties are used as acyl anion synthons to synthesizeboth symmetrical and unsymmetrical alkyl, aryl, alkenyl, and alkynyl 1,6-diketones by a lithiation, alkylation, and hydrolysis sequence. The hydrolysis ofthe dibenzotriazole intermediates is performed depending on the substituentsat the two ends either by dilute HCl or using a mixture of oxalic acid, water,and silica gel. — (KATRITZKY, ALAN R.; HUANG, ZHIZHEN; FANG,YUNFENG; PRAKASH, INDRA; J. Org. Chem. 64 (1999) 6, 2124-2126; Cent.Heterocycl. Comp., Dep. Chem., Univ. Fla., Gainesville, FL 32611, USA; EN)
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